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A 3D printing self-suspension photocatalytic device preparation method

A 3D printing and self-suspending technology, applied in the application field of photocatalysis technology, can solve problems such as easy warping of printing, and achieve the effect of solving high turbidity

Active Publication Date: 2022-04-26
FUJIAN NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the traditional ABS consumables have the problem of easy warping when printing, so they are modified with other polymers to be suitable for the deviceization of catalysts.

Method used

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  • A 3D printing self-suspension photocatalytic device preparation method
  • A 3D printing self-suspension photocatalytic device preparation method
  • A 3D printing self-suspension photocatalytic device preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A 3D printing self-suspension photocatalytic device preparation method is divided into the following steps:

[0045] 1) Mix 8 kg ABS and 2 kg TPU through a high-speed mixer, and then melt and blend them through a twin-screw extruder. 155°C, 165°C in the fifth zone, 185°C in the sixth zone, 195°C in the seventh zone, 180°C in the eighth zone, 170°C in the ninth zone, 165°C at the die head, and a rotation speed of 200 rpm. Extrude and granulate to obtain wire masterbatch;

[0046] 2) Melt and extrude the wire masterbatch obtained in step 1) through a single-screw extruder. The parameters of the single-screw extruder are: 120°C in the first zone, 180°C in the second zone, 195°C in the third zone, and 170°C in the fourth zone. 50 rpm, the extruded wire is cooled by water, and the tractor pulls and controls the wire diameter to make a wire with a wire diameter of 1.75±0.05 mm;

[0047] 3) Design a square sheet with a side length of 5 cm, a height of 0.2 cm, and a wall thick...

Embodiment 2

[0052] A 3D printing self-suspension photocatalytic device preparation method is divided into the following steps:

[0053] 1) After mixing 8.5 kg ABS and 1.5 kg TPU through a high-speed mixer, melt and blend them through a twin-screw extruder. 170°C, 185°C in the fifth zone, 195°C in the sixth zone, 200°C in the seventh zone, 190°C in the eighth zone, 175°C in the ninth zone, 165°C at the die head, and a rotation speed of 150 rpm. Extrude and granulate to obtain wire masterbatch;

[0054] 2) Melt and extrude the wire masterbatch obtained in step 1) through a single-screw extruder. The parameters of the single-screw extruder are: 120°C in the first zone, 190°C in the second zone, 200°C in the third zone, and 170°C in the fourth zone. 50 rpm, the extruded wire is cooled by water, and the tractor pulls and controls the wire diameter to make a wire with a wire diameter of 1.75±0.05 mm;

[0055] 3) Design a circular sheet with a radius of 2 cm, a height of 0.2 cm, and a wall thic...

Embodiment 3

[0060] A 3D printing self-suspension photocatalytic device preparation method is divided into the following steps:

[0061] 1) After mixing 7 kg ABS and 3 kg TPU through a high-speed mixer, melt and blend them through a twin-screw extruder. The twin-screw parameters are: 90°C in the first zone, 120°C in the second zone, 145°C in the third zone, and 145°C in the fourth zone 160°C, 170°C in the fifth zone, 180°C in the sixth zone, 185°C in the seventh zone, 175°C in the eighth zone, 165°C in the ninth zone, 160°C at the die head, and a rotation speed of 220 rpm. Extrude and granulate to obtain wire masterbatch;

[0062] 2) Melt and extrude the wire masterbatch obtained in step 1) through a single-screw extruder. The parameters of the single-screw extruder are: 120°C in the first zone, 170°C in the second zone, 185°C in the third zone, and 170°C in the fourth zone. 45 rpm, the extruded wire is cooled by water, and the tractor pulls and controls the wire diameter to make a wire wi...

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Abstract

The invention discloses a method for preparing a 3D printed self-suspension photocatalytic device, and the photocatalyst is loaded on a sheet by a thermal deposition method. The method comprises the following steps: after extruding the wire material through a twin-screw extruder and a single-screw extruder, printing it into a thin sheet with holes by using a 3D printing technology, and loading the photocatalyst on the thin sheet by thermal deposition. The method is suitable for photocatalytic degradation of pollutants and photolysis of water to produce hydrogen and oxygen. The invention utilizes the glass transition temperature of the sheet to firmly load the catalyst on the sheet. By adjusting the density of the sheet, it can be suspended on the liquid surface, which not only enables the catalyst to effectively use light, but also solves the difficulties of high turbidity of the suspension in the photocatalytic system, and difficulties in the recovery and reuse of photocatalysts.

Description

technical field [0001] The invention belongs to the application field of photocatalysis technology, and in particular relates to a preparation method of a 3D printed self-suspension photocatalyst. Background technique [0002] Environmental pollution and energy depletion are major issues that human beings face and need to be solved urgently. Among them, semiconductor photocatalysis technology is considered to be an ideal environmental pollution control technology because of its uniqueness such as direct use of sunlight, reaction at room temperature, and no secondary pollution. Moreover, the use of photocatalytic water splitting to produce hydrogen to realize the direct conversion from solar energy to hydrogen energy is an ideal way to obtain new energy. At present, photocatalysis, as an effective means to convert light energy into chemical energy, can be widely used in the fields of photocatalytic degradation of pollutants and photolysis of water to produce hydrogen and oxy...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29B9/06B29C64/314B29C64/379B33Y40/10B33Y40/20B33Y70/10C08L55/02C08L75/04
CPCB29B9/06B29C64/314B29C64/379B33Y40/10B33Y40/20B33Y70/10C08L55/02C08L75/04
Inventor 薛珲毛婧芸夏新曙钱庆荣郑荧炼刘欣萍曾令兴罗永晋
Owner FUJIAN NORMAL UNIV