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Dimensionally stable acrylic alloy for 3-d printing

An acrylic, acrylic technology, applied in the direction of 3D object support structure, metal processing equipment, manufacturing tools, etc., can solve problems such as can not be practically used to prepare silk

Active Publication Date: 2019-06-28
ARKEMA FRANCE SA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Unfortunately, the inherent brittleness of acrylic polymers makes them impractical for making filaments for extrusion additive 3D printing

Method used

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  • Dimensionally stable acrylic alloy for 3-d printing
  • Dimensionally stable acrylic alloy for 3-d printing
  • Dimensionally stable acrylic alloy for 3-d printing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0086] Example 1 .Method of preparing silk material

[0087] Filabot extruders were used to produce filaments by inputting dry pellets and outputting filaments using a bench-top mini-extruder (screw length approximately 1 foot) Filabot extruder. Filabot has only one adjustable setting (extrusion temperature), using this setting and the air cooling distance (height from extruder to collection box), we were able to adjust the diameter of the filament to the desired filament diameter ( 2.75-2.9mm). Once set, the diameter of the extruded filament will be very uniform, varying within ±0.05mm of the mean. The temperature used in the examples is between 180-210°C. Lower temperatures will cause the extruder screw to stall (torque is too high), while higher temperatures will cause the filaments to stick to each other due to insufficient cooling time / distance. In a more powerful system with stronger torque and cooling lines, the processing window can be increased.

Embodiment 2

[0088] Example 2 .extrusion printing

[0089] The silk was dried overnight and placed in 2 3D printing on a desktop FDM (FFF, material extrusion) machine. Design and slicing are manipulated through the standard 3D software Cura provided by Ultimaker. Unless otherwise stated, all parts here are printed solid, with 0.8mm walls, diagonal cross-fill, 0.2mm per layer thickness, and 0.4mm nozzle diameter. In order to get the best results, the nozzle temperature is set between 230-250°C, the print bed is heated to 75°C, and the printing speed is based on the normal (50mm / s) plus 5-10% of the flow (for increasing the density of the parts ), the fan speed is 50%. No glue or adhesives are required on the glass panels. As the glass plate cools, the extrusion-printed part pops open.

Embodiment 3

[0090] Example 3 .warping test

[0091] A simple test to measure and compare the substrate warpage of various materials on a 3D printing bed (substrate warpage is critical because a part cannot print if it is not attached to the substrate, it is an indication of overall warpage , although overall warpage is more difficult to quantify).

[0092] The test consists of printing thin lines / walls of various lengths (0.8mm thick, two channels of the nozzle) of different materials on a heated glass plate (heated to the Vicat temperature of the material) and then observing, to see which materials and what The length of the part warped / detached from the glass sheet. The measured length is 2cm to 20cm, and the height is about 1cm.

[0093] Each print was then evaluated from the edge showing no warping, occasional warping (some prints warped, others not), minor warping (any detachment from the substrate), moderate warping (a few millimeters away from the substrate) , Large warpage (>...

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Abstract

The invention relates to an acrylic alloy composition that can be 3-D printed by a material extrusion additive manufacturing process, to an acrylic filament that has a very uniform diameter useful inthe extrusion additive manufacturing process, to acrylic articles made from the acrylic alloy composition by a material extrusion additive process, and to a material extrusion additive manufacturing process for producing the acrylic articles. The acrylic alloy composition is an alloy of an acrylic polymer, and a low melt viscosity polymer, such as polylactic acid. The alloy may optionally be impact modified, preferably with hard core core-shell impact modifiers.

Description

field of invention [0001] The present invention relates to acrylic alloy compositions capable of 3D printing by material extrusion additive manufacturing, to acrylic filaments with very uniform diameters that can be used in extrusion additive manufacturing, to additive manufacturing by material extrusion Acrylic articles manufactured from acrylic alloy compositions, and a material extrusion additive manufacturing method for producing acrylic articles. Acrylic alloy compositions are alloys of acrylic polymers with low melt viscosity polymers such as polylactic acid. The alloy may optionally be impact modified, preferably with a hard core-shell impact modifier. Background of the invention [0002] Advances in equipment and falling prices have made 3D printing widely used in homes, schools, and industry as an easier and often cheaper shortcut to prototyping and manufacturing customer end-use parts. Specifically, material extrusion additive manufacturing 3D printing (also know...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B33Y10/00B33Y70/00
CPCB29C64/314B29C64/118C08L33/10C08L33/12B33Y70/10C08L101/16C08L67/04B33Y10/00B33Y80/00C08K3/041C08K3/042B29C64/321B29K2033/08C08K3/346C08K3/36C08K3/40C08K7/06C08K7/14C08K2003/265C08K2003/3045C08L1/12C08L33/08C08L2207/53B33Y70/00
Inventor D·S-R·刘J·J·雷利M·A·奥巴特
Owner ARKEMA FRANCE SA