531 results about "Alpha-naphthol" patented technology

A pattern is formed by applying a first positive resist composition onto a substrate, heat treatment, exposure, heat treatment and development to form a first resist pattern, the first positive resist composition comprising a polymer having copolymerized recurring units having naphthol and recurring units with an alkaline solubility that increases under the action of acid; causing the first resist coating to crosslink and cure by irradiation of high-energy radiation of sub-200 nm wavelength; further applying a second positive resist composition onto the substrate, heat treatment, exposure, heat treatment and development to form a second resist pattern. The double patterning process reduces the pitch between patterns to one half.

The invention belongs to recovery treatment on lead plaster of a waste lead-acid storage battery. The method comprises the following steps of: mixing the lead plaster of the waste lead-acid storage battery with waste sulfuric acid in the waste lead-acid storage battery according to the design requirement and roasting; adding roasting sand in a stirring kettle; adding tap water to a water level line of the device and stirring the roasting sand; adding a proper amount of calcium acetate, acetic acid and nitric acid; starting a solution circulating system pump, leaching out the roasting sand and maintaining the concentration of lead acetate to be saturated; adding a proper amount of bone glue and beta-naphthol, electrolyzing immersion liquid, recovering the metallic lead at the cathode and recovering lead dioxide at the anode; press filtering residues to obtain lead-off slag and filtrate; and adding calcium carbonate in the filtrate and recycling. The device mainly comprises a leaching part, a press filtration part, a circulating part and an electrolysis part, and concretely includes eight key components of the stirring kettle, a press filter, an overflow port, an electrolysis direct current power supply, an electrolytic cell, a cathode titanium basket, a corrosion resistant pump and a heating element.

The invention refers to the synthesizing method of 5-ethylene-2-norborene. The mol ratio of the butadiene and cyclopentadiene is 1-2:1. The invention chooses toluene or normal hexane as the solvent and the weight ratio of the reactants added to the solvent is between 20% and 30%. It chooses alpha-naphthol as the inhibitor and its dosage is between 50ppm and 3000ppm of the reactants. We put the material into the reaction kettle, increase the temperature when or after whisking and make them reacting for between 0.25 hour and 4 hours at the temperature of between 130deg.C and 160deg.C and at the pressure of between 1MPa and 8MPa. Or after being mixed we put the material into the reaction kettle or the tubular reactor and stay for between 0.25 hour and 1.0 hour at the temperature of between 130deg.C and 160deg.C and at the pressure of 1.8MPa. The weight ration of the dicyclopentadiene in the material of cyclopentadiene is less than between 5% and 8%. The invention obviously increases the yield of the turnoff by over 5mol%.

The invention discloses a reduced graphene oxide @ZIF-8 composite-film-modified electrode, a preparing method thereof and application of the electrode in simultaneously detecting naphthol isomers. According to the preparing method, a 2-methylimidazole solution is added into a reaction tube containing a graphene oxide agar gel matrix, a natural diffusion and penetration method is adopted for preparing a graphene oxide @ZIF-8 nano-compound, then a sample is divided into three layers according to the diffusion depth, afterwards, thermal reduction is conducted to prepare a reduced graphene oxide @ZIF-8 nano-compound, and then the corresponding modified electrode is prepared. The obtained modified electrode has the advantages of large effective area, many active sites, good dispersity and the like. Reduced graphene oxide and ZIF-8 overcome mutual defects, the synergistic effects of the reduced graphene oxide and ZIF-8 in the aspect of improving direct electrochemistry and electro-catalyticperformance are achieved, and the conductivity and catalytic performance of the modified electrode are improved. The obtained modified electrode simultaneously detects the high sensitivity of the naphthol isomers and has the advantages of being low in detection limit, wide in detection range, high in response speed and the like.

The invention belongs to the field of tin chemical engineering and in particular relates to a method for preparing a stable tin methanesulfonate solution. The method comprises the steps of preparing anode and cathode sheets from refined tin, adding stabilizers into methanesulfonic acid to prepare an anolyte, adding electroplating additives into methanesulfonic acid to prepare the catholyte, shade, separating the anolyte from the catholyte by an anion separator, preparing a crude tin methanesulfonate solution by a direct current electric melting method, and concentrating the crude tin methanesulfonate solution in vacuum under the protection of inert gas to obtain the stable tin methanesulfonate solution, wherein the stabilizers are phenol, ascorbic acid or tartaric acid and the electroplating additives are phenol sulphonic acid, latex, gelatin, cresol, aloin, cresylic acid or beta-naphthol. The stable tin methanesulfonate solution prepared by the method disclosed by the invention has the characteristics of stable quality and no precipitation, is difficult to oxidize and discolor, and has the advantages of simple preparation process, low cost, environment friendliness and the like, and good popularization and application value are achieved.

The invention discloses a method for measuring the content of magnesium oxide in iron ores, relates to a detection method, and particularly relates to a method for measuring the content of magnesium oxide in depositing iron rocks and ores. The method includes adopting sodium hydroxide as a fusing agent to melt an iron ore sample in a high-temperature furnace and leading magnesium ions to enter solution after acidification by aid of nitric acid; and adding benzilic acid, ethylene glycol tetraacetic acid (EGTA) solution and triethanolamine to mask metal ions of titanium, iron, aluminum, alkaline earth and the like, generating magnesium hydroxide deposit in alkaline solution with the pH (potential of hydrogen) larger than 12, depositing to generate hydrochloric acid solute after filtering, using acid chrome blue K and naphthol green B as indicators in solution with the pH of 10, adopting ethylene diamine tetraacetic acid (EDTA) standard solution for titration, and obtaining the content of the magnesium oxide. The method has the advantages of simplicity, convenience, speediness, low cost, fine reproducibility and the like.

In accordance with the present invention, a novel aromatic prenyltransferase, Orf2 from Streptomyces sp. strain CL190, involved in naphterpin biosynthesis has been identified and the structure thereof elucidated. This prenyltransferase catalyzes the formation of a C—C bond between a prenyl group and a compound containing an aromatic nucleus, and also displays C—O bond formation activity. Numerous crystallographic structures of the prenyltransferase have been solved and refined, e.g., (1) prenyltransferase complexed with a buffer molecule (TAPS), (2) prenyltransferase as a binary complex with geranyl diphosphate (GPP) and Mg²⁺, and prenyltransferase as ternary complexes with a non-hydrolyzable substrate analogue, geranyl S-thiolodiphosphate (GSPP) and either (3) 1,6-dihydroxynaphthalene (1,6-DHN), or (4) flaviolin (i.e., 2,5,7-trihydroxy-1,4-naphthoquinone, which is the oxidized product of 1,3,6,8-tetrahydroxynaphthalene (THN)). These structures have been solved and refined to 1.5 Å, 2.25 Å, 1.95 Å and 2.02 Å, respectively. This first structure of an aromatic prenyltransferase displays an unexpected and non-canonical (β/α)-barrel architecture. The complexes with both aromatic substrates and prenyl containing substrates and analogs delineate the active site and are consistent with a proposed electrophilic mechanism of prenyl group transfer. These structures also provide a mechanistic basis for understanding prenyl chain length determination and aromatic co-substrate recognition in this structurally unique family of aromatic prenyltransferases. This structural information is useful for predicting the aromatic prenyltransferase activity of proteins.

The present invention relates to a thermosetting resin composition, wherein the resin composition comprises: (A) an epoxy resin with main chain containing naphthol structure; (B) a cyanate ester compound or/and an isocyanate ester prepolymer; (C) a poly phosphonate ester or/and phosphonate-carbonate copolymer. The thermosetting resin provided by the present invention has low dielectric constant and dielectric loss angular tangent value. The prepreg and copper-clad laminate made from the thermosetting resin composition above has excellent dielectrical properties, wet-heat resistance, flame resistance of UL94 V-0 grade and good technical processing performance.

The invention discloses a fashi citric acid rod Citrobacter farmeri SC01 and the application. The bacterium is obtained by artificial accumulation culture and separation cleansing from phenols cyanogen waste water treatment station one level aerobic pool sludge. The bacterium is preserved in china typical culture entreasure center of Wuhan University on January 7th 2008 year whose short form is CCTCC and preserving identification serial number is CCTCC NO: M208004. The fashi citric acid rod Citrobacter farmeri SC01 incorporating the invention can degrade phenyl hydrate, 2-methylphenol, m-cresol, 1-naphthyl hydroxide, 696mg/L m-cresol in 114 hours on aerobic condition, and the average degrading rate of speed ran up to 8.94mg/(L h) and the bacterium is sensitive to acheomycin, chloramphenicol, rifampicin and streptomycin, and the bacterium can be used safe and wide in harnessing and repairing wasted water and soil phenols pollution because the bacterium can not carryover drug-resistance factor spreading in aborigines bacterium when the bacterium is released into environment.

The invention provides a preparing method of mannich base. The method takes three components of aldehyde, amine, ketone or naphthol as a raw material, takes water as a solvent, and takes liquid superacid as a catalyst, the raw material, the solvent and the catalyst are reacted at normal pressure and room temperature, and then recrystallized and dried to obtain the product of mannich base. The method has the advantages of mild condition, convenient operation, environment protection, high efficiency, good selectivity, high productivity and easy realization.

The invention discloses a novel synthesizing method of dapoxetine, wherein a series of reactions are carried out on trans-cinnamaldehyde and N-carbobenzoxy hydroxylamine which serve as initiative raw materials under the action of a self-prepared catalyst (s)-alpha-alpha-diisopropyl dimethyl tert-butyl silicon oxygroup prolinol, so that an important intermediate of the dapoxetine, namely an important chiral intermediate (S)-3-amino-3-phenyl propyl alcohol (compound 4), is obtained. The invention further discloses a preparation method of capecitabine, wherein the compound serving as a raw material is methylated and protected by hydroxyl and then reacts with 1-naphthol to form a salt, so that the capecitabine is obtained. The preparation method is easy in raw material obtainment, good in stereoselectivity and high in yield, thereby being suitable for industrial production.

The present invention relates to two visual detection reagents of isothermal amplification products of nucleic acids, the two visual detection reagents are that 1-(1-hydroxy-2-naphthalene azo)-6-nitro-2-naphthol-4-sodium sulfonate or derivatives thereof (hereinafter referred to as the reagent 1) and 4-(2-pyridine azo) resorcinol sodium salt or derivatives thereof (hereinafter referred to as the reagent 2), the two visual detection reagents are used alone, at the beginning of a reaction, the reagent 1 combines with magnesium ions to become red, and the reagent 2 combines with the magnesium ions to form an orange complex, with the reaction, by-product pyrophosphate groups combines the magnesium ions to form a precipitation, the reagent 1 or loses the magnesium ions to become blue from red, the reagent 2 becomes yellow from orange, amplification reaction results can be judged by color change, detection without opening of a cover can be realized by the method, the aerosol pollution can be overcome, and the false positive problem caused by primer dimmers can be solved.

The invention relates to a 3, 3'-position binaphthyl shaft chiral phosphoramidite ligand containing biaryl group and a preparation method thereof. The preparation method comprises the following steps of: leading 3, 3'-dual-biaryl group-2, 2'-dinaphthol to react with hexagon-alkyl group phosphoramidite in organic solvent at the temperature of 0-120 DEG C according to the mol rate of 1:1, or leading 3, 3'- dual-biaryl group-2, 2'-dinaphthol to react with phosphorus trichloride and dialkyl amine in steps, and after complete reaction, the object chiral phosphoramidite ligand can be obtained through washing, extraction and separation. After going through complexation with metallic copper salt, the chiral phosphoramidite ligand can be used for catalyzing the conjugate addition reaction of zinc alkyl with alpha, beta-unsaturated carbonyl compounds, and an additional product is prepared with high yield up to 78-98% and high enantioselectivity ee value up to 80-98%.

The invention provides a plating solution formula of a lead tin plating process for electronic components and the lead tin plating process. The plating solution formula comprises the following components by mass-volume concentration: 70-120 g/L sulfuric acid (AR), 45-60 g/L stannous mono-sulphate, 0.2-0.8 g/L sodium hypophosphite, 0.5-1.5 g/L ascorbic acid, 2-6 g/L of polyethylene glycol, 1-1.5 g/L catechol, 1-1.5 g/L beta-naphthol, 3-6 g/L cerium sulfate, an 8-10 g/L OP-10 emulsifier, 10-30 g/L phenolsulfonic acid and pure water. According to the lead tin plating process, hot-melt drawing passivation treatment is adopted after tin plating. A tin plating layer of a product produced by adoption of both the formula and the production process is greatly improved in compactness, so that the tin whisker growth prevention performance, the high temperature resistance, the anti-tarnishing capability and the neutral salt spray resistance of the product are improved.

The invention discloses an azobenzene derivative, a preparation method of the azobenzene derivative, an azobenzene-based light-operated reversible adhesive and a use method of the azobenzene light-operated reversible adhesive. The molecular structure of the azobenzene derivative is shown as P1 and P2. According to the preparation method of the azobenzene derivative, an azobenzene group and 3, 4, 5-tripentoxyl benzoic acid or 3, 4, 5-tridodecyloxy benzoic acid undergo an esterification reaction with 2, 2'-dyhydroxy-1, 1'-binaphthol, so that P1 or P2 can be obtained. The azobenzene derivatives P1 and P2 are jointly adjusted to a melting point slightly higher than the room temperature by using alkyl chains and binaphthol, the liquid P1 and P2 can be spontaneously and quickly cured within 2 minutes, the cured azobenzene derivatives show excellent bonding performance, and the bonding strength can reach several MPa to meet the requirements of subsequent processes, under irradiation of greenlight, the photothermal effect of P1 and P2 causes conversion from solid to liquid, and after irradiation of green light, P1 and P2 are heated to be melted and lose the bonding performance.

The invention discloses pendant naphthalene group-containing cyclopentadienyl-iron-benzyl ferrocenium salt compounds used as photoinitiators for cationic photopolymerization, and belongs to the technical fields of organic synthesis and cationic photopolymerization. The preparation method of the compounds comprises two steps: 1, taking ferrocene and chlorobenzene as raw materials, and generating ligand exchange reaction to obtain cyclopentadienyl-iron-chlorobenzene salts under the catalysis of Lewis acid; and 2, generating nucleophilicsubstitutionreaction with corresponding naphthol compounds under alkaline environment, and introducing the pendant naphthalene group onto the benzene ligand. The compounds have good ultraviolet absorptivity and photo initiating activity, can initiate polymerization of epoxy compounds and vinyl ethers compounds, and have wide study potential and application prospect in the field of photocuring application.

The invention discloses a method for preparing (S)-N, N-dimethyl-3-(naphthol-1-oxygroup)-1- phenyl propyl group-1-amine. (S)-3-(naphthol-1-oxygroup)-1- phenyl propyl group-1-amine serves as the raw materials, and dimethyl carbonate replaces formaldehyde in the prior art to serve as a methylation reagent to prepare the (S)-N, N-dimethyl-3-(naphthol-1-oxygroup)-1- phenyl propyl group-1-amine. On the basis, the (S)-N, N-dimethyl-3-(naphthol-1-oxygroup)-1- phenyl propyl group-1-amine is dissolved in ethyl acetate to further prepare (S)-N, N-dimethyl-3-(naphthol-1-oxygroup)-1- phenyl propyl group-1-amine hydrochloride. The method reduces environment pollution without increasing the cost, simplifies reaction operations, reduces requirements on equipment and can be used in industrial production easily.

The invention discloses a sodium nitrite determination method. The method comprises the following steps: taking a water sample to be determined, standing the water sample to be determined for 30min, transferring 10.0mL of the above obtained supernatant into a 25mL colorimetric pipe through a pipet, sequentially adding 1.0mL of an aqueous potassium bromide solution, 1.0mL of an aqueous sulfanilic acid solution and 1.0mL of an aqueous hydrochloric acid solution, shaking up, and standing to obtain a solution of diazo salt of the sample to be determined; taking a 25mL volumetric flask, and adding 3mL of an aqueous sodium carbonate solution and 1.0mL of an aqueous 2-N-ethyl-5-naphthol-7-sulfonic acid solution; transferring the solution of diazo salt of the sample to be determined into the volumetric flask, adding deionized water to a certain volume, and determining the absorbance of the above obtained orange diazo compound solution at a wavelength of 480nm by using 1cm cuvette with a blank reagent as a reference; and calculating according to the curve regression equation of standard sodium nitrite to obtain the content of sodium nitrite in the sample to be determined. The determination method has the advantages of convenient operation, high sensitivity, accurate result, and small toxicity of used reagents.

The invention discloses a methyl naphthol wastewater treatment method implemented by using a PAC/PAM composite coagulant and a Fenton reagent. The method comprises the following steps: firstly, carrying out pretreatment on methyl naphthol wastewater by using PAC/PAM, wherein the concentration of PAC is 80-160mg/L, the concentration of PAM is 10-40mg/L, the pH value of a solution is 1-9, the stirring speed is 60r/min, and the stirring time is 10-50min. When the concentration of PAC is 140mg/L, the concentration of PAM is 20mg/L, the pH value is 5, and the stirring time is 30min, the CODCr (chemical oxygen demand) of wastewater is reduced from 5665-4820mg/L to 2925-2688mg/L. When the concentration of Fe<2+> is 1.0g/L, the concentration of H2O2 is 0.8g/L, and the reaction time is 120min, the final removal rate of CODCr reaches to be 89.6-92.5%. According to the treatment method disclosed by the invention, simplicity is realized, the cost is low, and the treatment effect on wastewater which is high in organic pollutant content, deep in colority and poor in biodegradability is good.

The invention relates to double-schiff-base based on naphthol, synthesis thereof and application thereof as a fluorinion sensor molecule. The invention provides the fluorinion sensor molecule, namely the double-schiff-base based on naphthol, wherein the double-schiff-base is faint yellow and almost free of fluorescence in a dimethyl sulfoxide solution; when fluorinions are added into the solution, the solution emits stronger blue fluorescence at the position of 467 nm immediately, the ultraviolet absorption spectrum of the solution has a red shift of 20 nm, and meanwhile the solution becomes deep yellow immediately; when other negative ions are added in, the fluorescence and color of the solution with the sensor molecule are not changed almost, so that the sensor molecule can identity fluorinions through single fluorescence, and the identification process cannot be disturbed by the other negative ions. Through titration experimental determination, the minimum detection line of the sensor molecule to the fluorinions can reach 1.4*10<-8> mol/L, which is far lower than the detection standard of fluorinions in drinking water, thus the double-schiff-base can be used for detecting the content of the fluorinions in the drinking water.

The invention relates to an epoxy resin with relatively lower linear thermal expansion coefficient and higher resistance to heat and humidity, which is applied to epoxy resin sealing material, laminated sheets and powder coatings, in particular to an epoxy resin of naphthol and naphthoic aldehyde and a production method thereof. An epoxy resin of naphthol and naphthoic aldehyde with the structure above is provided, in which n is equal to 1 to 6.

The invention discloses a method for determining earthy-smell substances in fish flesh, which comprises the following steps: taking fish flesh prepared by taking a cis-decahydro-1-naphthol solution asan internal standard as a sample, extracting geosmin and 2-methylisoborneol in the sample by adopting a headspace solid-phase microextraction method, and performing a determination process by adopting a gas chromatography-mass spectrometry method. A headspace solid-phase microextraction method is adopted to extract earthy-smell substances in the fish flesh, cis-decahydro-1-naphthol is taken as aninternal standard, and qualitative and quantitative determination is carried out by a gas chromatography-mass spectrometry method, so that the detection method of the geosmin and the 2-methylisoborneol in the fish flesh is established, and a detection method basis is provided for removing peculiar-smell substances in cultured aquatic products.