Silver bismuth iodine single crystal, preparation method and applications thereof

A single crystal, silver-bismuth technology, applied in the field of radiation detection crystal materials, can solve the problems of poor energy resolution, inconvenient portability, small size of semiconductor detectors, etc., and achieve high sensitivity and environmental friendliness

Inactive Publication Date: 2020-01-03
INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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Problems solved by technology

[0003] In the early detection of nuclear radiation, gas ionization detectors and scintillation crystal detectors have been widely used, but gas ionization detectors are bulky, inconvenient to carry, and have low X-ray blocking ability, so the detection efficiency is very low. Detector, although its detection efficiency is very high, but

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  • Silver bismuth iodine single crystal, preparation method and applications thereof
  • Silver bismuth iodine single crystal, preparation method and applications thereof
  • Silver bismuth iodine single crystal, preparation method and applications thereof

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Embodiment Construction

[0030] In order to make the objectives, technical solutions and advantages of the present invention clearer, the technical solutions of the present invention will be described in detail below. Obviously, the described embodiments are only a part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other implementations obtained by a person of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.

[0031] In any embodiment, such as figure 1 As shown, a silver bismuth iodine crystal of the present invention has a chemical formula of AgBi 2 I 7 , Has a face-centered cubic structure, and the unit cell parameters are α=β=γ=90°, each Bi 3+ Around with eight I - Form a regular hexahedron, each Ag + Around with six I - Form a regular octahedron.

[0032] In a specific embodiment, the above-mentioned preparation method of silver bismuth iodine crystal i...

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Abstract

The invention discloses a silver bismuth iodine single crystal. According to the silver bismuth iodine single crystal, the chemical formula is AgBi2I7, and the crystal has a face-centered cubic structure; the cell parameters comprise that a, b and c are the same and equal to 12.22 angstrom, and alpha, beta and gamma are the same and equal to 90 DEG; and each Bi<3+> and the surrounding eight I<-> form a regular hexahedron, and each Ag<+> and the surrounding six I<-> form a regular octahedron. According to the invention, the crystal is a novel radiation detection material, and is environmentallyfriendly; the X-ray detection sensitivity of the detector prepared from the crystal is 364.7 [mu]CGy[air]<-1>cm<-2>, is equivalent to the sensitivity (318 [mu]CGy[air]<-1>cm<-2>) of the traditional tellurium-zinc-cadmium X-ray detector, and is higher than the sensitivity (20 [mu]CGy[air]<-1>cm<-2>) of the amorphous selenium X-ray detector; and the novel Bi-based halide single crystal material canfurther be used for X-ray imaging and preparation of gamma-ray detectors.

Description

Technical field [0001] The invention relates to a radiation detection crystal material, specifically a chemical formula of AgBi 2 I 7 Bi-based halide single crystal material, its preparation method and the application of the prepared device in the field of radiation detection. Background technique [0002] X-ray detection plays a vital role in medical imaging, safety inspection, industrial non-destructive testing, national defense security, and cosmic radiation detection. Therefore, the research on X-ray detection materials is very necessary. [0003] In the early nuclear radiation detection, gas ionization detectors and scintillation crystal detectors have been widely used. However, gas ionization detectors are large in size, inconvenient to carry, and have low X-ray blocking ability, and the detection efficiency is very low. The detector, although its detection efficiency is high, but its energy resolution is poor, and still cannot meet the needs of use. In the second half of th...

Claims

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Application Information

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IPC IPC(8): C30B29/12C30B11/02
CPCC30B11/02C30B29/12
Inventor 张文华郑霄家帖舒婕黄巍赵伟龙继东
Owner INST OF CHEM MATERIAL CHINA ACADEMY OF ENG PHYSICS
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