Near-infrared fluorescent powder, preparation method thereof and light-emitting device
A light-emitting device and phosphor technology, applied in the field of phosphor, can solve the problems of limited application, low efficiency of infrared phosphor excitation by ultraviolet light, etc., and achieve the effects of long service life, low cost, and high excitation efficiency by ultraviolet light
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[0033] The second aspect of the embodiment of the present application provides a method for preparing a near-infrared phosphor, including steps:
[0034] S10. According to the ratio of each element in the near-infrared phosphor, after mixing the precursor of A, the precursor of Mg, the precursor of M and the precursor of Eu, perform the first sintering treatment to obtain the intermediate;
[0035] S20. After crushing the intermediate body, mix it with the precursors of R and Cr, perform a second sintering treatment, and crush to obtain a near-infrared phosphor.
[0036] The preparation method of the near-infrared fluorescent powder provided by the second aspect of the application, according to the general chemical formula A of the near-infrared fluorescent powder 1- y MgM 10-x-z R x o 17-x N x :yEu 2+ , zCr 3+ In , the proportion of each element is used to obtain the precursor of each element. Then, first mix the precursor of A, the precursor of Mg, the precursor of M...
Embodiment 1
[0045] A kind of near-infrared fluorescent powder, its chemical formula is: (Ba, Sr) 1-y Mg(Al, Ga) 10-x-z Si x o 17-x N x :yEu 2+ , zCr 3 + , Ba / Sr ratio 1:1, Al / Ga ratio 5:1, y=0.035, x=2.5, z=0.05.
[0046] Its preparation method comprises steps:
[0047] ①According to the ratio of elements in the chemical formula of the phosphor powder above, after mixing the A-site oxide, Mg oxide, M-site oxide and Eu oxide according to the proportion, at 1400°C, under the mixed atmosphere of nitrogen and hydrogen, Sintering for 4-6h to prepare the intermediate;
[0048] ②Crush the intermediate, mix it with the nitride at the R site and the oxide at the Cr site, sinter at 1600°C in a mixed atmosphere of nitrogen and hydrogen for 4-6 hours, and finally form the target near-infrared after crushing, washing, and sieving Phosphor.
Embodiment 2
[0050] A kind of near-infrared fluorescent powder, its chemical formula is: (Ba, Sr) 1-y Mg(Al, Ga) 10-x-z Si x o 17-x Nx :yEu 2+ , zCr 3 + , Ba / Sr ratio 2:1, Al / Ga ratio 6:1, y=0.035, x=2.5, z=0.05.
[0051] Its preparation method is with embodiment 1.
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