Synthetic method of petrosiols A-E and pharmaceutical potential thereof
A technology for drugs and compounds, applied in the field of chemistry and medicine, can solve the problems of low penetration of the blood-brain barrier and limited wide application.
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[0024] 1. All biological experiments are operated according to standardized and known procedures. Experimental model mice are purchased and raised from qualified animal rooms. All relevant parameters are completed in the Toxicology Laboratory of the Eco-Environmental Research Center of the Chinese Academy of Sciences. .
[0025] 2. The idea of divergent synthesis is as shown in formula 1. The synthesis of Petrosiol E is taken as an example below to specifically illustrate the new method for preparing the compound. Other Petrosiols compounds can be completed by personnel with professional knowledge with reference to the method disclosed in the present invention.
[0026]
[0027] 1. Provide the following examples of the present invention (taking the above compound Petrosiol E as an example):
[0028] Synthesis of Compound 18:
[0029] 0°C, under nitrogen protection, dissolve 10-bromodecyl alcohol (1eqv) and catalytic amount of cuprous chloride in dry tetrahydrofuran, add ...
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