Concentration self-adaption detection device and method for total nitrogen/total phosphorus of seawater

A detection device and self-adaptive technology, applied in the measurement of color/spectral characteristics, etc., can solve the problems of the service life of consumable components, high cost, and the inability to guarantee the constant light source intensity, etc., and achieve the adjustable reference light intensity and compact structure. Effect

Inactive Publication Date: 2019-11-08
OCEANOGRAPHIC INSTR RES INST SHANDONG ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] However, this process cannot guarantee that the intensity of the light source remains unchanged. Due to factors such as environmental fluctuations, temperature changes, signal fluctuations, and unstable power supply voltage of the light source LED, the intensity of the light source will vary from time to time, which will affect the true absorbance of the sample or Nitrogen and phosphorus content, the cost of ensuring almost constant light source intensity is relatively high
However, the flow cell with fixed optical path has too small absorbance when the sample concentration is low and is difficult to measure, and when the concentration is high, the absorbance is too high and it is not easy to measure. The sample needs to be diluted, which increases the detection time and reagent consumption. consumes the service life of the component

Method used

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  • Concentration self-adaption detection device and method for total nitrogen/total phosphorus of seawater
  • Concentration self-adaption detection device and method for total nitrogen/total phosphorus of seawater
  • Concentration self-adaption detection device and method for total nitrogen/total phosphorus of seawater

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Embodiment 1

[0040] Example 1 as figure 1 As shown, the concentration adaptive seawater total nitrogen / total phosphorus detection device of the present invention is mainly composed of a first circulation path and a second circulation path. The first circulation includes a long base 11 , a first LED light source 13 , a first light splitting assembly 14 , a first photodiode 16 , a long flow cell 17 , a long pressure plate 18 , a large cover 19 and a second photodiode 20 . The second circulation path includes a short base 21 , a third photodiode 22 , a second LED light source 23 , a second light splitting assembly 24 , a fourth photodiode 25 , a short flow cell 26 , a short pressure plate 27 , and a small cover plate 28 .

[0041] The long base 11 is similar in structure to the short base 21 and has the same height, and the difference between the two is only in length. like figure 2 , 3 , 4, the long base 11 or the short base 21 is provided with a light source screw hole 111, a light sou...

Embodiment 2

[0051] Example 2 The principles and steps of the method for detecting total nitrogen / total phosphorus in seawater with an adaptive concentration of the present invention are described in detail as follows.

[0052] The principle of the method of the present invention that can eliminate the influence of light source fluctuation on the absorbance of the detected sample is as follows: Figure 12 shown. The light intensity of the LED light source is I', and the ratio of the transmittance and reflectivity of the beam splitter is 8:2 (different transmittance and reflectivity beam splitters can be customized according to actual needs, so as to achieve adjustable reference light intensity), through the beam splitter The light intensity received by the photodiode in the measurement optical path after being absorbed by the sample in the Z-type flow cell is I, and the light intensity received by the photodiode in the reference light path after being reflected by the beam splitter is I 0...

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Abstract

The invention belongs to the technical field of marine environment monitoring and relates to an online monitoring and in-situ monitoring device and method for total nitrogen/total phosphorus of seawater. The detection device comprises a first flowing channel and a second flowing channel which are connected in sequence; the first flowing channel or the second flowing channel comprises a base, a light splitting assembly, LED light sources, a photodiode and a flowing pond; the light splitting assemblies and the flowing ponds are embedded in the bases; light through holes are formed between the light splitting assemblies and the flowing ponds; the LED light sources are optically connected with the light splitting assemblies; one photodiode is vertical to the LED light sources; the other photodiode is horizontal to the LED light sources; the optical length of the flowing pond of the first flowing channel is greater than that of the flowing pond of the second flowing channel. According to the device and method, the influence of light source fluctuation caused by other factors on the defection result can be eliminated, high sample concentration or low sample concentration can be measuredat a time, and the device and method have the advantages that a high-concentration sample does not need to be diluted, the structure is relatively compact, and the reference light intensity can be adjusted.

Description

technical field [0001] The invention belongs to the technical field of marine environment monitoring, and relates to an on-line monitoring and in-situ monitoring device and method for total nitrogen and total phosphorus in seawater. Background technique [0002] In the 21st century, mankind has entered a period of large-scale development and utilization of the ocean. my country is both a land power and a sea power. The red tides and Enteromorpha outbreaks that occur every year from south to north in my country's coastal areas are a hurdle that hinders the sustainable development of the ocean and the protection of the blue ocean. The main reason for this phenomenon is that the enrichment of nitrogen and phosphorus nutrients leads to water bodies Eutrophication. Therefore, real-time and accurate monitoring of the content of total nitrogen and total phosphorus in seawater can provide an important decision-making basis for protecting the ocean and controlling the deterioration ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01N21/31
CPCG01N21/31
Inventor 孙中梁王阳吴宁王茜邹妍于涛鱼卫星
Owner OCEANOGRAPHIC INSTR RES INST SHANDONG ACAD OF SCI
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