Environment-friendly die-casting aluminum alloy anode oxide film and environment-friendly preparation process thereof

A technology of anodic oxidation film and cast aluminum alloy, which is applied in the direction of anodic oxidation, electrolytic coating, surface reaction electrolytic coating, etc., and can solve problems such as cracks in the oxide film, decrease in the quality of the oxide film, and insufficient strength

Inactive Publication Date: 2021-03-12
江苏航运职业技术学院
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the existing preparation process, the non-aluminum elements contained in the die-casting aluminum alloy will lead to a decrease in the quality of the oxide film, insufficient strength, and cracks on the surface of the oxide film during the anodic oxidation process. In the subsequent use process, if the ambient temperature is too high , will lead to uneven thermal stress in the oxide layer, causing cracking of the film layer, which needs to be improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0026] The preparation method of the die-casting aluminum alloy comprises the following steps:

[0027] Step 1: According to mass percentage: Mg: 3.0~6.0wt%, Zn: 2.5~4.5wt%, Si: 1.0~2.5wt%, Mn: 0.5~1.0wt%, Cr: 0.3~0.8wt%, the balance is Al, after weighing the raw material Mg, the raw material Zn, the raw material Si, the raw material Mn, the raw material Cr, and the raw material Al, melting is carried out to obtain a molten metal;

[0028] Step 2: adding a refining agent to the molten metal for refining, and stirring the molten metal during the refining process;

[0029] Step 3: removing impurities from the refined molten metal and then casting it to obtain an aluminum alloy ingot, melting the aluminum alloy ingot and then die-casting it to obtain a die-cast aluminum alloy.

[0030] The smelting temperature in the step 1 is 720-780° C., and the melting time is 30-45 minutes.

[0031] The refining agent in the step 2 is one or a combination of zinc chloride, manganese chlorid...

Embodiment 1

[0042] According to mass percentage: Mg: 3.0~6.0wt%, Zn: 2.5~4.5wt%, Si: 1.0~2.5wt%, Mn: 0.5~1.0wt%, Cr: 0.3~0.8wt%, the balance is Al, for The raw material Mg, raw material Zn, raw material Si, raw material Mn, raw material Cr, and raw material AL are weighed and smelted to obtain a molten metal, wherein the melting temperature is 720-750°C and the time is 35 minutes;

[0043] Add a refining agent to the molten metal for refining, and stir the molten metal during the refining process, wherein the refining agent is zinc chloride and manganese chloride, and the stirring speed is 30r / min;

[0044] Purifying the refined molten metal and then casting it to obtain an aluminum alloy ingot, melting the aluminum alloy ingot and then die-casting it to obtain a die-cast aluminum alloy;

[0045] Grinding and degreasing the die-casting aluminum alloy to obtain pretreated workpieces;

[0046] The pretreated workpiece is immersed in the electrolyte as an anode, and anodized with an externa...

Embodiment 2

[0051] According to mass percentage: Mg: 3.0wt%, Zn: 3.5wt%, Si: 2.0wt%, Mn: 0.5wt%, Cr: 0.4wt%, the balance is Al, for raw material Mg, raw material Zn, raw material Si, raw material Mn, raw material Cr, and raw material AL are weighed and smelted to obtain molten metal, wherein the smelting temperature is 740-770°C and the time is 35 minutes;

[0052] Add a refining agent to the metal melt for refining, and stir the melt during the refining process, wherein the refining agent is zinc chloride and manganese chloride, and the stirring speed is 45r / min;

[0053] Purifying the refined molten metal and then casting it to obtain an aluminum alloy ingot, melting the aluminum alloy ingot and then die-casting it to obtain a die-cast aluminum alloy;

[0054] Grinding and degreasing the die-casting aluminum alloy to obtain pretreated workpieces;

[0055] The pretreated workpiece is immersed in the electrolyte as an anode, and anodized with an external power supply to form an oxide lay...

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Abstract

The invention discloses an environment-friendly die-casting aluminum alloy anode oxide film and an environment-friendly preparation process thereof. The environment-friendly die-casting aluminum alloyanode oxide film comprises die-casting aluminum alloy used for anodic oxidation, and the die-casting aluminum alloy comprises 3.0 wt%-6.0 wt% of Mg, 2.5 wt%-4.5 wt% of Zn, 1.0 wt%-2.5 wt% of Si, 0.5wt%-1.0 wt% of Mn, 0.3 wt%-0.8 wt% of Cr and the balance Al. The preparation method of the die-casting aluminum alloy comprises the following steps that 1, the raw materials comprising 3.0 wt%-6.0 wt%of Mg, 2.5 wt%-4.5 wt% of Zn, 1.0 wt%-2.5 wt% of Si, 0.5 wt%-1.0 wt% of Mn, 0.3 wt%-0.8 wt% of Cr and the balance Al are weighed and melt. The strength of the oxide film can be remarkably improved through a post-treatment process of firstly heat-sealing and then cold-sealing the oxide film, and in the preparation process of the die-casting aluminum alloy, molten metal is refined and matched withthe post-treatment process, so that the surface microstructure of the oxide film can be improved, cracks are reduced, and therefore, during heating, non-uniform thermal stress is prevented from beinggenerated in an oxide film layer, and cracking of the film layer is avoided.

Description

technical field [0001] The invention relates to an aluminum alloy anodized film, in particular to an environment-friendly die-casting aluminum alloy anodized film and an environment-friendly preparation process thereof. Background technique [0002] In order to overcome the defects of aluminum alloy surface hardness, wear resistance, etc., expand the scope of application, and prolong the service life, surface treatment technology has become an indispensable part of the use of aluminum alloys, and anodizing technology is the most widely used and most successful , Anodizing refers to the electrochemical oxidation of metals or alloys. The process of forming an oxide film on an aluminum product (anode) under the corresponding electrolyte and specific process conditions of aluminum and its alloys under the action of an applied current. Anodic oxidation, if not specified, usually refers to the sulfuric acid anode oxidation. [0003] In the existing preparation process, the non-a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C21/08C22C21/10C22C1/02C22C1/06C25D11/04C25D11/18C25D11/24
CPCC22C1/026C22C1/06C22C21/08C22C21/10C25D11/04C25D11/18C25D11/246
Inventor 凌付平曹将栋蒋坤松黄诚张丽娜黄亮
Owner 江苏航运职业技术学院
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