Application method of hydrophobic extractant in cloud point extraction system
An application method and extraction agent technology, which are applied to the application field of hydrophobic extractant in cloud point extraction system, can solve the problem that the hydrophobic extractant cannot be applied, and can simplify the post-processing process, reduce environmental pollution, and reduce post-processing. cost effect
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[0027] 1. Solubilization of extractant Et-Tol-DAPhen
[0028] In order to solubilize the insoluble extractant Et-Tol-DAPhen, the present invention tried several systems, as shown in Table 1. For single micellar solutions in typical CPE systems, such as TX-100 and TX-114, neither can dissolve the extractant. Even adding long-chain alkylimidazolium ionic liquids cannot solve the problem of dissolution. Studies have shown that the use of nonionic surfactants and cationic surfactants to construct mixed micelles can improve the solubility of the extractant, change the charge properties of the micelles, and improve the extraction efficiency. [7-8] . Here, cationic surfactants cetyltrimethylammonium bromide (CTAB) and dioctadecyldimethylammonium chloride (DDAC) were selected to construct mixed micelles with TX-114, respectively. But unfortunately, the extractant still cannot dissolve in the system. The reason may be that the extractant has a large size, strong rigidity, and stron...
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