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Ultraviolet-transmitting high-boron glass tube and preparation method thereof

A technology of high boron glass and ultraviolet rays, applied in glass manufacturing equipment, glass furnace equipment, glass forming, etc., can solve the problems of poor consistency, glass tube finished product streaks, easy hardening and forming, etc. The method is simple, convenient and resistant Corrosion performance, complete melting effect

Pending Publication Date: 2020-10-27
驻马店市辉源照明器材有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For a long time, ultraviolet-transmitting glass tubes have been melted in a crucible and drawn by hand. Due to the low output of melting the crucible and drawing by hand, the labor intensity of the workers is high, and the full melting of the glass cannot be guaranteed, let alone the drawing. The uniformity of the outer diameter and wall thickness of the glass tube affects the purple transmittance, and the outer diameter and wall thickness are uneven and poor in consistency, which cannot realize industrial production in the process of making lamps, nor can it meet the needs of the high-quality market
At present, there are other methods to prepare UV-transparent glass tubes, such as the down-draw method to produce UV-transparent high-boron glass tubes. Due to the high boron content in the glass tube composition, the concentration of the glass liquid is very low due to the change of the composition. During the cooling process, it will The accumulation of glass liquid will cause streaks in the finished glass tube and affect the purple transmission rate, so it is not suitable for the down-draw method
In addition, although the Dan La method (parallel drawing) is a commonly used glass production technology, this kind of high boron glass tube, because the concentration of the glass liquid is low at high temperature, the conventional cooling is easy to harden and difficult to form in a short time. As a result, drawing cannot be carried out. Therefore, there are great limitations in the preparation of such UV-transparent glass tubes by the traditional Dan La method.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] An ultraviolet transparent high boron glass tube, comprising the following raw materials in parts by weight: 20 parts of boric acid, 12 parts of borax pentahydrate, 18 parts of zero water borax, 1 part of aluminum hydroxide, 64 parts of quartz sand, 0.4 parts of tartaric acid, and titanium oxide 0.2 parts.

[0022] A preparation method of ultraviolet-transmitting high boron glass tube, which is prepared by the following steps:

[0023] (1) Pour boric acid, borax pentahydrate, zero water borax, aluminum hydroxide, quartz sand, tartaric acid, and titanium oxide into the mixer, stir at 80r / min for 5 minutes, mix well, and then enter the automatic feeder according to 2kg / The feeding speed of min is added to the electric melting furnace, and it is completely melted into molten glass at 1480°C. The molten glass passes through the liquid hole to cool to 1450°C, the ascending channel to 1400°C, and the cooling channel to 1200°C. The temperature of the material trough is cooled to ...

Embodiment 2

[0026] An ultraviolet transparent high boron glass tube, comprising the following raw materials in parts by weight: 22 parts of boric acid, 12 parts of borax pentahydrate, 14.5 parts of zero water borax, 3.4 parts of aluminum hydroxide, 64 parts of quartz sand, 0.6 parts of tartaric acid, and titanium oxide 0.4 copies.

[0027] A method for preparing an ultraviolet-transmitting high boron glass tube, which is prepared by the following steps:

[0028] (1) Pour boric acid, borax pentahydrate, zero water borax, aluminum hydroxide, quartz sand, tartaric acid, and titanium oxide into the mixer, stir at 80r / min for 5 minutes, mix well, and then enter the automatic feeder, according to 2.5kg The feed rate is added to the electric melting furnace at 1500°C and melted into molten glass at 1500°C. The molten glass passes through the liquid hole to cool down to 1450°C, the rising channel to 1400°C, and the cooling channel to 1200°C. The temperature of the discharging trough is cooled to 1050...

Embodiment 3

[0031] An ultraviolet transparent high boron glass tube, including the following raw materials in parts by weight: 22.5 parts of boric acid, 15 parts of borax pentahydrate, 13 parts of zero water borax, 2.5 parts of aluminum hydroxide, 62.5 parts of quartz sand, 0.55 parts of tartaric acid, and titanium oxide 0.35 copies

[0032] A method for preparing an ultraviolet-transmitting high boron glass tube, which is prepared by the following steps:

[0033] (1) Pour boric acid, borax pentahydrate, zero water borax, aluminum hydroxide, quartz sand, tartaric acid, and titanium oxide into the mixer, stir at 80r / min for 5 minutes, mix well, and then enter the automatic feeder according to 3kg / The feeding speed of min is added to the electric melting furnace, and it is completely melted into molten glass at 1500℃. The molten glass is successively cooled to 1450℃ through the liquid hole, the ascending channel is cooled to 1400℃, the cooling channel is cooled to 1200℃, and the The temperatur...

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PUM

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Abstract

The invention discloses an ultraviolet-transmitting high-boron glass tube, which is prepared from the following raw materials by weight: 20-25 parts of boric acid, 12-18 parts of borax pentahydrate, 8-18 parts of anhydrous borax, 1-4 parts of aluminum hydroxide, 60-65 parts of quartz sand, 0.4-0.7 part of tartaric acid and 0.2-0.5 part of titanium oxide. The ultraviolet-transmitting high-boron glass tube provided by the invention has the characteristics of uniform outer diameter and wall thickness, good lamp working performance, high ultraviolet transmittance and the like; the preparation method comprises the following steps of: (1) uniformly mixing boric acid, borax pentahydrate, anhydrous borax, aluminum hydroxide, quartz sand, tartaric acid and titanium oxide, adding the mixture into anelectric melting furnace, completely melting the mixture into molten glass at 1480-1520DEG C, cooling the molten glass to 1000-1100DEG C, and enabling the molten glass to flow into a rotating pipe ofa forming machine; and (2) enabling the molten glass in the rotating pipe in the step (1) to enter a heat preservation box for homogenizing forming, then enabling the molten glass to flow into a cooling runway of 400-600DEG C, and enabling the molten glass to enter a dragger for drawing and cutting, thus obtaining the ultraviolet-transmitting high-boron glass tube. Standardized production of continuous feeding and continuous drawing is achieved through a Danla method (parallel drawing method).

Description

Technical field [0001] The invention belongs to the technical field of glass tubes, and specifically relates to an ultraviolet-transmitting high-boron glass tube and a preparation method thereof. Background technique [0002] Ultraviolet transparent glass tube has a good sterilization effect and can be widely used for sterilization in homes, schools and public places. For a long time, UV-transmitting glass tubes are made by melting glass in a crucible and manually drawn. Due to the low output of crucible melting and manual drawing, the labor intensity of workers is high, and the full melting of the glass cannot be guaranteed, let alone the drawing. The uniformity of the outer diameter and wall thickness of the glass tube affects the purple penetration rate, and the outer diameter and wall thickness are uneven, and the consistency is poor. It cannot be industrialized in the lamp making process, nor can it meet the needs of the high-quality market. At present, there are other meth...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C6/04C03C3/091C03C4/00C03B5/16C03B17/04
CPCC03B5/16C03B17/04C03C1/00C03C3/091C03C4/0085
Inventor 李方玉李汇通
Owner 驻马店市辉源照明器材有限公司
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