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67 results about "Trans-2-hexenal" patented technology

Trans-2-hexenal; from MeSH. Depositor-Supplied Synonyms. Chemical names and identifiers provided by individual data contributors and associated to PubChem Substance records. Synonyms of Substances corresponding to a PubChem Compound record are combined.

Method for synthesizing trans-2-hexenal

ActiveCN108752177AHigh yieldThe physical and chemical properties have not changedOrganic chemistry methodsPreparation from heterocyclic compoundsDistillationBoiling point
The invention discloses a method for synthesizing trans-2-hexenal. The method includes steps of (1), adding acidic ionic liquid into reaction flasks, completely dropwise adding vinyl ethyl ether and butyraldehyde mixed liquid into the reaction flasks at the temperatures of 0-25 DEG C, then heating systems until the temperatures of the systems reach 20-45 DEG C, carrying out stirring reaction for 1-6 hours, and carrying out reduced pressure distillation after the reaction is completely carried out so as to obtain cyclization intermediates A; adding dilute sulfuric acid aqueous solution and theintermediates A into reaction flasks, erecting reflux oil and water layering devices, carrying out heating normal-pressure distillation for 4-48 hours, and extracting upper oil layers into oil layer receiving flasks; (3), rectifying and purifying hexenal crude products, carrying out normal-pressure rectification to obtain substances with low boiling points and then carrying out reduced pressure rectification to obtain the trans-2-hexenal. A molar ratio of butyraldehyde to vinyl ethyl ether is 2:1-5:1, and the usage of the acidic ionic liquid accounts for 0.1-5% of the total weight of the vinylethyl ether; the acidic ionic liquid is [(CH2)3SO3HMIM][HSO4] or [(CH2)3SO3HMIM][CF3SO3]. The oil layers are the hexenal crude products; the mass concentration of the dilute sulfuric acid aqueous solution is 0.5-25%, and a weight ratio of the dilute sulfuric acid aqueous solution to the intermediates A is 0.2:1-2:1. The method has the advantages of environmental protection, low cost and high yield.
Owner:JIANGSU YANGNONG CHEM GROUP +2
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