Swelling particle heterogeneous crack plugging effect improver and preparation method thereof
A body-expanding granule and heterogeneous technology, applied in the field of volume-expanding granule non-homogeneous crack plugging effect improver and preparation field, to achieve the effect of breakthrough pressure gradient increase and plugging effect improvement
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[0033] A preparation method of a volume-expanding particle heterogeneous crack plugging effect improving agent, comprising the following steps:
[0034] Step 1: Prepare coupling agent modified matrix particles;
[0035] Step 2: Grinding the coating resin into powder and preheating, while preheating the coupling agent modified matrix particles obtained in step 1;
[0036] Step 3: Mix the lubricant, the coating resin in step 2, and the modified matrix particles of the coupling agent evenly, and heat at 120-180°C; take out the mixture every t time during the heating process, stir evenly and continue heating , After 0.5-1h, the desired modifier can be obtained.
[0037] The preparation process of the coupling agent modified matrix particles in step 1 is as follows:
[0038] S11: Mix the coupling agent, water and alcohol evenly under the condition of pH = 4-9, and react for 1-2 hours to obtain a coupling agent hydrolyzate;
[0039] S12: mix and react the matrix particles and the...
Embodiment 1
[0045] According to the following steps, the volume-expanding particle heterogeneous crack plugging effect improving agent is prepared;
[0046]Step 1: At room temperature, mix 6mL of γ-aminopropyltriethoxysilane, 4ml of water and 40ml of ethanol at pH = 9.0 and react for 2 hours to obtain a coupling agent hydrolyzate; 50g of The volcanic stone balls and 25g coupling agent hydrolyzate were mixed and reacted at room temperature for 2 hours; then the volcanic stone balls were filtered and placed in an oven at 60°C for 5 hours to obtain the coupling agent modified matrix particles.
[0047] Step 2: Grind 15g of terpene phenolic resin into powder and preheat at 40°C for 10min, meanwhile preheat 84.6g of coupling agent-modified matrix particles at 130°C for 10min.
[0048] Step 3: Mix the preheated terpene phenolic resin powder, coupling agent modified matrix particles and 0.4g calcium stearate evenly, and place in a constant temperature oven at 170°C for heating; remove the mixtur...
Embodiment 2
[0062] According to the following steps, the volume-expanding particle heterogeneous crack plugging effect improver is prepared:
[0063] Step 1: At room temperature, mix 5mL of γ-(2,3-glycidoxy)propyltrimethoxysilane, 40ml of water and 5ml of methanol at pH = 4.0 and react for 2 hours to obtain the hydrolyzed coupling agent solution; 50g of medical stone balls with an average particle size of 1mm and 20g of coupling agent hydrolyzate were mixed and reacted for 2h at room temperature; then the medical stone balls were filtered and dried in an oven at 60°C for 5h to obtain the coupling agent Linking agent modified matrix particles.
[0064] Step 2: Grind 10 g of solid epoxy resin into powder and preheat at 40° C. for 10 minutes, and at the same time preheat 89.5 g of coupling agent-modified matrix particles at 100° C. for 10 minutes.
[0065] Step 3: Mix the preheated solid epoxy resin powder, coupling agent modified matrix particles and 0.5g calcium stearate evenly, and place...
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