Water-based pearlescent ink binder for decoration paper
A pearlescent ink, water-based technology, used in inks, applications, household appliances, etc., can solve the problems of loss of pearlescent effect, poor water resistance of ink, corrosion of pearlescent powder, etc. Effect
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[0032] In some embodiments, the preparation method of the modified casein includes the following steps: dissolving the casein in alkaline water, heating to 70-80°C, adding graft monomer and 0.1wt% potassium persulfate, Concentrate to the specified solid content at 85°C, and cool to obtain the obtained product.
[0033] In some preferred embodiments, the preparation method of the modified casein includes the following steps: disperse the casein (CAS No. 9000-71-9) in water, adjust the pH to alkaline, heat to 75°C, add The modified monomer and 10 ml of 0.1wt% potassium persulfate were concentrated at 80°C and cooled to obtain the obtained product.
[0034] In some preferred embodiments, the preparation method of the modified casein includes the following steps: stirring and dispersing 15g of casein in 100mL of water, adding ammonia water dropwise, adjusting the pH to >8, heating to 75°C, adding the modified monomer and 10 ml of 0.1wt% potassium persulfate, concentrated at 80°C,...
Embodiment 1
[0068] Embodiment 1 provides a water-based pearlescent ink binder for decorative paper, and its preparation raw materials include: 10.5% resin, 0.6% film-forming aid, 0.1% color-fixing agent, 0.3% wetting agent, anti- Precipitating agent 1%, defoamer 0.1%, bactericide 0.03%, and the balance is deionized water.
[0069] The resin is a mixture of waterborne polyurethane resin, casein and polyvinylpyrrolidone; the weight ratio of the waterborne polyurethane resin, casein and polyvinylpyrrolidone is 2.75:1.5:1.
[0070] The casein is modified casein, and its preparation method includes the following steps: stirring and dispersing 15g of casein in 100mL of water, adding ammonia water dropwise, adjusting the pH>8, heating to 75°C, adding modified monomer and 10ml of 0.1 wt% potassium persulfate, concentrated at 80°C, cooled, to get that; the amount of the modified monomer is 30wt% of the casein; the modified monomer of the modified casein is caprolactam and methylol Mixing of acryl...
Embodiment 2
[0079] Embodiment 2 provides a water-based pearlescent ink binder for decorative paper, and its preparation raw materials include: 9% resin, 0.5% film-forming aid, 0.05% color-fixing agent, 0.2% wetting agent, anti- Precipitating agent 0.5%, defoamer 0.1%, bactericide 0.01%, and the balance is deionized water.
[0080] The resin is a mixture of waterborne polyurethane resin, casein and polyvinylpyrrolidone; the weight ratio of the waterborne polyurethane resin, casein and polyvinylpyrrolidone is 3:2:1.
[0081] The casein is modified casein, and its preparation method includes the following steps: stirring and dispersing 15g of casein in 100mL of water, adding ammonia water dropwise, adjusting the pH>8, heating to 75°C, adding modified monomer and 10ml of 0.1 wt% potassium persulfate, concentrated at 80°C, cooled, to get that; the amount of the modified monomer is 30wt% of the casein; the modified monomer of the modified casein is caprolactam and methylol Mixing of acrylamide...
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