All-solid-state electrochromic device taking lithium aluminum silicate as electrolyte layer and preparation method of all-solid-state electrochromic device

A technology of electrochromic devices and electrolyte layers, applied in instruments, nonlinear optics, optics, etc., can solve the problems of high manufacturing cost, small device transmittance modulation range, slow coloring and fading response speed, etc., and achieve stable chemical properties , excellent stability, the effect of improving the adjustment range and stability

Pending Publication Date: 2021-01-29
HARBIN INST OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] The purpose of the present invention is to solve the problems of slow coloring and fading response speed of the existing all-solid-state electrochromic device, small transmittance modulation range of the device and high preparation cost, and provide a lithium aluminum silicate electrolyte layer All-solid-state electrochromic device and preparation method thereof

Method used

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  • All-solid-state electrochromic device taking lithium aluminum silicate as electrolyte layer and preparation method of all-solid-state electrochromic device
  • All-solid-state electrochromic device taking lithium aluminum silicate as electrolyte layer and preparation method of all-solid-state electrochromic device
  • All-solid-state electrochromic device taking lithium aluminum silicate as electrolyte layer and preparation method of all-solid-state electrochromic device

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specific Embodiment approach 1

[0029] Embodiment 1: An all-solid-state electrochromic device with lithium aluminum silicate as the electrolyte layer consists of a base, a lower transparent conductive layer, an ion storage layer, a lower protective layer, an electrolyte layer, and an upper protective layer that are sequentially arranged from bottom to top. layer, an electrochromic layer and an upper transparent conductive layer; the electrolyte layer is LiAlSiO 4 ; The lower protective layer is Si 3 N 4 or ZrO 2 ; The upper protective layer is Si 3 N 4 or ZrO 2 .

specific Embodiment approach 2

[0030] Embodiment 2: The differences between this embodiment and Embodiment 1 are: the substrate is a rigid substrate or a flexible substrate; the rigid substrate is silicon, metal or glass; the flexible substrate is polyethylene terephthalate Ethylene glycol formate or dimethicone. Other steps are the same as in the first embodiment.

specific Embodiment approach 3

[0031] Embodiment 3: This embodiment differs from Embodiment 1 or Embodiment 2 in that: the lower transparent conductive layer is an ITO layer, an FTO layer, an AZO layer, Ag nanowires or Ag nanoframes. Other steps are the same as those in Embodiment 1 or 2.

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Abstract

The invention discloses an all-solid-state electrochromic device taking lithium aluminum silicate as an electrolyte layer and a preparation method of the all-solid-state electrochromic device, and relates to an electrochromic device and a preparation method thereof. The invention aims to solve the problems that the fading response speed of an existing all-solid-state electrochromic device is low,the transmittance modulation range of the device is small and the preparation cost is high. According to the method, the all-solid-state electrochromic device with the lithium aluminum silicate as theelectrolyte layer is composed of a substrate, a lower transparent conductive layer, an ion storage layer, a lower protective layer, the electrolyte layer, an upper protective layer, an electrochromiclayer and an upper transparent conductive layer which are sequentially arranged from bottom to top. The method comprises the steps: 1, depositing the lower transparent conductive layer, the ion storage layer and the lower protective layer by adopting a magnetron sputtering method; 2, depositing the electrolyte layer by adopting a magnetron sputtering method; and 3, depositing the upper protectivelayer, the electrochromic layer and the upper transparent conductive layer by adopting a magnetron sputtering method. According to the invention, the all-solid-state electrochromic device taking lithium aluminum silicate as the electrolyte layer can be obtained.

Description

technical field [0001] The invention relates to an electrochromic device and a preparation method thereof. Background technique [0002] Electrochromism is a phenomenon in which the optical properties of materials (reflectivity, transmittance, absorptivity, etc.) undergo stable and reversible color changes under the action of small electrical signals. The material with electrochromic phenomenon is called electrochromic material. [0003] Electrochromic materials can be divided into inorganic electrochromic materials and organic electrochromic materials according to material types, and inorganic electrochromic materials include transition metals such as tungsten oxide, molybdenum oxide, vanadium oxide, titanium oxide, niobium oxide, and nickel oxide. Oxide and Prussian blue systems, organic electrochromic materials include polyaniline, polythiophene, viologen and other materials. Electrochromic devices made of electrochromic materials have been widely used in the fields of ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G02F1/1523G02F1/153G02F1/15
CPCG02F1/1523G02F1/1533G02F1/1508G02F1/15G02F2001/1536
Inventor 李垚赵英明张翔赵九蓬李文杰李梓同
Owner HARBIN INST OF TECH
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