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Preparation method of self-supporting semi-impregnated self-adhesive non-buckling pre-shaped fabric

A pre-shaped, self-supporting technology, applied in the field of low-cost preparation of high-performance composite materials, can solve the problems that are not conducive to the flow and infiltration of liquid resin, affect the mechanical properties of composite materials, and low in-plane mechanical properties, so as to improve the laying process , Improving the manufacturability of operation and the effect of improving toughness

Active Publication Date: 2020-12-29
AVIC BASIC TECH RES INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the RTM process also has some limitations. For example, 1) the in-plane mechanical properties of the composite materials prepared by the RTM process are generally lower than those of the autoclave process (the fiber volume fraction is generally about 60%), because the low viscosity in the RTM process The resin infiltrates the dry preform under the action of hydraulic pressure, and the fiber volume fraction of the RTM process composite material is generally controlled at about 55%, further increasing the fiber volume fraction will not be conducive to the flow infiltration of the liquid resin; 2) The traditional RTM process uses The dry fiber braid is used as a reinforcement material. During the weaving process of the fiber braid, the fiber bundles are worn, and the fiber bundles after weaving have a certain degree of buckling, which will affect the mechanical properties of the composite material, especially the fiber bundles. Dominant mechanical properties (such as longitudinal tension and longitudinal compression); 3) Composite materials, especially aerospace composite materials, generally require high impact damage resistance (composite materials have high toughness). Impregnated composite materials can be toughened by adding a high-viscosity thermoplastic toughening agent to the matrix resin to achieve high toughness of the composite material
However, the RTM molding process requires the resin to have a lower viscosity in order to improve the flow wettability of the resin to the dry fiber preform, so it is impossible to achieve high toughness of RTM composites through in-situ toughening.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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  • Preparation method of self-supporting semi-impregnated self-adhesive non-buckling pre-shaped fabric

Examples

Experimental program
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Effect test

specific Embodiment 1

[0026] High tenacity epoxy resin is used as the matrix resin of the pre-set fabric, domestic T800 12K carbon fiber is used as the reinforcing fiber of the pre-set fabric, nylon non-woven fabric is used as the connection and toughening material, and the surface density of the pre-set fabric is 201g / m 2 , the width is 300mm, and the fiber surface density is 145g / m 2 , The surface density of nylon non-woven fabric is 10g / m 2 , The surface density of the resin film is 18g / m 2 . The preparation process of self-supporting semi-impregnated self-adhesive non-buckling pre-set fabric is discussed.

[0027] (a) Preheat the high-toughness epoxy resin and put it into the glue film machine, and prepare the surface density of 18g / m under the condition of the resin viscosity of 120Pa·s 2 (accounting for 9% of the mass content of the preformed fabric) continuous resin film;

[0028](b) Calculated on the basis of 300mm width and fiber bundle yarn density of 0.45g / m, the fiber surface densit...

specific Embodiment 2

[0033] Using high-toughness bismaleimide resin as the matrix resin of the pre-set fabric, domestic T700 12K carbon fiber as the reinforcing fiber of the pre-set fabric, and polyaryletherketone non-woven fabric as the connection and toughening material, the pre-set fabric Area density 199g / m 2 , the width is 1000mm, and the fiber surface density is 133g / m 2 , Polyaryletherketone non-woven fabric surface density is 15g / m 2 , The surface density of the resin film is 18g / m 2 . The preparation process of self-supporting semi-impregnated self-adhesive non-buckling pre-set fabric is discussed.

[0034] (a) Preheat the high-toughness bismaleimide resin and put it into the film machine, and prepare the areal density of 18g / m under the condition of the resin viscosity of 100Pa·s 2 (accounting for 9% of the mass content of the preformed fabric) continuous resin film;

[0035] (b) Calculated on the basis of a width of 1000mm and a fiber bundle yarn density of 0.80g / m, the fiber surfa...

specific Embodiment 3

[0040] Cyanate resin is used as the matrix resin of the pre-set fabric, domestic M40J 12K carbon fiber is used as the reinforcing fiber of the pre-set fabric, polyimide non-woven fabric is used as the connection and toughening material, and the surface density of the pre-set fabric is 256g / m 2 , the width is 500mm, and the fiber surface density is 190g / m 2 , Polyimide non-woven fabric surface density is 10g / m 2 , The surface density of the resin film is 23g / m 2 . The preparation process of self-supporting semi-impregnated self-adhesive non-buckling pre-set fabric is discussed.

[0041] (a) Preheat the cyanate resin and put it into the film machine, and prepare the surface density of 23g / m under the condition of the resin viscosity of 140Pa·s 2 (accounting for 9% of the mass content of the preformed fabric) continuous resin film;

[0042] (b) Calculated on the basis of 500mm width and fiber bundle yarn density of 0.45g / m, the fiber surface density is 190g / m 2 , 211 shaft f...

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Abstract

The invention belongs to the technical field of low-cost preparing of high-performance composite materials, and relates to a preparing method for self-supporting half-infiltration self-adhesion non-buckling pre-sized fabric. A preparing thought for the self-supporting half-infiltration self-adhesion non-buckling pre-sized fabric is provided, high-alignment arrangement of fiber bundles is achievedthrough a yarn arranging mechanism and a tension control device arranged in a pre-impregnation compound machine, and buckling braided fabric used in the traditional RTM technology is replaced. When the pre-sized fabric is subjected to pre-impregnation, high-porosity ultra-thin non-woven fabric is guided to the surface of fiber bundle yarn, the operation manufacturability of the pre-sized fabric isimproved, and meanwhile the tenacity of the composite material can be effectively improved through the high-porosity ultra-thin non-woven fabric. Through optimization of preparing technology parameters, a high-viscosity resin glue film is distributed on the surface of the pre-sized fabric, and compared with the dry-state fiber pre-sized fabric used in the traditional RTM technology, the pavementmanufacturability of the pre-sized fabric is greatly improved.

Description

technical field [0001] The invention belongs to the technical field of low-cost preparation of high-performance composite materials, and relates to a preparation method of a self-supporting semi-impregnated self-adhesive non-buckling predetermined fabric. Background technique [0002] Advanced resin-based composite materials have the advantages of excellent specific strength, specific stiffness, fatigue resistance, stiffness design and easy realization of structure-function integrated design, etc., and their application in the aerospace field shows incomparable advantages of other materials. [0003] At present, the most important composite material forming process at home and abroad is the autoclave forming process, which is suitable for the manufacture of large-sized, relatively low-complexity skin and wall panels. Prepreg composites can guarantee a high fiber volume fraction and thus have excellent in-plane mechanical properties. Utilizing the good surface viscosity and ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C70/48B29K63/00B29K79/00B29K105/08
CPCB29C70/48B29K2049/00B29K2063/00B29K2079/08B29K2105/0809
Inventor 李伟东包建文钟翔屿李晔罗楚养张朋杨喆赵秀芬秦永乐
Owner AVIC BASIC TECH RES INST
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