Network and mobile terminal water quality detection method and detection system
A technology of water quality detection and mobile terminal, which is applied in signal transmission system, measuring device, and material analysis by observing the influence of chemical indicators, etc. problems, to achieve the effect of preventing fraud, saving testing costs, expanding the scope of testing and testing items
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Embodiment 1
[0057] For a group of liquids containing the detected items with similar concentrations, carry out the dyeing reaction according to the specification requirements to form a group of solutions containing the detected items. In the interval where the concentration is close to that obtained by photoelectric colorimetry, the concentration D of this group of detected items, and the first absorbance A of the detected item corresponding to the same wavelength of light, are obtained by using the Lambert-Beer law. Correspondence between the concentration D of the item and the absorbance A of the detected item:
[0058] D=bA+Z...(I);
[0059] In the formula: both b and Z are constants, and since the first absorbance A and the first light transmittance T are in a logarithmic relationship, the value of the first light transmittance T can also be collected here, and then the first light transmittance T can be obtained according to the logarithmic operation. As for the value of absorbance ...
Embodiment 2
[0078] The value of B in Example 1 can also be obtained by linear or nonlinear regression, or when an unacceptable difference between D and d is found through experiments, linear or nonlinear regression is used to correct the value of B.
[0079] That is when:
[0080] (D-d)>K...(IV)
[0081] Then: A>a+K / b...(V)
[0082]When there is still a large error in formula (III) and formula (IV), the relationship between A and a can be obtained from the regression equation, which is the relationship between the absorbance obtained from the color clicked on the chromatogram on the display screen and the true absorbance A. From Table-3, a and d can be linearly or nonlinearly regressed to obtain:
[0083] d=Ba+z...(VI), wherein: B=∑(ai-a0)(di-d0) / ∑(ai-a0)(ai-a0), in this example, i=1,2,... 30, a0 and d0 are the average values of a and d respectively. z=d0-B(a0). That is, both B and z are constants. Formula (I)-formula (VI) draws: A=(D-d+z-Z+Ba) / b...(VII), then also can draw K valu...
Embodiment 3
[0085] Compared with photoelectric colorimetry, visual colorimetry has certain errors, so this embodiment shows a method for correcting the deterioration of visual colorimetry in step S1, which is specifically as follows.
[0086] First, take 30 to 50 standard samples in a certain concentration range for the tested items of water samples, for example, take 30 standard water samples in the range of 0.01mg / L to 1mg / L for heavy metal chromium, which are: 0.005,0.01…1.5. The concentration range of sampling depends on two factors. The first is that within this concentration range, there is a linear relationship between concentration and absorbance; the second is that within this concentration range, the absorption light has a peak, and the wavelength is a known number, 540nm. Both of these factors can be found in the standard operation of water quality testing. Then, 30 standard water samples were detected by photoelectric colorimetry, and the linear relationship between their abs...
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