A kind of magnetic quantum dot and its preparation method, ink cartridge
A technology of quantum dots and quantum dot layers, applied in the field of quantum dots, can solve the problems of non-magnetic ink and difficult adjustment of ink components, and achieve the effect of improving printing efficiency and
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[0037] The present invention also provides a method for preparing magnetic quantum dots, comprising the steps of:
[0038]adding quantum dots and magnetic nanoparticles to an aqueous solution containing a surfactant, mixing to coat the quantum dots on the outer surface of the magnetic nanoparticle core, and obtaining a micellar solution in which the quantum dot layer coats the magnetic nanoparticle core;
[0039] Mixing the micelle solution in which the quantum dot layer coats the magnetic nano particle core with the organic shell material, so that the organic shell material is coated on the outer surface of the quantum dot layer to obtain the magnetic quantum dot.
[0040] The magnetic quantum dots prepared by the method of the present invention use magnetic nanoparticles as the core and coat a layer of quantum dots outside the core, which neither affects the performance of the quantum dots, but also makes the quantum dots magnetic. The dot layer is coated with an organic lay...
Embodiment 1
[0049] Containing 4mg red CdSe-CdS core-shell quantum dots and 6mg nanometer superparamagnetic nano-ferric oxide (MNP) (quantum dots, magnetic nanoparticles combined with organic ligands, such as Figure 2a As shown, 1 represents CdSe-CdS core-shell quantum dots, 2 represents magnetic nanoparticles, 3 represents organic ligands) in 1ml chloroform solution into 1ml dodecyltrimethylammonium bromide (DTAB) aqueous solution (20mg / ml in ultrapure water), (QDs and MNPs modified, such as Figure 2b shown, 4 means DTAB). The solution was mixed thoroughly by vortexing for 5 sec. Chloroform was removed from the mixture by blowing Ar at room temperature, and the red CdSe-CdS core-shell quantum dots were combined with nano-superparamagnetic nano-Fe3O4 through the action of solvent-repelling (dodecyltrimethylammonium bromide). Together, a clear red CdSe-CdS core-shell quantum dot and nano-superparamagnetic nano-ferric oxide aqueous micellar solution (red CdSe-CdS core-shell quantum dots ...
Embodiment 2
[0053] Inject 1ml of chloroform solution containing 4mg of red CdSe-CdS core-shell quantum dots and 6mg of nano-superparamagnetic nano-iron tetroxide (MNP) into 1ml of dodecyltrimethylammonium bromide (DTAB) aqueous solution (20mg / ml in in ultrapure water). The solution was mixed thoroughly by vortexing for 5 sec. Chloroform was removed from the mixture by blowing Ar at room temperature, and the red CdSe-CdS core-shell quantum dots were combined with nano-superparamagnetic nano-Fe3O4 through the action of solvent-repelling (dodecyltrimethylammonium bromide). Together, a clear red CdSe-CdS core-shell quantum dot and nano-superparamagnetic nano-Fe3O4 micellar aqueous solution was obtained.
[0054] The micellar solution was quickly injected into 5ml polyvinylpyrrolidone (PVP) ethylene glycol (EG) solution at room temperature at a stirring speed of 800rpm and stirred for 30 minutes, and the obtained magnetically doped Red quantum dot supernanoparticles.
[0055] The magnetical...
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