Flame retardant polyphenylene ether material

A polyphenylene ether and polystyrene technology, applied in the field of flame-retardant polyphenylene ether materials, can solve the problems of reducing the flame retardancy of PPO, difficulty in processing and molding, and poor melt fluidity

Inactive Publication Date: 2019-10-18
合肥邦联新材料有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Good electrical properties in a wide temperature and frequency range, the main disadvantages are poor melt fluidity, difficult processing and molding, and low stress cracking resistance
[0004] At present, the melt fluidity, processability and stress crack resistance are mainly improved by adding plastics, resins, elastomers, etc.; but with the addition of plastics, resins, elastomers, etc., the flame retardancy of PPO will be reduced

Method used

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  • Flame retardant polyphenylene ether material

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A kind of flame-retardant polyphenylene ether material, its raw material comprises by weight: 60 parts of polyphenylene ether, 34 parts of impact-resistant polystyrene, 0.4 part of antioxidant, 0.6 part of anti-dripping agent PTEE, 0.8 part of crosslinking agent , 2 parts of lubricant, 2.8 parts of compatibilizer, 7 parts of elastomer, 25 parts of flame retardant; Wherein, flame retardant is bisphenol A bis (diphenyl phosphate), polyphenylmethylsiloxane.

Embodiment 2

[0021] A flame-retardant polyphenylene ether material, the raw materials of which include by weight: 80 parts of PPO 040, 26 parts of HIPS 3441, 0.6 parts of antioxidant, 0.4 parts of anti-dripping agent PTEE, 1.2 parts of crosslinking agent, and 1.5 parts of lubricant , 3.7 parts of maleic anhydride graft compatibilizer, 5 parts of elastomer, 30 parts of flame retardant; Wherein, flame retardant is bisphenol A bis (diphenyl phosphate), polyphenylmethylsiloxane;

[0022] Among them, in the preparation process of the elastomer, the ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer and γ-methacryloxypropyltrimethoxysilane modified nano-kaolin are mixed, and the rotating speed is adjusted to 100 rpm. min, and ball milled for 9 hours to obtain an elastomer, wherein the weight ratio of ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer and modified nano-kaolin is 1:6:0.2.

Embodiment 3

[0024] A kind of flame-retardant polyphenylene ether material, its raw material comprises by weight: PPO 040 65 parts, HIPS 3441 32 parts, antioxidant 0.45 parts, anti-dripping agent PTEE 0.55 parts, crosslinking agent 0.9 parts, lubricant 1.8 parts , 3 parts of maleic anhydride graft compatibilizer, 6.5 parts of elastomer, 26 parts of flame retardant; Wherein, flame retardant is bisphenol A bis (diphenyl phosphate), polyphenylmethylsiloxane;

[0025] Wherein, in the preparation process of the elastomer, ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer and γ-methacryloxypropyl trimethoxysilane modified nano-kaolin are mixed, and the rotating speed is adjusted to 150 rpm. min, ball milling for 7h to obtain an elastomer, wherein the weight ratio of ethylene-vinyl acetate copolymer, SEBS thermoplastic elastomer and modified nano kaolin is 2:5:0.4;

[0026] The weight ratio of bisphenol A bis(diphenyl phosphate) to polyphenylmethylsiloxane is 18:10.

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PUM

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Abstract

The invention discloses a flame retardant polyphenylene ether material, which comprises the following raw materials by weight: 60-80 parts of polyphenylene ether, 26-34 parts of impact resistant polystyrene, 0.4-0.6 part of an antioxidant, 0.4-0.6 part of an anti-dripping agent PTEE, 0.8-1.2 parts of a cross-linking agent, 1.5-2 parts of a lubricant, 2.8-3.7 parts of a compatilizer, 5- 7 parts ofan elastomer and 25-30 parts of a flame retardant. Specifically, the flame retardant is bisphenol A bis(diphenyl phosphate) and polyphenylmethylsiloxane. Through the interaction of all the substances,the flame retardant polyphenylene ether material provided by the invention has good flame retardance, stress cracking resistance, melt fluidity and processability.

Description

technical field [0001] The invention relates to the technical field of plastics, in particular to a flame-retardant polyphenylene ether material. Background technique [0002] The chemical name of polyphenylene ether is poly 2,6-dimethyl-1,4-phenylene ether, referred to as PPO or PPE, also known as polyphenylene oxide or polyphenylene ether. [0003] PPO is mainly used in electronic appliances, automobiles, household appliances, office equipment and industrial machinery. PPO is non-toxic, transparent, low relative density, and has excellent mechanical strength, stress relaxation resistance, creep resistance, heat resistance, flame retardancy, water resistance, water vapor resistance, and dimensional stability. It has good electrical properties in a wide temperature and frequency range, but its main disadvantages are poor melt fluidity, difficult processing and molding, and low stress cracking resistance. [0004] At present, the melt fluidity, processability and stress cra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L71/12C08L51/04C08L23/08C08L53/02C08L83/04C08L27/18C08K13/06C08K9/06C08K3/34C08K5/523
CPCC08L71/12C08K2201/011C08L2201/02C08L2205/08C08L2205/035C08L51/04C08L23/0853C08L53/025C08L83/04C08L27/18C08K13/06C08K9/06C08K3/346C08K5/523
Inventor 孙业林高振兴郭洪武祁赫
Owner 合肥邦联新材料有限责任公司
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