Preparation method of zinc oxide-active carbon composite catalysts
A technology of composite catalyst and activated carbon, which is applied in the field of materials, can solve the problems of unsatisfactory photocatalytic effect of composite catalyst and achieve good photocatalytic effect and good application prospect
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[0021] The invention discloses a preparation method of a zinc oxide-activated carbon composite catalyst, comprising:
[0022] (1) Pretreatment of activated carbon: soak activated carbon in inorganic acid solution for 12-24 hours, filter, wash with deionized water until neutral, then soak in inorganic alkali solution for 12-24 hours, filter, wash with deionized water until neutral, dry, Obtain pretreated activated carbon;
[0023] (2) adding the above-mentioned pretreated activated carbon into deionized water, and ultrasonically dispersing for 6-8 hours to obtain activated carbon suspension;
[0024] (3) Add carbonate solution to the above activated carbon suspension, stir for 15 to 30 minutes, then add zinc salt solution, stir for 3 to 5 hours, filter with suction, dry, and calcinate at 280 to 400°C for 1 to 2 hours to obtain Zinc-activated carbon composite catalyst.
[0025] In the above step (1), the inorganic acid solution is selected from one of hydrochloric acid solutio...
Embodiment 1
[0030] Soak activated carbon in inorganic acid solution for 12 hours, filter, wash with deionized water until neutral, then soak in inorganic alkali solution for 12 hours, filter, wash with deionized water until neutral, and dry to obtain pretreated activated carbon;
[0031] Add the above-mentioned pretreated activated carbon into deionized water, and ultrasonically disperse for 6 hours to obtain an activated carbon suspension;
[0032] Add carbonate solution to the activated carbon suspension, stir for 15-30 minutes, then add zinc salt solution, stir for 3 hours, filter with suction, dry, and calcinate at 280°C for 1 hour to obtain a zinc oxide-activated carbon composite catalyst.
[0033] In this example, in the zinc oxide-activated carbon composite catalyst prepared according to the above method, the mass ratio of zinc oxide to activated carbon is 1:10, and the photocatalytic efficiency of the catalyst is 80%.
Embodiment 2
[0035] Soak activated carbon in inorganic acid solution for 18 hours, filter, wash with deionized water until neutral, then soak in inorganic alkali solution for 18 hours, filter, wash with deionized water until neutral, and dry to obtain pretreated activated carbon;
[0036] Add the above-mentioned pretreated activated carbon into deionized water, and ultrasonically disperse for 7 hours to obtain an activated carbon suspension;
[0037] Add carbonate solution to the activated carbon suspension, stir for 15-30 minutes, then add zinc salt solution, stir for 4 hours, filter with suction, dry, and calcinate at 300°C for 1.5 hours to obtain a zinc oxide-activated carbon composite catalyst.
[0038] In this example, in the zinc oxide-activated carbon composite catalyst prepared according to the above method, the mass ratio of zinc oxide to activated carbon is 1:5, and the photocatalytic efficiency of the catalyst is 95%.
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