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Preparation method of catalyst for electro-catalytic degradation of phenolic environmental pollutants

A technology for electrocatalytic degradation and environmental pollutants, applied in the direction of physical/chemical process catalysts, water pollutants, chemical instruments and methods, etc., can solve problems such as poor catalytic effect, low catalytic efficiency, and insufficient improvement of catalyst performance

Inactive Publication Date: 2020-08-25
UNIV OF JINAN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The traditional single catalyst faces problems such as low catalytic efficiency and poor catalytic effect. Therefore, the development of highly efficient doped catalysts has important guiding significance for the field of catalysis. Single doping does not improve the performance of catalysts significantly, so the development of multi-doped Heterocatalysts are imperative

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Add the molybdenum source reagent, 10 g of phytic acid, and 15 g of glucose into 300 mL of deionized water, and stir evenly; then add 10 mL of 1 M mixed acid, and stir vigorously to obtain a catalyst preparation solution.

Embodiment 2

[0019] The prepared solution was transferred to a polytetrafluoroethylene-lined autoclave, and reacted at 200°C for 10 h. After the reaction, the obtained material was rinsed with deionized water and dried to obtain carbon, phosphorus-doped Precursors of molybdenum heterooxide catalysts.

Embodiment 3

[0021] The carbon, phosphorus-doped molybdenum oxide catalyst precursor obtained above was annealed at 90 °C for 3 h in an argon atmosphere to obtain C, P-MoO 3 nanosheet catalysts.

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Abstract

A phenolic compound is a compound generated by substituting a hydrogen atom on a benzene ring in aromatic hydrocarbon with a hydroxyl group, and can be divided into monohydric phenol and polyhydric phenol according to the number of hydroxyl groups contained in the molecule. Catalytic degradation of phenolic pollutants is a hotspot problem in the field of environmental catalytic chemistry, and electro-catalytic degradation of phenolic pollutants has important scientific and practical significance for evaluating environmental ecology. Pollution caused by phenolic organic pollutants in a water body can pollute the atmosphere, water, soil and food if the phenolic organic pollutants are directly discharged and irrigated in a farmland without being treated, and the ecological environment and thelife safety of people are seriously harmed. The electro-catalytic degradation of the phenolic organic pollutants is used in the electro-catalytic process, so that the degradation of the phenolic organic pollutants is realized, and a new thought is provided for constructing an environment-friendly society.

Description

technical field [0001] The present invention relates to the preparation method and application field of a catalyst doped with various nonmetals, in particular to a method for preparing C, P-MoO 3 The method of nanosheet catalyst and its application in the field of electrocatalytic degradation of phenolic environmental pollutants. Background technique [0002] Hydroxyl-containing derivatives of aromatic hydrocarbons are divided into volatile phenols and non-volatile phenols according to their volatility. Most of the phenolic compounds that exist in nature are the result of plant life activities. The phenols contained in plants are called endogenous phenols, and the rest are called exogenous phenols. Phenolic compounds have a special aromatic smell, are weakly acidic, and are easily oxidized in the environment. The content of phenol and cresol is the highest in phenolic wastewater. Therefore, volatile phenols such as phenol and cresol are often used as pollution indicators i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J27/19C02F1/461C02F1/467C02F101/34
CPCB01J27/19C02F1/46109C02F1/467C02F2001/46142C02F2101/345C02F2303/04B01J35/33Y02A50/20
Inventor 赵金秀任祥薛晓东张森赵磊闫涛赵燕芳魏琴
Owner UNIV OF JINAN
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