Anti-ultraviolet PET (Polyethylene Terephthalate) thermal shrinkage film

A heat-shrinkable film and anti-ultraviolet technology, applied in the field of PET heat-shrinkable film, can solve the problems of poor anti-ultraviolet performance of PET heat-shrinkable film, shorten the life of PET heat-shrinkable film, and decrease the performance of PET heat-shrinkable film, etc., to achieve excellent mechanical properties performance, improved durability, anti-aging effect

Inactive Publication Date: 2019-01-11
马鞍山卓凡新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Among the heat-shrinkable films produced in the prior art, PVC heat-shrinkable films are widely used and are currently used as more film packaging materials, but the existing PVC heat-shrinkable films do not conform to environmental protection. Therefore, PET heat-shrinkable films are gradually Became popular, PET heat-shrinkable film is a new type of heat-shrinkable packaging material, because it is easy to recycle, non-toxic, tasteless, good mechanical properties, especially in line with environmental protection, polyester (PET) has become a substitute in developed countries An ideal substitute for polyvinyl chloride (PVC) heat-shrinkable film, because the shrinkable film is often suitable for outdoor use, and the UV resistance of the PET heat-shrinkable film currently on the market is not good, after long-term ultraviolet radiation, it will cause PET heat-shrinkable film The performance of the heat shrinkable film is greatly reduced, reducing the life of the PET heat shrinkable film

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] An anti-ultraviolet PET heat-shrinkable film, the anti-ultraviolet PET heat-shrinkable film contains 7.52% of its mass butyl glucoside modified mullite, and the butyl glucoside modified mullite is doped with Its mass is 1.23% maleic acid modified nano-graphene.

[0022] Further, the preparation method of the butyl glucoside modified mullite is:

[0023] (1) Synthesis of butyl glucoside: Dried glucose, mixed with n-butanol, added to the reaction kettle, stirred at 1500r / min for 23min, and then dripped concentrated sulfuric acid at a rate of 0.02mL / 2s Add it to the reaction kettle, keep stirring at 1500r / min, heat to 100°C, react for 8 hours, use Fehling's reagent to detect the end of the reaction, after the reaction is over, add potassium hydroxide solution to neutralize the excess concentrated sulfuric acid, and distill under reduced pressure Remove n-butanol, obtain reaction product butyl glucoside; Wherein, the mol ratio of n-butanol and glucose is 3.5:1.2;

[0024]...

Embodiment 2

[0033] An anti-ultraviolet PET heat-shrinkable film, the anti-ultraviolet PET heat-shrinkable film contains 7.68% of its mass butyl glucoside modified mullite, and the butyl glucoside modified mullite is doped with Its quality is 1.26% maleic acid modified nano-graphene.

[0034] Further, the preparation method of the butyl glucoside modified mullite is:

[0035] (1) Synthesis of butyl glucoside: Dried glucose, mixed with n-butanol, added to the reaction kettle, stirred at 1500r / min for 23min, and then dripped concentrated sulfuric acid at a rate of 0.02mL / 2s Add it to the reaction kettle, keep stirring at 1500r / min, heat to 100°C, react for 8 hours, use Fehling's reagent to detect the end of the reaction, after the reaction is over, add potassium hydroxide solution to neutralize the excess concentrated sulfuric acid, and distill under reduced pressure Remove n-butanol, obtain reaction product butyl glucoside; Wherein, the mol ratio of n-butanol and glucose is 3.5:1.2;

[00...

Embodiment 3

[0045] An anti-ultraviolet PET heat-shrinkable film, the anti-ultraviolet PET heat-shrinkable film contains 7.55% of its mass butyl glucoside modified mullite, and the butyl glucoside modified mullite is doped with Its quality is 1.24% maleic acid modified nano-graphene.

[0046] Further, the preparation method of the butyl glucoside modified mullite is:

[0047] (1) Synthesis of butyl glucoside: Dried glucose, mixed with n-butanol, added to the reaction kettle, stirred at 1500r / min for 23min, and then dripped concentrated sulfuric acid at a rate of 0.02mL / 2s Add it to the reaction kettle, keep stirring at 1500r / min, heat to 100°C, react for 8 hours, use Fehling's reagent to detect the end of the reaction, after the reaction is over, add potassium hydroxide solution to neutralize the excess concentrated sulfuric acid, and distill under reduced pressure Remove n-butanol, obtain reaction product butyl glucoside; Wherein, the mol ratio of n-butanol and glucose is 3.5:1.2;

[00...

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Abstract

The invention discloses an anti-ultraviolet PET (Polyethylene Terephthalate) thermal shrinkage film and relates to the technical field of novel materials. The anti-ultraviolet PET thermal shrinkage film contains butyl glucoside modified mullite having the mass fraction of 7.52-7.68%, wherein the maleic acid modified nano graphene having the mass fraction of 1.23-1.26% is doped in the butyl glucoside modified mullite. The PET thermal shrinkage film prepared according to the invention has excellent mechanical property, ultraviolet resistance and excellent barrier property.

Description

technical field [0001] The invention belongs to the technical field of film capacitors, and in particular relates to an ultraviolet-resistant PET heat-shrinkable film. Background technique [0002] Heat shrinkable film is used for sales and transportation of various products, and its main function is to stabilize, cover and protect products. The shrink film must have high puncture resistance, good shrinkage and certain shrinkage stress. During shrinkage, the film must not develop holes. [0003] Among the heat-shrinkable films produced in the prior art, PVC heat-shrinkable films are widely used and are currently used as more film packaging materials, but the existing PVC heat-shrinkable films do not conform to environmental protection. Therefore, PET heat-shrinkable films are gradually Became popular, PET heat-shrinkable film is a new type of heat-shrinkable packaging material, because it is easy to recycle, non-toxic, tasteless, good mechanical properties, especially in l...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L29/04C08K9/04C08K3/36C08K3/22C08K3/04C08J5/18
CPCC08J5/18C08J2367/02C08J2429/04C08K3/042C08K3/36C08K9/04C08K2003/2227C08K2201/011
Inventor 郭坤
Owner 马鞍山卓凡新材料科技有限公司
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