Chemically resistant fluorinated multiblock polymer structures, methods of manufacturing and use
A technology of fluorinated polymers and polymers, applied in chemical instruments and methods, membranes, membrane technology, etc.
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[0026] The present invention is a homoporous structure comprising at least one multi-block polymer, wherein at least one block comprises at least one moiety containing fluorine atoms ("fluorinated"), e.g. membranes, films, fabrics , Monolith. The incorporation of fluorine atoms imparts chemical resistance and antifouling properties to the homoporous block copolymer structure. This combination of fluorinated polymer blocks (e.g., A-B, A-B-C, A-B-C-D, or A-B-C-D-E) in a multi-block copolymer structure generated by self-assembly results in separations in non-aqueous liquid media such as organic or harsh liquid media. High permeability and high selectivity homoporous structure. In addition, fluorination adds an anti-fouling effect to the material.
[0027] Table 1 below provides non-limiting examples of block copolymer configurations. Different letters indicate different chemical compositions, where A, B, C, D, and E are each polymer blocks formed from the same monomer, and -co...
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