A kind of copper foil additive for the fifth generation mobile communication board, copper foil and its production process
A mobile communication and additive technology, applied in electroforming, electrolysis process, etc., can solve the problems of unsatisfactory bonding force and signal loss, unsuitable copper foil, low roughness, etc., to improve the uniformity of microstructure and signal loss. less, the effect of reducing the roughness
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Embodiment 1
[0058] An electrolytic copper foil additive for the fifth-generation mobile communication high-frequency and high-speed board, the additives are additive A and additive B;
[0059] Additive A includes the following components: 0.1 g / L of cerium sulfate and 1 g / L of sodium mercaptoimidazole propanesulfonate.
[0060] Additive B includes the following components: sodium phenyl dithiopropane sulfonate (BSP) 15 mg / L and thiazolinyl sodium dithiopropane sulfonate (SH110) 5 mg / L.
[0061] The preparation method of 12 μm copper foil comprises the steps:
[0062] (1) Preparation of electrolyte: adding copper to a solution containing sulfuric acid to obtain an electrolyte, the content of copper in the electrolyte is 60g / L, the content of sulfuric acid is 100g / L, and the temperature is 50°C;
[0063] (2) Preparation of raw foil: add additive A to the electrolyte prepared in step (1), and conduct electrodeposition on the cathode roll. During the electrodeposition process, the flow rate ...
Embodiment 2
[0069] An electrolytic copper foil additive for the fifth-generation mobile communication high-frequency and high-speed board, the additives are additive A and additive B;
[0070] Additive A includes the following components: lanthanum sulfate 0.2g / L and hexylbenzylamine salt 2g / L.
[0071] Additive B includes the following components: sodium phenyldithiopropanesulfonate (BSP) 20mg / L and sodium thiazolinyldithiopropanesulfonate (SH110) 7mg / L.
[0072] The preparation method of 18 μm copper foil comprises the steps:
[0073] (1) Preparation of electrolyte: adding copper to a solution containing sulfuric acid to obtain an electrolyte, the content of copper in the electrolyte is 65g / L, the content of sulfuric acid is 120g / L, and the temperature is 52°C;
[0074] (2) Preparation of raw foil: add additive A to the electrolyte prepared in step (1), and conduct electrodeposition on the cathode roller. The flow rate of the electrolyte during the electrodeposition process is 45m 3 / ...
Embodiment 3
[0079] An electrolytic copper foil additive for the fifth-generation mobile communication high-frequency and high-speed board, the additives are additive A and additive B;
[0080] Additive A includes the following components: 0.1 g / L of cerium sulfate, 0.1 g / L of lanthanum sulfate, 1 g / L of sodium mercaptoimidazole propanesulfonate and 1 g / L of hexylbenzylamine salt.
[0081] Additive B includes the following components: sodium phenyl dithiopropane sulfonate (BSP) 30 mg / L and thiazolinyl sodium dithiopropane sulfonate (SH110) 10 mg / L.
[0082] The preparation method of 35 μm copper foil comprises the steps:
[0083] (1) Preparation of electrolyte: adding copper to a solution containing sulfuric acid to obtain an electrolyte, the content of copper in the electrolyte is 70g / L, the content of sulfuric acid is 140g / L, and the temperature is 52°C;
[0084] (2) Preparation of raw foil: add additive A to the electrolyte prepared in step (1), and conduct electrodeposition on the cat...
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