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A short process, no water consumption and release paper saving water-based synthetic leather manufacturing method

A manufacturing method and technology of release paper, applied in textiles and papermaking, etc., can solve the problems of low peel strength, low production efficiency, large loss of release paper, etc., to improve market competitiveness, reduce manufacturing process, The effect of improving production efficiency

Active Publication Date: 2021-07-27
SICHUAN UNIV
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  • Application Information

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Problems solved by technology

However, this requires a large amount of water to be consumed during the coagulation process. According to statistics, about 35 tons of coagulation water is required for every 10,000 meters of wet-process synthetic leather; and the post-treatment of salt and acid in wastewater is difficult, which pushes up production costs; at the same time, this High process energy consumption and low production efficiency (production efficiency is 6-10 m / min)
[0004] Another patent document CN107059420A discloses a water-based polyurethane dry foaming process to produce garment leather. The method is to use release paper as a carrier and transfer coating to manufacture water-based foamed garment leather. First, the surface layer of water-based polyurethane surface layer slurry The material is coated on the release paper, and after drying, the foam layer is coated and scraped. Finally, the dried and shaped foam layer is bonded to the base fabric through the water-based adhesive layer and dried, and the release paper is recycled to obtain a fully water-based foam garment. leather, the process steps are as image 3 As shown in a; although this production process replaces traditional solvent-based water-based polyurethane with water-based polyurethane, and eliminates the pollution of organic solvents from the source, the high-temperature drying in the production process causes a large loss of release paper, and the price of release paper is high. The price is as high as 50 yuan / square meter, which seriously pushes up the production cost; and it adopts the production process of release paper transfer coating, the process is complicated and cumbersome, and the production efficiency is not high
[0005] The Chinese invention patent with the application number CN105239417A discloses a formula and process for the production of superfiber synthetic leather by water-based polyurethane foam finishing. Finally, complex finishing steps such as skin grinding, embossing, and lamination of the surface layer and the foamed bass by using release paper as a carrier to obtain water-based polyurethane microfiber synthetic leather. Although this process is completely water-based and meets environmental protection requirements, its follow-up Still use the release paper to transfer the surface layer, the loss of the release paper is large, and it is directly coated with the foam coating, the foam coating has a high viscosity, the slurry is not easy to penetrate into the microfiber base cloth, and the foam coating is bonded to the substrate Not strong, low peel strength, difficult to meet the high peel strength requirements of shoe upper leather, sofa leather, automobile leather, ball leather, etc.

Method used

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  • A short process, no water consumption and release paper saving water-based synthetic leather manufacturing method
  • A short process, no water consumption and release paper saving water-based synthetic leather manufacturing method
  • A short process, no water consumption and release paper saving water-based synthetic leather manufacturing method

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Embodiment 1

[0032] (1) Preparation of water-based polyurethane back cover slurry, high-solid water-based polyurethane foam slurry, and surface layer slurry, in parts by weight

[0033] a) Preparation of back cover slurry: Mix 100 parts of N-methyldiethanolamine (N-MDEA) cationic waterborne polyurethane with a solid content of 50% and 0.5 part of thickener evenly to obtain a back cover slurry with a viscosity of 3000 Pa•s material;

[0034]b) Preparation of foaming slurry: 100 parts of anionic polyether type aliphatic waterborne polyurethane with a solid content of 60%, 0.3 parts of thickener, 2 parts of foam stabilizer, 0.3 parts of leveling agent, 1 part Anionic water-based color paste, 2 parts of water-based crosslinking agent, and 5 parts of filler are mixed evenly, and the foam slurry is made into a foam slurry through an intelligent dynamic generator to obtain a foam slurry with a foaming ratio of 1 to 3 times and a viscosity of 7000Pa•s ;

[0035] c) Preparation of surface layer s...

Embodiment 2

[0043] (1) Preparation of water-based polyurethane back cover slurry, high-solid water-based polyurethane foam slurry, and surface layer slurry, in parts by weight

[0044] a) Preparation of back cover slurry: 100 parts of N-methyldiethanolamine (N-MDEA) cationic waterborne polyurethane and N-propyldiethanolamine (N-BDEA) cationic waterborne polyurethane with a solid content of 35%, 1 Mix one part thickener evenly to obtain a back cover slurry with a viscosity of 4000Pa•s;

[0045] b) Preparation of foaming slurry: 100 parts of anionic polyether type and polycarbonate type aliphatic waterborne polyurethane with a solid content of 55%, 2 parts of thickener, 3 parts of foam stabilizer, 1 part of leveling agent, 3 parts of non-ionic water-based color paste, 3 parts of water-based crosslinking agent, and 10 parts of filler are mixed evenly, and the foam slurry is made into a foam slurry through an intelligent dynamic generator to obtain a foam with a foaming ratio of 2 times and a...

Embodiment 3

[0054] (1) Preparation of water-based polyurethane back cover slurry, high-solid water-based polyurethane foam slurry, and surface layer slurry, in parts by weight

[0055] a) Preparation of back cover slurry: Mix 100 parts of N-ethyldiethanolamine (N-PDEA) cationic waterborne polyurethane with a solid content of 50% and 2 parts of thickener evenly to obtain a back cover slurry with a viscosity of 6000 Pa s material;

[0056] b) Preparation of foaming slurry: 100 parts of anionic polycarbonate aromatic waterborne polyurethane with a solid content of 50%, 3 parts of thickener, 5 parts of foam stabilizer, 1.7 parts of leveling agent, 5 parts of anion and Mix non-ionic water-based color paste, 5 parts of water-based cross-linking agent, and 20 parts of filler evenly, and make a foam slurry through an intelligent dynamic generator to obtain a foaming slurry with a foaming ratio of 3 times and a viscosity of 9000 Pa·s;

[0057] c) Preparation of surface layer slurry: 100 parts of ...

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Abstract

The invention discloses a short process, no water consumption and release paper-saving water-based synthetic leather manufacturing method, the method is characterized in that the foam coating and surface layer are directly coated on the back cover to produce water-based foam Synthetic leather. The synthetic leather produced by this method has a porous structure, which improves the air and moisture permeability of water-based polyurethane synthetic leather (as shown in Figure 1). At the same time, the specific peel strength of the finished leather is greatly improved due to the special back cover technology. Compared with the water-based wet coagulation process, the process of coagulation, washing and salty wastewater treatment is omitted, which has the effect of saving water, reducing emissions, and reducing the amount of the process; Type paper resources and the entire manufacturing process is short, so its production technology is a short process, no water consumption, zero pollution, release paper-saving water-based synthetic leather manufacturing technology, and has broad application prospects.

Description

technical field [0001] The invention belongs to the field of synthetic leather manufacture, and in particular relates to a short process, no water consumption and release paper-saving water-based synthetic leather manufacturing method. Background technique [0002] After decades of development, my country's synthetic leather industry has grown from scratch to today's big production and consumption country. Since the early synthetic leather used solvent-based polyurethane, its solvent pollution has gradually attracted attention from all walks of life. Therefore, in recent years, it is the general trend to gradually adopt water-based polyurethane instead of solvent-based polyurethane to produce synthetic leather. Although water-based polyurethane synthetic leather is more environmentally friendly than solvent-based polyurethane synthetic leather, its hygienic performance is not as good as that of natural leather, and its comfort needs to be improved. Therefore, how to increase...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D06N3/14D06N3/00
Inventor 范浩军叶留留向均陈意颜俊王忠辉
Owner SICHUAN UNIV
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