Preparation method of MXene nanofiltration membrane

A nanofiltration membrane and nanosheet technology, which is applied in the field of preparation of new MXene nanofiltration membranes, can solve the problem that MXenes do not have a two-dimensional sheet structure under etching conditions, and achieve good retention performance and increase water flux.

Active Publication Date: 2019-04-05
ZHEJIANG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, stronger energy is required in the selective etching process, and the harsh etching conditions lead to the fact that the prepared MXenes often do not have a good

Method used

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  • Preparation method of MXene nanofiltration membrane
  • Preparation method of MXene nanofiltration membrane
  • Preparation method of MXene nanofiltration membrane

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Ti 3 CNT x / CNT nanofiltration membrane preparation

[0031] Take 1g Ti 3 Al(C,N) 2 Soak the powder in 100ml of aqueous solution containing 0.5g of ammonium hydrofluoride, stir for 72h, and after centrifugal drying, take 0.1g of dried MXene powder and put it into a tube furnace for water vapor stripping. The water content of the gas is 10vol%, and the water vapor heating temperature is 500 degrees, heat treatment time is 1h. The powder after heat treatment and stripping is dried and set aside. Afterwards, take 0.2 g of purchased single-walled carbon nanotubes (Aladdin’s reagent) (2nm in diameter, 0.3-5 μm in length) and place them in 50ml of water for ultrasonic dispersion. After the dispersion is complete, add 1 g of stripped MXene powder, continue ultrasonic dispersion, and finally pass The prepared solution is suction-filtered on a ceramic substrate to form a film by suction filtration.

[0032] Membrane flux test is carried out under 0.1Mpa pressure, prepare 1...

Embodiment 2

[0034] Zr 3 C 2 T x / CNT nanofiltration membrane preparation

[0035] Take 1g Zr 3 al 3 C 2 Soak the powder in 100ml of aqueous solution containing 0.5g of ammonium hydrofluoride, stir for 72h, and after centrifugal drying, take 0.1g of dried MXene powder and put it into a tube furnace for water vapor stripping. The water content of the gas is 10vol%, and the water vapor heating temperature is 500 degrees, heat treatment time is 10h. The powder after heat treatment and stripping is dried and set aside. Afterwards, take 0.2 g of purchased single-walled carbon nanotubes (Aladdin’s reagent) (2nm in diameter, 0.3-5 μm in length) and place them in 50ml of water for ultrasonic dispersion. After the dispersion is complete, add 1 g of stripped MXene powder, continue ultrasonic dispersion, and finally pass The prepared solution is suction-filtered on a ceramic substrate to form a film by suction filtration.

[0036] Membrane flux test is carried out under 0.1Mpa pressure, prepa...

Embodiment 3

[0038] Ti 4 N 3 T x / CNT nanofiltration membrane preparation

[0039] Take 1g Ti 4 AlN 3Soak the powder in 100ml of aqueous solution containing 0.5g of ammonium hydrofluoride, stir for 72h, and after centrifugal drying, take 0.1g of dried MXene powder and put it into a tube furnace for water vapor stripping. The water content of the gas is 10vol%, and the water vapor heating temperature is 500 degrees, heat treatment time is 5h. The powder after heat treatment and stripping is dried and set aside. Afterwards, take 0.2 g of purchased single-walled carbon nanotubes (Aladdin’s reagent) (2nm in diameter, 0.3-5 μm in length) and place them in 50ml of water for ultrasonic dispersion. After the dispersion is complete, add 1 g of stripped MXene powder, continue ultrasonic dispersion, and finally pass The prepared solution is suction-filtered on a ceramic substrate to form a film by suction filtration.

[0040] Membrane flux test is carried out under 0.1Mpa pressure, prepare 1g ...

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Abstract

The invention provides a preparation method of an MXene nanofiltration membrane. A series of MAX materials is etched by adopting ammonium hydrofluoric acid to obtain an MXene blocked material, the massive MXene is decomposed into small nanosheets by virtue of a vapor striping method, then the single-wall carbon nanotube is embedded into MXene nanosheet layers by adopting a solution intercalation method, and then a novel MXene nanofiltration membrane is prepared by virtue of a vacuum suction filtration means. The MXene nanofiltration membrane obtained in the invention is high in flux and interception characteristics.

Description

(1) Technical field [0001] The invention belongs to the technical field of separation of inorganic membrane materials, and in particular relates to a preparation method of a novel MXene nanofiltration membrane. (2) Background technology [0002] 2D materials have been widely studied and discussed because of their unique electronic, mechanical, magnetic and optical properties. The most studied so far is graphene oxide (GO), an atomically thin layer built from sp2-bonded C atoms. Recently, a new family of 2D materials has been mentioned, including the emergence of pre-transition metal carbides, nitrides, and carbonitrides, becoming the latest class of 2D functional materials, called MXenes. The origin of MXenes is obtained by selectively etching the A atomic layer in the three-dimensional solid phase MAX. Now all known MAX is a layered hexagonal P63 / mmc symmetric ternary structure, and its crystal structure is M n+1 AX n , where M represents the early transition metals (su...

Claims

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Application Information

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IPC IPC(8): B01D71/02B01D67/00B01D61/00C02F1/44C02F101/30
CPCB01D61/027B01D67/0039B01D71/02C02F1/442C02F2101/308
Inventor 张国亮徐泽海
Owner ZHEJIANG UNIV OF TECH
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