Anti-aging nylon modified elastomer and preparation method thereof

An anti-aging and elastomer technology, applied in the field of anti-aging nylon modified elastomer and its preparation, can solve the problems of poor impact performance, lack of high elasticity of elastomer, weak anti-aging ability, etc., to improve the performance of anti-ultraviolet aging , The effect of nylon elastomer interior fluffy, good deformation recovery performance

Pending Publication Date: 2021-02-26
张文俊
View PDF6 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, nylon is easy to become brittle at low temperature or in a dry state, has poor impact performance, and does not have the high elasticity of elastomers. Therefore, nylon needs to be toughened and modified to improve the impact resistance of nylon.
[0003] Existing nylon elastomers are prepared by thermoplastic elastomers, rarely by hard-segment nylon, and hard-segment nylon has a large output and low cost, and the existing nylon elastomers have weak aging resistance. It is easy to age under the environment, thus affecting the service life
[0004] The patent application number is CN201711417157.4, which proposes a thermoplastic elastomer material for coating glass fiber reinforced nylon and its preparation method. By adjusting the specific material selection and proportion of styrenic block copolymers, the mineral materials are Modification, adjusting the compatibility of each component, the obtained thermoplastic elastomer material, coated with glass fiber reinforced nylon, has strong adhesion, high melt index, good fluidity, and good processing performance. No soft glue residue, can be widely used in the coating of various tool handles of glass fiber reinforced nylon substrate; but its anti-aging performance is poor, only adding anti-aging agent can not achieve good anti-aging ability, for this reason, this The invention proposes an anti-aging nylon modified elastomer and its preparation method

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Anti-aging nylon modified elastomer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A kind of anti-aging nylon modified elastomer that the present invention proposes, is made up of the raw material of following weight part: nylon 6 60 parts, chlorinated butyl rubber 6 parts, 5.5 parts of pine sylvestris lignocellulose, 3.5 parts of flame retardant, 35 parts of naphthenic oil, 30 parts of maleic anhydride grafted polypropylene, 6 parts of graphene, 1.5 parts of o-hydroxybenzophenone derivatives, 1.5 parts of ethylene, 1.3 parts of 2,6-di-tert-butyl-p-cresol , 1.3 parts of antioxidant 1010, 1.3 parts of triethylenediamine, and 1.0 parts of 2,5-furandione.

[0026] A kind of preparation method of aging-resistant nylon modified elastomer that the present invention proposes, comprises the following steps,

[0027] S1, carrying out the polyaddition reaction of the above weight parts of ethylene to form polyethylene, fully mixing the polyethylene and o-hydroxybenzophenone derivatives uniformly to obtain a mixture A;

[0028] S2, mixing the nylon 6, chlorobut...

Embodiment 2

[0033] A kind of anti-aging nylon modified elastomer that the present invention proposes, is made up of the raw material of following parts by weight: nylon 6 78 parts, chlorinated butyl rubber 12 parts, pine sylvestris lignocellulose 7 parts, flame retardant 4.0 parts, 42 parts of naphthenic oil, 33 parts of maleic anhydride grafted polypropylene, 6.2 parts of graphene, 1.6 parts of o-hydroxybenzophenone derivatives, 1.6 parts of ethylene, 1.5 parts of 2,6-di-tert-butyl-p-cresol , 1.5 parts of antioxidant 1010, 1.5 parts of triethylenediamine, and 1.2 parts of 2,5-furandione.

[0034] A kind of preparation method of aging-resistant nylon modified elastomer that the present invention proposes, comprises the following steps,

[0035] S1, carrying out the polyaddition reaction of the above weight parts of ethylene to form polyethylene, fully mixing the polyethylene and o-hydroxybenzophenone derivatives uniformly to obtain a mixture A;

[0036] S2, mixing the nylon 6, chlorobuty...

Embodiment 3

[0041] An anti-aging nylon modified elastomer proposed by the present invention is composed of the following raw materials in parts by weight: 652.5 parts of nylon, 52.5 parts of nylon 66, 20 parts of chlorinated butyl rubber, 15 parts of pine wood cellulose, flame retardant 6 parts of agent, 50 parts of naphthenic oil, 40 parts of maleic anhydride grafted polypropylene, 6.5 parts of graphene, 1.8 parts of o-hydroxybenzophenone derivatives, 1.8 parts of ethylene, 2,6-di-tert-butyl p- 1.7 parts of cresol, 1.7 parts of antioxidant 1010, 1.7 parts of triethylenediamine, and 1.5 parts of 2,5-furandione.

[0042] A kind of preparation method of aging-resistant nylon modified elastomer that the present invention proposes, comprises the following steps,

[0043] S1, carrying out the polyaddition reaction of the above weight parts of ethylene to form polyethylene, fully mixing the polyethylene and o-hydroxybenzophenone derivatives uniformly to obtain a mixture A;

[0044] S2, mixing ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses an anti-aging nylon modified elastomer and a preparation method thereof, and belongs to the field of nylon modified elastomers. The material is prepared from the following rawmaterials in parts by weight: 50-200 parts of hard segment nylon, 5-40 parts of chlorinated butyl rubber, 3-30 parts of pinus sylvestris lignocellulose, 3-10 parts of a functional additive, 35-80 parts of filling oil, 20-70 parts of a compatilizer, 5-10 parts of graphene, 1-3 parts of o-hydroxybenzophenone derivatives, 1-3 parts of ethylene and 1-3 parts of 2,6-butylated hydroxytoluene. The preparation method comprises the following steps: performing a polyaddition reaction on above-mentioned parts by weight of ethylene to to form polyethylene, fully and uniformly mixing polyethylene and an o-hydroxybenzophenone derivative to obtain a mixture A; and mixing the hard segment nylon, the chlorinated butyl rubber, the pinus sylvestris lignocellulose, the filling oil and the compatilizer in parts by weight to obtain a mixture B. The product has the advantages of reasonable components, favorable aging resistance and low cost, and is suitable for popularization and application.

Description

technical field [0001] The invention relates to the technical field of nylon modified elastomers, in particular to an aging-resistant nylon modified elastomer and a preparation method thereof. Background technique [0002] Nylon, as the largest engineering plastic, has a wide variety, has excellent mechanical properties, wear resistance, self-lubricating properties, chemical resistance, oil resistance and solvent resistance, and is widely used in transportation, electronics, machinery and other fields. However, nylon is easily brittle at low temperature or in a dry state, has poor impact performance, and does not have the high elasticity of elastomers. Therefore, it is necessary to toughen nylon to improve the impact resistance of nylon. [0003] Existing nylon elastomers are prepared by thermoplastic elastomers, rarely by hard-segment nylon, and hard-segment nylon has a large output and low cost, and the existing nylon elastomers have weak aging resistance. It is easy to a...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L77/02C08L77/06C08L23/28C08L1/02C08L51/06C08L23/06C08K13/02C08K5/132C08K5/13C08K5/134C08K5/3462C08K3/04C08K5/1535C08F110/02
CPCC08L77/02C08L77/06C08F110/02C08L2205/035C08L2201/08C08L2205/02C08L23/283C08L1/02C08L51/06C08L23/06C08K13/02C08K5/132C08K5/13C08K5/1345C08K5/3462C08K3/042C08K5/1535
Inventor 张文俊
Owner 张文俊
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products