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A kind of anti-high salinity type slick water drag reducing agent and its preparation method and application

A technology of salinity and slick water, applied in chemical instruments and methods, drilling compositions, etc., can solve problems such as failure to meet the requirements of flowback fluid configuration, decrease in resistance reduction rate of drag reducing agents, etc., and achieve improved salt resistance. performance, improve stability, increase the effect of rigidity

Active Publication Date: 2022-04-12
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Laboratory test results show that the drag-reducing rate of existing drag-reducing agents in brine has dropped significantly, which cannot meet the configuration requirements of flowback fluid. Therefore, it is necessary to develop new salt-resistant drag-reducing agents to realize the reuse of unconventional fracturing flowback fluid

Method used

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  • A kind of anti-high salinity type slick water drag reducing agent and its preparation method and application
  • A kind of anti-high salinity type slick water drag reducing agent and its preparation method and application
  • A kind of anti-high salinity type slick water drag reducing agent and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Add monomer AM (acrylamide), SSS (sodium styrene sulfonate), 2-vinylpyridine and acryloylmorpholine to the flask at a molar ratio of 9:1:0.3:0.2, and press four Add initiator azobisisobutylamidine hydrochloride (V50) to 0.15wt% of the total mass of the monomer, mix with deionized water in the flask, fully disperse the monomer and initiator, then add deionized water again, Make the monomer concentration of the reaction system reach the reaction mass percentage, then pass through high-purity nitrogen to deoxygenate by bubbling for 30 minutes, raise the temperature to 40°C, react for 6h, cut the obtained gel into pieces and put it in an oven at 80°C to dry for 24h , and then the dried gel was put into a pulverizer to pulverize, and sieved to obtain 70-mesh particles, and the target product sample 1 was obtained. Wherein, based on the total weight of the mixture after mixing the four monomers, the initiator and water and adding water again, the total weight of the four mono...

Embodiment 2

[0035] In the flask, add AM, SSS, 2-vinylpyridine and acryloylmorpholine at a molar ratio of 9.5:0.5:0.3:0.2, and then add V50 according to 0.15wt% of the total mass of the four monomers. Mix the deionized water in the mixture, then add deionized water again, blow high-purity nitrogen gas to deoxygenate for 30 minutes, raise the temperature to 50°C, react for 10h, cut the obtained gel into pieces and dry it in an oven at 80°C for 24h , and then put the dried gel into a pulverizer to pulverize, and sieve to obtain 60-mesh particles to obtain the target product sample 2. Wherein, based on the total weight of the mixture after mixing the four monomers, the initiator and water and adding water again, the total weight of the four monomers is 35wt% of the total weight of the mixture, and the monomers are acrylamide, Sodium styrene sulfonate, 2-vinylpyridine and acryloylmorpholine.

Embodiment 3

[0037] In the flask, add AM, SSS, 2-vinylpyridine and acryloylmorpholine at a molar ratio of 9.8:0.2:0.3:0.2, and then add V50 at 0.15wt% of the total mass of the four monomers, and the flask Mix the deionized water in the mixture, then add deionized water again, blow high-purity nitrogen gas to deoxygenate for 30 minutes, raise the temperature to 45°C, react for 8h, cut the obtained gel into pieces and dry in an oven at 80°C for 24h , and then the dried gel was put into a pulverizer to pulverize, and sieved to obtain 65-mesh particles, and the target product sample 3 was obtained. Wherein, based on the total weight of the mixture after mixing the four monomers, the initiator and water and adding water again, the total weight of the four monomers is 35wt% of the total weight of the mixture, and the monomers are acrylamide, Sodium styrene sulfonate, 2-vinylpyridine and acryloylmorpholine.

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Abstract

The invention discloses a high-salinity-resistant slick water drag reducing agent, a preparation method and application thereof. The high salinity resistant slick water drag reducer has structural units as shown in formula I, formula II, formula III and formula IV: the high salinity resistant slick water drag reducer prepared by the present invention is It can reach the highest viscosity after dissolving in brine with a concentration as high as 111902.9mg / L for 8 minutes, and the resistance reduction rate under this salinity water can reach about 70%, and the viscosity is still high after shearing for one hour. Good shear resistance.

Description

technical field [0001] The invention belongs to the field of petroleum development, and more specifically relates to a high-salinity-resistant slick water drag reducing agent and its preparation method and application. Background technique [0002] As an unconventional energy with abundant reserves, shale gas has been widely valued by countries all over the world. As an emerging unconventional natural gas, shale gas is of great significance for optimizing the energy consumption structure and alleviating the dependence on external energy sources. Fracturing technology is one of the main technologies for shale gas exploitation at home and abroad, and drag reducer is one of the core additives of slick water fracturing fluid. [0003] Chinese patent application CN 201710357652.4 discloses a high-salt-tolerant inverse emulsion drag reducer suitable for shale reservoir fracturing, which is made of the following raw materials in mass percentages: non-ionic monomer: 30% to 45%; cati...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09K8/68C08F220/56C08F212/14C08F226/06C08F220/58
CPCC09K8/68C09K8/882C08F220/56C08F212/14C08F226/06C08F220/58
Inventor 崔佳张汝生陈瞰瞰张鹏陈秋林苏建政林鑫黄兴华田尧黄志文
Owner CHINA PETROLEUM & CHEM CORP