Frankliniella occidentalis attractant composition
A technology of Western flower thrips and a composition, which is applied in the field of attractant compositions for Western flower thrips, can solve problems such as less than ideal control effect, insect resistance, unstable control effect, etc., and achieves suitable popularization and promotion, The effect of strong autonomy and flexible use
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Embodiment 1
[0017] The preparation of embodiment 1 (R)-lavender acetate
Embodiment 3
[0018] The aggregation pheromone component (R)-lavender acetate, marmosetyl (S)-methylbutyrate and plant volatile component trans-2-hexenal used in Example 3 were tested Laboratory synthesis, α-pinene was purchased from Beijing Coupling Technology Co., Ltd., and benzaldehyde was purchased from Hefei Tianjian Chemical Co., Ltd. The compounds of the present invention can be synthesized by the following routes.
[0019] Dissolve 2.00g (12.97mmol) of 5-methyl-2-(1-methylvinyl)-4-hexen-1-ol in 27mL of anhydrous dichloromethane, add 1.97g (19.46mmol) of triethyl Use an amine as an acid-binding agent. Under ice-salt bath conditions, keep the temperature at about 0°C, slowly add 1.22g (15.56mmol) of acetyl chloride in dichloromethane solution dropwise, and react for 30 minutes, then slowly rise to room temperature to continue the reaction. TLC monitored that the starting material no longer decreased. Quench the reaction with deionized water, keep the organic phase in layers, wash wi...
Embodiment 2
[0020] Example 2 Preparation of Marmosetyl (S)-Methyl Butyrate
[0021] Dissolve 2.00g (12.97mmol) (Z)-3,7-dimethyl-2,6-octadiene-1-ol in 27mL of anhydrous dichloromethane, add 3.94g (38.91mmol) triethyl Amines were used as acid-binding agents, using 4-lutidine as a catalyst, and under ice-salt bath conditions, the temperature was maintained at about 0°C, and 3.62g (19.46mmol) (S)-(+)-2- The dichloromethane solution of methyl butyric anhydride, after reacting for 30min, was slowly raised to room temperature to continue the reaction, and was monitored by TLC until the raw material no longer decreased. Quench the reaction with deionized water, keep the organic phase in layers, wash with saturated brine (10mL×3) to remove water-soluble aggregated impurities, dry with anhydrous magnesium sulfate for 1 h, filter with a vacuum pump, and then remove the filtrate by rotary evaporation under reduced pressure. dichloromethane, column separation to obtain yellow oil 2.64g (12.97mmol), y...
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