Low-cost black FDM printing filament prepared by utilizing recycled tobacco film masterbatch as well as preparation method and application of printing filament

A printing filament, low-cost technology, applied in the field of materials, can solve the problems of expensive PLA type 3D printing materials, increase production time and cost, increase processing links, etc., to achieve uniform coloring effect, good coloring effect, and coloring effect without color cast Effect

Active Publication Date: 2019-11-01
KUNMING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, PLA-type 3D printing materials are still relatively expensive, and the cost of printing is high, making it difficult to popularize
In addition, the PLA masterbatch is white. In the process of use, different color masterbatches, dispersants, compatibilizers and other additives need to be added for coloring according to different market demands. In this way, not only additional processing links are required, but also greatly increased. Generate time and cost

Method used

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  • Low-cost black FDM printing filament prepared by utilizing recycled tobacco film masterbatch as well as preparation method and application of printing filament
  • Low-cost black FDM printing filament prepared by utilizing recycled tobacco film masterbatch as well as preparation method and application of printing filament
  • Low-cost black FDM printing filament prepared by utilizing recycled tobacco film masterbatch as well as preparation method and application of printing filament

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0039] The preparation method of the low-cost black FDM printing wire rod prepared by recycling cigarette film masterbatch according to the present invention comprises the following steps:

[0040] A. Dry the raw material recycled tobacco film masterbatch and polylactic acid (PLA) in a vacuum drying oven for 24 hours for later use;

[0041] B. Weigh the dried recycled cigarette film masterbatch and polylactic acid, compatibilizer, additives, and white oil according to the formula ratio, add them to the high-mixer and heat to 90~110°C, and stir at a speed of 4000~6000rpm for 30 ~50min to get material a;

[0042] C. Extrude material a through a twin-screw extruder, then cool to room temperature and send it to a pelletizer to cut to obtain material b;

[0043] D. Extrude material b through a die in a twin-screw extruder to obtain the target product.

[0044] The temperature of the twin-screw extruder described in step C is 150-210nb°C, and the rotation speed is 50-70rpm.

[00...

Embodiment 1

[0048] (1) The weight percentage formula is as follows:

[0049] Recycled tobacco film masterbatch 5

[0050] PLA 95

[0051] PE-g-MAH 2

[0052] DA-310ST 0.5

[0053] White oil 0.5

[0054] (2) Preparation method:

[0055] A. Place the recovered cigarette film masterbatch and PLA in a vacuum drying oven to dry;

[0056] B. According to the weight percentage formula, weigh the dried recycled cigarette film masterbatch, PLA, PE-g-MAH, P990, white oil;

[0057] C. Place the weighed components in a high-speed kneader, keep the speed at 2000 rpm, and stir at high speed for 20 minutes;

[0058] D. Add the uniformly mixed recycled cigarette film masterbatch, PLA, PE-g-MAH, P990, and white oil to the feed port of the twin-screw extruder. The temperature of the twin-screw extruder is 150-210°C, and the rotation speed is 70rpm; The raw material extruded from the screw is sent to the pelletizer after being cooled and cut into pellets, such as figure 1 As shown, dry and set aside...

Embodiment 2

[0063] (1) weight percentage formula is as follows:

[0064] Recycled tobacco film masterbatch 10

[0065] PLA90

[0066] POE-g-GMA 5

[0067] DA-310ST 1

[0068] white oil 1

[0069] (2) Preparation method:

[0070] A. Place the recovered cigarette film masterbatch and PLA in a vacuum drying oven to dry;

[0071] B. According to the weight percentage formula, weigh the dried recycled cigarette film masterbatch, PLA, POE-g-GMA, DA-310ST, white oil;

[0072] C. Place the weighed components in a high-speed kneader, keep the speed at 1000-6000 rpm, and stir at high speed for 5-30 minutes;

[0073] D. Add the uniformly mixed recycled cigarette film masterbatch, PLA, POE-g-GMA, DA-310ST, and white oil to the feeding port of the twin-screw extruder. The temperature of the twin-screw extruder is 150-210°C, and the speed is 150rpm; the raw material extruded from the screw is cooled and sent to the pelletizer to be cut into pellets, such as figure 1 As shown, dry and set aside;...

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Abstract

The invention discloses a low-cost black FDM printing filament prepared by utilizing recycled tobacco film masterbatch as well as a preparation method and application of the printing filament. The black FDM printing filament is prepared from the following raw materials, in parts by weight: 5-40 parts of the recycled tobacco film masterbatch, 60-95 parts of polylactic acid, 0.2-3 parts of a compatibilizer, 0.5-1 part of a toughening agent, 0.5-1.5 parts of an auxiliary agent, and 0.5-1 part of white oil. The preparation method comprises the following steps: weighing each raw material accordingto one corresponding formula ratio, adding the weighed materials into a high-speed mixing machine, and performing stirring to obtain a material a; and performing extrusion by a twin-screw extruder, performing cutting to obtain a material b, and performing extrusion through a die opening of a twin-screw extruder to obtain the target product. According to the method provided by the invention, the recycled tobacco film masterbatch low-density polyethylene (PE) in a Yunnan region and polylactic acid (PLA) are mixed to prepare the polymer filament suitable for black 3D printing, the method can finda cheap substitute for 3D printing PLA filament coloring black masterbatch, the printing filament provided by the invention has a good, uniform and non-color-cast coloring effect, and the method broadens an application range of the recycled tobacco film masterbatch, realizes green recycling of PE-based polymer materials, and provides the novel 3D printing filament.

Description

technical field [0001] The invention belongs to the technical field of materials, and in particular relates to a low-cost black FDM printing wire material prepared by using recycled cigarette film masterbatch, a preparation method and application thereof. Background technique [0002] The tobacco planting area in Yunnan Province ranks first in the country. The tobacco industry is an important economic pillar industry in Yunnan Province and has an important impact on economic growth. In order to prevent weeds and increase the ground temperature, tobacco farmers need a large amount of mulching film during the tobacco cultivation process. The average life cycle of tobacco film is 1 to 3 years, so there is a large amount of waste tobacco film in Yunnan Province every year. At present, there are many waste cigarette film recycling enterprises in Yunnan that can produce and produce more than 30,000 tons of recycled cigarette film materials each year. Compared with ordinary househo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L23/06C08L51/06C08L23/08C08L91/00B29B9/06B29C48/02B29C48/05B33Y70/00
CPCC08L67/04B29B9/06B29C48/022B29C48/05B33Y70/00C08L2207/20C08L2207/066C08L2205/035C08L23/06C08L51/06C08L23/0853C08L91/00
Inventor 吴琼王宝玲李劲东李维莉鞠海东刘空崔焱
Owner KUNMING UNIV
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