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Purification method of sulfur-containing tail gas of high-temperature furnace

A high-temperature furnace and tail gas technology, which is applied in chemical instruments and methods, separation methods, and dispersed particle separation, etc., can solve the problems of excessive sulfur oxide content, cure the symptoms but not the root cause, and increase the height of the chimney. The effect of low personnel requirements

Inactive Publication Date: 2019-01-18
辽宁新瑞碳材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, during the production of expanded graphite, the expansion furnace produces excessive (even much higher than the national emission standards) sulfur oxides. Most expanded graphite manufacturers discharge the tail gas generated by the expansion furnace directly into the atmosphere, and the sulfur oxides will Pollution to the atmosphere near the factory. In order to reduce the pollution to the surrounding air environment, only a few enterprises have adopted heightening treatment for the tail gas discharged from the expansion furnace (over 15m in height). In essence, it really solves the problem that the content of sulfur oxide exceeds the standard

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] When the processing capacity of expandable graphite is 39.0kg / h, the measured gas discharged from the top of the solid-gas separation system contains 4.5mg / L of sulfur dioxide, which is produced after the acid-base neutralization reaction in the calcium hydroxide reactor. Ca(HSO 3 ) 2 The amount of sulfur dioxide in the gas is 20.1kg / h, and the content of sulfur dioxide in the gas is 2.5mg / L. After the reaction with sodium hydroxide lye in the sodium hydroxide reaction tower, the product NaHSO 3 The amount of sulfur dioxide is 22.0kg / h, and the final gas discharged by the fan has a sulfur dioxide concentration of 0.10mg / L.

Embodiment 2

[0048] When the processing capacity of expandable graphite is 27.8kg / h, the measured gas discharged from the top of the solid-gas separation system contains 3.2mg / L of sulfur dioxide, which is produced after the acid-base neutralization reaction in the calcium hydroxide reactor Ca(HSO 3 ) 2 The amount of sulfur dioxide in the gas is 14.3kg / h, and the content of sulfur dioxide in the gas is 1.5mg / L. After the reaction with sodium hydroxide lye in the sodium hydroxide reaction tower, the product NaHSO 3 The amount of sulfur dioxide is 13.2kg / h, and the final gas discharged by the fan has a sulfur dioxide concentration of 0.08mg / L.

Embodiment 3

[0050] When the processing capacity of expandable graphite is 53.0kg / h, the measured gas discharged from the top of the solid-gas separation system contains 6.1mg / L of sulfur dioxide, which is produced after the acid-base neutralization reaction in the calcium hydroxide reactor. Ca(HSO 3 ) 2 The amount of sulfur dioxide in the gas is 27.2kg / h, and the content of sulfur dioxide in the gas is 3.1mg / L. After the reaction with sodium hydroxide lye in the sodium hydroxide reaction tower, the product NaHSO 3 The amount of sulfur dioxide is 25.3kg / h, and the final gas discharged by the fan has a sulfur dioxide concentration of 0.13mg / L.

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Abstract

The invention discloses a purification method of sulfur-containing tail gas of a high-temperature furnace. The purification method comprises the following steps: a, introducing the sulfur-containing tail gas discharged from the high-temperature furnace into a first-grade purification system; neutralizing sulfur dioxide in the sulfur-containing tail gas in the first-grade purification system and removing the sulfur dioxide from the tail gas to obtain first-grade purified gas; b, introducing the first-grade purified gas into a second-grade purification system through a gas conveying pipe; neutralizing residual sulfur dioxide in the first-grade purified gas in the second-grade purification system and removing the sulfur dioxide from the tail gas to obtain second-grade purified gas; discharging the second-grade purified gas into the atmosphere through a draught fan. According to the purification method of the sulfur-containing tail gas of the high-temperature furnace, disclosed by the invention, the sulfur-containing tail gas is subjected to two times of purification by utilizing a system, and the effect of purifying the tail gas is good; the problem that the content of sulfur oxide inthe tail gas in a graphite purification process exceeds the standards can be radically solved, and the pollution to the atmosphere is reduced; the preparation method can help to establish an environment-friendly factory.

Description

technical field [0001] The invention relates to the field of environmental protection, in particular to a purification system for sulfur-containing tail gas of a high-temperature furnace. Background technique [0002] At present, during the production of expanded graphite, the expansion furnace produces excessive (even much higher than the national emission standards) sulfur oxides. Most expanded graphite manufacturers discharge the tail gas generated by the expansion furnace directly into the atmosphere, and the sulfur oxides will Pollution to the atmosphere near the factory. In order to reduce the pollution to the surrounding air environment, only a few enterprises have adopted heightening treatment for the tail gas discharged from the expansion furnace (over 15m in height). In essence, it really solves the problem that the content of sulfur oxide exceeds the standard. [0003] Therefore, it is an urgent technical problem in this field to provide a method for purifying su...

Claims

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Application Information

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IPC IPC(8): B01D53/78B01D53/50
CPCB01D53/502B01D53/78B01D2251/304B01D2251/404
Inventor 孙飞田金星罗立群
Owner 辽宁新瑞碳材料科技有限公司
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