Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Nickel pyridine methylene phosphonate coordination polymer as well as preparation method and application thereof

A technology of pyridylmethylene phosphonic acid and coordination polymers, applied in organic compound/hydride/coordination complex catalysts, chemical instruments and methods, chemical/physical processes, etc., can solve the problem that photocatalysts cannot be recycled and reused and other issues, to achieve the effect of high stability and high photochemical activity

Active Publication Date: 2019-09-10
JIANGSU UNIV OF TECH
View PDF2 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In order to solve the technical problems that most photocatalysts in the prior art cannot effectively utilize the visible light in the sunlight band to catalyze and degrade pollutants and the photocatalysts cannot be recycled and reused, a nickel pyridylmethylene phosphonate coordination polymer and Its preparation method and its application in photocatalytic degradation of pollutants, especially its application in catalytic degradation of methylene blue

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Nickel pyridine methylene phosphonate coordination polymer as well as preparation method and application thereof
  • Nickel pyridine methylene phosphonate coordination polymer as well as preparation method and application thereof
  • Nickel pyridine methylene phosphonate coordination polymer as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The preparation method of the nickel pyridyl methylene phosphonate coordination polymer of the present embodiment is as follows:

[0029] Weigh 4-pyridinemethylenephosphonic acid (0.1mmol, 0.0173g) and nickel acetate (0.1mmol, 0.0249g), dissolve it in 8mL of distilled water, stir and mix evenly with ultrasonic, and measure the pH of the mixture with a pH meter to be 5.3. Put the mixed solution in a high-pressure hydrothermal kettle lined with polytetrafluoroethylene, and place the hydrothermal kettle in a closed oven at 120°C for heating reaction. After the reaction for 80 hours, naturally cool to room temperature, filter, wash, and dry to obtain Target product, marked 1. Yield 52.8%. Product 1 was characterized by PXRD, such as figure 2 As shown, the structure of the product of this example is consistent with the simulation results of theoretical values, indicating that the product is very pure.

Embodiment 2

[0031] The preparation method of the nickel pyridyl methylene phosphonate coordination polymer of the present embodiment is as follows:

[0032] Weigh 4-pyridylmethylenephosphonic acid (0.1mmol, 0.0173g) and nickel acetate (0.1mmol, 0.0249g), dissolve it in 6mL of distilled water, stir and mix evenly with ultrasonic, and measure the pH value of the mixture with a pH meter to be 5.3. The mixed solution was placed in a high-pressure hydrothermal kettle lined with polytetrafluoroethylene, and the hydrothermal kettle was placed in a closed oven at 120°C for heating reaction. After the reaction was completed for 72 hours, it was naturally cooled to room temperature, filtered, washed, and dried to obtain Target product, marked 2. Yield 50.7%. Product 2 was characterized by PXRD, such as figure 2 Shown, PXRD test result shows, the product of the present embodiment is identical with the product of embodiment 1.

Embodiment 3

[0034] The preparation method of the nickel pyridyl methylene phosphonate coordination polymer of the present embodiment is as follows:

[0035] Weigh 4-pyridinemethylenephosphonic acid (0.1mmol, 0.0173g) and nickel acetate (0.1mmol, 0.0249g), dissolve it in 10mL of distilled water, and mix well by ultrasonic stirring. The mixed solution was placed in a high-pressure hydrothermal kettle lined with polytetrafluoroethylene, and the hydrothermal kettle was placed in a closed oven at 130°C for heating reaction. After the reaction was completed for 72 hours, it was naturally cooled to room temperature, filtered, washed, and dried to obtain Target product, marked 3. Yield 45%. Product 3 was characterized by PXRD, such as figure 2 Shown, PXRD test result shows, the product of the present embodiment is identical with the product of embodiment 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to a nickel pyridine methylene phosphonate coordination polymer as well as a preparation method and application thereof. The nickel pyridine methylene phosphonate coordination polymer has a molecular formula of [Ni(4-pmp)(H2O)3]n, belongs to a monoclinic system and has P21 / c space groups, and a space accumulation structure is of a two-dimensional layered structure. The coordination polymer prepared by the method disclosed by the invention has a high photocatalytic degradation rate on methylene blue under visible light conditions, and the degradation rate is up to 71.7%; and after the methylene blue is subjected to photocatalytic degradation of 3 cycles, the structure of the coordination polymer disclosed by the invention is not changed, the coordination polymer has high stability and high photochemical activity, is basically invariable in photocatalytic effect of the methylene blue, can be recycled, meets requirements of green materials, and provides a new selection for degradation of azo dyes.

Description

technical field [0001] The invention relates to the technical field of coordination polymers, in particular to a nickel pyridylmethylene phosphonate coordination polymer and its preparation method, and its application in photocatalytic degradation of azo dyes, especially its application in catalytic degradation of methylene blue . Background technique [0002] Photocatalytic technology has attracted widespread attention because of its ability to utilize abundant solar energy to effectively degrade pollutants. At present, research in the field of photocatalysis mainly focuses on two types of photocatalytic systems. One is the heterogeneous photocatalyst of inorganic semiconductor represented by titanium dioxide. Although it has high stability and photocatalytic activity, they can only be excited by ultraviolet light. The ultraviolet region only accounts for about 5% of the entire solar spectrum, and the composition and crystal phase adjustment of inorganic semiconductors can...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08G83/00B01J31/22
CPCB01J31/1691B01J31/2217C08G83/008
Inventor 杨廷海仇丽君孙明慧王琦王欣
Owner JIANGSU UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com