Thermolysis method and thermolysis system of waste lithium ion battery
A technology for lithium-ion batteries and waste, which is applied in the field of pyrolysis methods and systems for waste lithium-ion batteries, and can solve the problems that organic solvents cannot be degraded or adsorbed
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Embodiment 1
[0057] use figure 1 and 2 The process and device in the treatment of waste ternary lithium-ion batteries:
[0058] Put the waste ternary lithium-ion battery into 2mol / L NaCl solution and discharge for 24h, and take out the battery to dry after discharge. Freeze the dried battery in a -80°C deep freezer for 3 hours to reduce the activity of its electrolyte. Take out the frozen battery, cut open the outer packaging shell of the battery under the protection of nitrogen gas, and take out the battery cell. Put 300g of battery cells into a tube furnace, raise the temperature to 650°C at a rate of 10°C / min under a nitrogen protection atmosphere of 0.8L / min, keep it warm for 3 hours, and then cool it down to room temperature naturally. The gas outlet of the tube furnace is connected to the activated carbon adsorption device and the alkali absorption device. The mass of activated carbon is 100g, and 2L of sodium hydroxide solution with a concentration of 2mol / L is installed in the a...
Embodiment 2
[0062] use figure 1 and 2 The process and device in the treatment of waste ternary lithium-ion batteries:
[0063] Put the waste ternary lithium-ion battery into 4mol / L NaCl solution and discharge it for 24h, and take out the battery to dry after discharge. Freeze the dried battery in a -60°C deep freezer for 8 hours to reduce the activity of its electrolyte. Take out the frozen battery, cut open the outer packaging shell of the battery under the protection of nitrogen gas, and take out the battery cell. Put 300g of battery cells into a tube furnace, raise the temperature to 600°C at a rate of 5°C / min under a nitrogen protection atmosphere of 1L / min, keep it warm for 5 hours, and then cool it down to room temperature naturally. The gas outlet of the tube furnace is connected to the activated carbon adsorption device and the alkali absorption device. The mass of activated carbon is 200g, and 2L of sodium hydroxide solution with a concentration of 4mol / L is installed in the alk...
Embodiment 3
[0067] use figure 1 and 2 The process and device in the treatment of waste ternary lithium-ion batteries:
[0068] Put the waste ternary lithium-ion battery into 1mol / L NaCl solution and discharge it for 24h, and take out the battery to dry after discharge. Freeze the dried battery in a -20°C deep freezer for 8 hours to reduce the activity of its electrolyte. Take out the frozen battery, cut open the outer packaging shell of the battery under the protection of nitrogen gas, and take out the battery cell. Put 300g of battery cells into a tube furnace, raise the temperature to 650°C at a rate of 20°C / min under a 0.2L / min nitrogen protective atmosphere, keep it warm for 1 hour, and then cool it down to room temperature naturally. The gas outlet of the tube furnace is connected to the activated carbon adsorption device and the alkali absorption device. The mass of activated carbon is 600g, and 2L of NaHCO with a concentration of 5mol / L is installed in the alkali absorption devi...
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Abstract
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