Lead alloy deslagging agent and application method thereof

A technology of lead alloy and slag remover, which is applied in the field of electrochemistry, can solve problems such as unstable lead slag rate, fluctuation of lead quality, uneven technical level, etc., and achieve improved electrochemical corrosion resistance, low alloy impurity content, lead Good fluidity

Inactive Publication Date: 2020-06-12
江苏海宝电池科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The quality of the lead-based alloy not only affects the forming condition, casting efficiency and yield of the grid, but also affects the corrosion resistance of the grid, and ultimately affects the life of the battery
In recent years, with the continuous strengthening of the country's control over the recycling and reuse of waste batteries and the continuous expansion of the battery recycling industry, more than 40% of the lead currently on the market is made from recycling and smelting waste batteries. At the same time, due to the recycling and smelting technology of various manufacturers The levels are uneven and the types of lead recovered are different, resulting in fluctuations in the quality of lead. The lead slag rate and yield of different batches of lead are not stable in the process of alloy preparation and grid casting, which affects product quality and cost.
Although there are slag remover products on the market, which have a certain effect on reducing the rate of lead slag, they have little effect on improving the quality of alloy products, and the fluidity of lead liquid is average.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] A lead alloy slag remover, comprising 40% of bamboo charcoal powder, 5% of sodium hydroxide, 5% of sodium nitrate, 3% of sulfur powder, 27% of coal powder, 20% of pine wood powder It is uniformly prepared by mechanical grinding and stirring.

[0019] Bamboo charcoal powder, coal powder, and pine tree powder in the formula can change the surface tension of the lead liquid, make the lead liquid and lead slag well separated, and make the lead slag powdery, reducing the risk of metal lead mixed in the salvaged lead slag. content; at the same time, the sulfur powder in the formula can reduce part of the lead oxide to metallic lead under high temperature conditions, further reducing the production of lead oxide slag; the addition of sodium hydroxide and sodium nitrate makes the lead liquid alkaline, reducing Sb, Cu The solubility of impurities such as Fe and Fe in the lead liquid accelerates the floating of these impurities and oxidized slag particles. Less impurities and oxi...

Embodiment 2

[0025] A lead alloy slag remover, comprising 27% of bamboo charcoal powder, 5% of sodium hydroxide, 5% of sodium nitrate, 3% of sulfur powder, 20% of coal powder, and 40% of pine tree powder by weight It is uniformly prepared by mechanical grinding and stirring. When the battery grid is prepared with lead alloy, the prepared slag remover is added to the electrolytic lead, reacts with the lead liquid of the electrolytic lead, separates the lead slag, and removes impurities; then, the prepared lead alloy is put into the casting production of the grid .

Embodiment 3

[0027] A lead alloy slag remover, comprising 20% ​​of bamboo charcoal powder, 5% of sodium hydroxide, 5% of sodium nitrate, 3% of sulfur powder, 40% of coal powder, and 27% of pine tree powder by weight It is uniformly prepared by mechanical grinding and stirring. When the battery grid is prepared with lead alloy, the prepared slag remover is added to the electrolytic lead, reacts with the lead liquid of the electrolytic lead, separates the lead slag, and removes impurities; then, the prepared lead alloy is put into the casting production of the grid .

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PUM

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Abstract

The invention discloses a lead alloy deslagging agent which is prepared by uniformly mixing bamboo charcoal powder, sodium hydroxide, sodium nitrate, sulfur powder, pulverized coal and pine wood powder by a mechanical grinding and stirring way. The deslagging agent is prepared from the following components in percent by weight: 20-40% of bamboo charcoal powder, 5% of sodium hydroxide, 5% of sodiumnitrate, 3% of sulfur powder, 20-40% of pulverized coal and 20-40% of pine wood powder. When a lead alloy for a storage battery grid is prepared, the prepared deslagging agent is added into electrolytic lead to be reacted with molten lead of the electrolytic lead, so that lead slag is separated and impurities are removed. By preparing the alloy from the deslagging agent, the lead slag rate can bereduced by over 50%, and the alloy is low in impurity content and good in flowability of molten lead. The prepared lead is used for pouring the grid, and the grid is formed well, and is high in rateof finished products and high in corrosion resistance.

Description

technical field [0001] The invention relates to the technical field of electrochemistry, in particular to a lead alloy slag remover. Background technique [0002] The grids for lead-acid batteries are mainly prepared by gravity casting with lead-based alloys. The quality of the lead-based alloy not only affects the forming condition of the grid, casting efficiency, and yield, but also affects the corrosion resistance of the grid, and ultimately affects the life of the battery. In recent years, with the continuous strengthening of the country's control over the recycling and reuse of waste batteries and the continuous expansion of the battery recycling industry, more than 40% of the lead currently on the market is made from recycling and smelting waste batteries. At the same time, due to the recycling and smelting technology of various manufacturers The levels are uneven and the types of lead recovered are different, resulting in fluctuations in the quality of lead. The lead...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/02C22C1/06C22C11/00
CPCC22C1/02C22C1/06C22C11/00
Inventor 杨海涛沈煜婷沈维新
Owner 江苏海宝电池科技有限公司
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