Process for gasification production of synthesis gas through low temperature entrained-flow bed by using ultrafine powder

A technology of entrained bed and ultra-fine powder, which is applied in gasification process, granular/powdered fuel gasification, petroleum industry, etc. It can solve the problems of refractory material erosion and achieve the goal of reducing erosion, prolonging service life and high-efficiency gasification Effect

Inactive Publication Date: 2019-09-20
SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims at the problems that the gasification of the current entrained bed gasification furnace must be carried out under high temperature conditions and the erosion of refractory materials, etc., and proposes a new gasification method and process, which is characterized in that compared with

Method used

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  • Process for gasification production of synthesis gas through low temperature entrained-flow bed by using ultrafine powder
  • Process for gasification production of synthesis gas through low temperature entrained-flow bed by using ultrafine powder
  • Process for gasification production of synthesis gas through low temperature entrained-flow bed by using ultrafine powder

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The gasification raw material adopts coal powder with a particle size of less than 75μm.

[0029] The properties of pulverized coal, processing capacity and amount of gasification agent are shown in the table below.

[0030] The industrial analysis, element analysis and ash melting point analysis data of coal are shown in the following table:

[0031]

[0032] The main operating conditions of the gasifier are as follows:

[0033]

[0034] According to the gasification method of the present invention, gasification raw materials and gasification agents (oxygen and water vapor) are injected into the gasification furnace 1 from a burner at the top center of the entrained bed gasification furnace 1, and the gasification operation temperature of the gasification furnace 1 The temperature is controlled at 1200-1250°C and the gasification pressure is 3.0MPa; the coal gas and ash produced by the reaction flow in the downward flow process; the chilled water is sprayed, and the water volu...

Embodiment 2

[0041] The gasification raw material adopts coal powder with a particle size of less than 75μm.

[0042] The properties of pulverized coal are the same as in Example 1, and the processing capacity and the amount of gasification agent are shown in the table below.

[0043] The main operating conditions of the gasifier are as follows:

[0044]

[0045] According to the gasification method of the present invention, gasification raw materials and gasification agents (oxygen and CO 2 ) Inject from the burner at the top center of the entrained bed gasifier 1 into the gasifier 1. The gasification operation temperature of the gasifier 1 is controlled at 1200-1250°C, and the gasification pressure is 4.0MPa; the coal gas and ash produced by the reaction are combined During the downward flow; spray chilled water, adjust the water volume to control the temperature of the gas after chilling at 800-850℃.

[0046] The chilled coal gas and the ash entrained by the coal gas exit the gasifier 1 and ent...

Embodiment 3

[0052] The gasification raw material adopts coal powder with a particle size of less than 75μm.

[0053] The properties of pulverized coal are the same as in Example 1, and the processing capacity and the amount of gasification agent are shown in the table below.

[0054] The main operating conditions of the gasifier are as follows:

[0055]

[0056] According to the gasification method of the present invention, gasification raw materials and gasification agents (oxygen and water vapor) are injected into the gasification furnace 1 from the burner at the top center of the entrained bed gasification furnace 1, and the gasification operation temperature of the gasification furnace 1 The temperature is controlled at 1200-1250°C and the gasification pressure is 0.1MPa; the coal gas and ash produced by the reaction flow in the downward flow process; the chilled water is sprayed, and the water volume is adjusted to control the gas temperature after quenching at 750-800°C.

[0057] The chille...

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Abstract

The invention discloses a process for gasification production of synthesis gas through a low temperature entrained-flow bed by using ultrafine powder. The process comprises the steps: spraying an ultrafine gasified raw material which is pulverized to less than 75 [mu]m and a gasification agent into a gasification furnace from the top of the gasification furnace of the entrained-flow bed, performing a reaction on the gasified raw material and the gasification agent so as to generate the synthesis gas containing carbon monoxide and hydrogen at a gasification temperature of lower than 1300 DEG C, spraying chilled water during downward flow of the synthesis gas, and reducing the temperature of the gas so as to meet requirements for the entrance temperature of a cyclone separator, wherein the entrance temperature of the cyclone separator is generally lower than 900 DEG C; discharging the gas with ash slag from a lower outlet of the gasification furnace after cooling, introducing the gas directly into the cyclone separator, removing most of coarse particles and a part of fine ash which are carried by the gas, then introducing the obtained gas into a waste heat boiler for further cooling of the gas, generating steam at the same time, finally introducing the gas into a filter so as to remove fine dust entrained in the gas, and sending the obtained gas to a subsequent section. In the gasification process, the ash slag does not have to reach a melt flow state, and the process is particularly suitable for production processes of low-activity coal and gasification of coal with a high-ash fusion point.

Description

Technical field [0001] The invention relates to a process for producing synthesis gas by gasification of ultrafine powder in a low-temperature entrained bed, in particular to a gasification method and process for producing synthesis gas by using carbonaceous materials as raw materials. Background technique [0002] Entrained-flow gasification technology has been recognized and applied in the current coal chemical industry production of synthesis gas and hydrogen production in the refining and chemical industry. In order to ensure the smooth discharge of the remaining ash and slag after gasification during the operation of the entrained bed gasifier, and to ensure the normal flow of liquid ash and slag in the entrained bed gasifier, the gasification temperature of the entrained bed gasifier is generally higher than that of the gasification. The flow temperature of the ash remaining after the raw material has been gasified. In industrial enterprise applications, in order to achiev...

Claims

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Application Information

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IPC IPC(8): C10J3/46C10J3/84
CPCC10J3/466C10J3/84C10J2300/0906C10J2300/0909C10J2300/1687Y02P20/129
Inventor 李庆峰赵建涛房倚天李春玉黄戒介
Owner SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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