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Nitrification tail gas treatment method and system

A treatment method and technology of a treatment system are applied in the treatment field of nitrification tail gas, which can solve the problems of consuming large adsorbents or lye, wasting nitric acid raw materials, and high treatment costs, and achieves reduction of nitric acid consumption, treatment cost, and low treatment cost. Effect

Pending Publication Date: 2021-02-19
JIANGSU SINORGCHEM TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nitrogen oxides (NO X ) content is relatively high, the processing cost is higher by the above method, and a large amount of adsorbent or lye is required to be consumed, and it is generally discharged directly after processing, which will cause high consumption of nitric acid in the nitrification system and waste nitric acid raw materials

Method used

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  • Nitrification tail gas treatment method and system

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Effect test

Embodiment 1

[0091] Nitrification tail gas, that is, NO in the tail gas produced by nitrification reaction x The content is 1000mg / m 3 , after the nitrification tail gas is mixed with the waste acid which is circulated in the nitrobenzene production system through the first mixer 3, it enters the acid absorption unit 1 to obtain the first tail gas and the first mixed liquid. The specific components of the waste acid are 68.0wt% sulfuric acid, 0.60wt% nitric acid and 31.4wt% water. Nitrification tail gas flow rate is 30m 3 / h, the waste acid flow rate is 9m 3 / h, the volume ratio of waste acid to nitrification tail gas is 9:30, the absorption temperature of waste acid is 20°C, and the flow rate of the first tail gas is 30m 3 / h. NO in nitrification tail gas x Absorbed by waste acid and converted into nitric acid, NO in the first tail gas x content reduced to 584mg / m 3 , The specific components of the first mixed solution are 67.99wt% sulfuric acid, 0.63wt% nitric acid, and 31.38wt% w...

Embodiment 2

[0095] Nitrification tail gas, that is, NO in the tail gas produced by nitrification reaction x The content is 1500mg / m 3 , after the nitrification tail gas is mixed with the waste acid which is circulated in the nitrobenzene production system through the first mixer 3, it enters the acid absorption unit 1 to obtain the first tail gas and the first mixed liquid. The specific components of the waste acid are 68.0wt% sulfuric acid, 0.5wt% nitric acid and 31.5wt% water. Nitrification tail gas flow rate is 34m 3 / h, the waste acid flow rate is 11m3 / h, the volume ratio of waste acid to nitrification tail gas is 11:34, the absorption temperature of waste acid is 30°C, and the flow rate of the first tail gas is 34m 3 / h. NO in nitrification tail gas x Absorbed by waste acid and converted into nitric acid, NO in the first tail gas x Content reduced to 900mg / m 3 , The specific components of the first mixed solution are 68wt% sulfuric acid, 0.54wt% nitric acid, and 31.46wt% water...

Embodiment 3

[0099] Nitrification tail gas, that is, NO in the tail gas produced by nitrification reaction x The content is 1300mg / m 3 , after the nitrification tail gas is mixed with the waste acid which is circulated in the nitrobenzene production system through the first mixer 3, it enters the acid absorption unit 1 to obtain the first tail gas and the first mixed liquid. The specific components of the waste acid are 67.95wt% sulfuric acid, 0.55wt% nitric acid and 31.5wt% water. Nitrification tail gas flow rate is 37m 3 / h, the waste acid flow rate is 12m 3 / h, the volume ratio of waste acid to nitrification tail gas is 12:37, the absorption temperature of waste acid is 38°C, and the flow rate of the first tail gas is 37m 3 / h. NO in nitrification tail gas x Absorbed by waste acid and converted into nitric acid, NO in the first tail gas x The content is reduced to 806mg / m 3 , The specific components of the first mixed solution are 67.94wt% sulfuric acid, 0.58wt% nitric acid, and ...

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Abstract

The invention relates to the technical field of environmental engineering, in particular to a nitrification tail gas treatment method and system. The invention provides a nitrification tail gas treatment method, which comprises: 1) carrying out a mixing reaction on nitrification tail gas and an acid to obtain first tail gas and a first mixed solution; and 2) mixing the first mixed solution obtained in the step 1) with an extraction agent, performing extracting and separating to obtain an oil phase and an acid phase. The invention provides a nitrification tail gas treatment system, which comprises: an acid absorption unit, which is used for carrying out a mixing reaction on nitrification tail gas and the acid to obtain the first tail gas and the first mixed solution; and an extraction and separation unit is used for carrying out mixing extraction and separation on the first mixed solution and the extraction agent to obtain the oil phase and the acid phase, wherein the acid absorption unit is in fluid communication with the extraction and separation unit. The nitrification tail gas treatment method and system provided by the invention are low in treatment cost and low in consumptionof acid and alkaline solutions or adsorbents, and the treated tail gas can be directly discharged.

Description

technical field [0001] The invention relates to the technical field of environmental engineering, in particular to a treatment method and system for nitrification tail gas. Background technique [0002] With the rapid development of the domestic economy, nitrogen oxides (NO X ) The discharge of pollutants has increased rapidly, seriously polluting the ecological environment, and has become one of the important factors restricting social and economic development. The control of nitrogen oxides has become an urgent requirement for national economic sustainable development and environmental protection. At present, the treatment methods of nitrogen oxides in nitrification tail gas include: using solid adsorbent combined with regeneration means to treat tail gas containing nitrogen oxides; using two-stage hydrogen peroxide to absorb nitrogen oxides in series; using liquid alkali absorption tower to absorb nitrogen oxides, The NOx is transferred to the liquid phase, generating n...

Claims

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Application Information

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IPC IPC(8): B01D53/78B01D53/75B01D53/56B01D53/04B01D11/04C07C201/08C07C205/06
CPCB01D11/04B01D53/04B01D53/56B01D53/75B01D53/78B01D2253/102C07C201/08C07C205/06
Inventor 李祥王林成冯殿兴颜涛李华李风新
Owner JIANGSU SINORGCHEM TECH CO LTD
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