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Pasty organic peroxide cross-linking agent and compounding process thereof

An organic peroxide and cross-linking agent technology, which is applied in the field of pasty organic peroxide cross-linking agent and its compounding process, can solve the problems of poor product uniformity, unstable system, uneven dispersion, etc., and achieve convenient Transportation and use, excellent physical stability, excellent effect of physical stability

Pending Publication Date: 2021-03-19
SHANDONG YANGGU HUATAI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Water is the most common and cheap desensitizer, but after high-purity organic peroxides are dispersed in water, system instability such as settling and floating often occurs, resulting in poor product uniformity and affecting product use
At the same time, simply dispersing high-purity organic peroxides into water, since the subsequent reaction system is usually in an organic environment, it is easy to cause the problem of uneven dispersion during use
Moreover, when the ambient temperature is lower than 0°C, the water is easy to freeze, resulting in an increase in the relative concentration of high-purity organic peroxides and increased risk.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] A compounding process of a pasty organic peroxide type crosslinking agent, comprising the following steps:

[0030] Step 1, mix dibenzoyl peroxide and water according to the ratio of 47% to 53% by weight of dibenzoyl peroxide and 14% to 18% of water to prepare dibenzoyl peroxide and water mixture, spare;

[0031] Step 2: Add 20% to 24% phlegmatizer by weight to the mixture of dibenzoyl peroxide and water in step 1, turn on the stirring device, and stir for 0.5h to 1.0h at a speed of 2000r / min to 2500r / min , stir evenly, make the mixture of dibenzoyl peroxide, water and phlegmatizer, set aside;

[0032] Step 3, add 0.1% to 2.0% of nonionic surfactant and 4% to 15% of inorganic filler by weight into the mixture of dibenzoyl peroxide, water and phlegmatizer in step 2, and start the emulsifier for emulsification , continue for 1.0h to 3.0h to obtain an emulsion;

[0033] Step 4: add a phlegmatizer to the emulsified product in step 3 by weight, so that the phlegmatizer is...

Embodiment 2

[0039] A compounding process of a pasty organic peroxide type crosslinking agent, comprising the following steps:

[0040] Step 1, mix dibenzoyl peroxide and water according to the ratio of 47% to 53% by weight of dibenzoyl peroxide and 14% to 18% of water to prepare dibenzoyl peroxide and water mixture, spare;

[0041] Step 2, adding 20% ​​to 26% of phlegmatizer by weight to the mixture of dibenzoyl peroxide and water in step 1, stirring evenly to make a mixture of dibenzoyl peroxide, water and phlegmatizer, spare;

[0042] Step 3, adding 0.1% to 2.0% of nonionic surfactant and 4% to 15% of inorganic filler by weight into the mixture of dibenzoyl peroxide, water and phlegmatizer in step 2, and emulsifying to obtain Paste organic peroxide crosslinking agent.

[0043] During compounding, turn on the temperature control device and keep the system temperature at 20°C to 25°C.

[0044] The above-mentioned nonionic surfactant refers to a polyether type nonionic surfactant, whic...

Embodiment 3

[0048] A compounding process of a pasty organic peroxide type crosslinking agent, comprising the following steps:

[0049] Step 1, the dibenzoyl peroxide and water are mixed in advance, the content of dibenzoyl peroxide is 75% (by weight), and the others are moisture to make a mixture of dibenzoyl peroxide and water, spare;

[0050]Step 2, in the 5L enamel reactor that common emulsifying machine, agitator are equipped with, add 2680g dibenzoyl peroxide and water mixture (water content rate 25%), 920g acetyl tributyl citrate in step 1, Turn on the stirring device, according to the rotating speed of 2200r / min, stir for 0.6h, stir evenly, make a mixture of dibenzoyl peroxide, water and acetyl tributyl citrate, set aside;

[0051] Step 3, add 80g polyether type nonionic surfactant PluronicRPE, 240g nano-calcium carbonate by weight in the mixture of dibenzoyl peroxide, water and acetyl tributyl citrate in step 2, open the emulsifier and emulsify , continued for 2.0h to obtain an ...

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Abstract

The invention discloses a pasty organic peroxide cross-linking agent, belongs to the technical field of peroxide cross-linking agents, and particularly relates to a pasty organic peroxide cross-linking agent and a compounding process thereof. The pasty organic peroxide cross-linking agent is characterized by comprising the following components by weight: 47%-53% of dibenzoyl peroxide, 14%-18% of water, 0.1%-2.0% of a non-ionic surfactant, 20%-26% of a desensitizer and 4%-15% of inorganic filler. The pasty organic peroxide cross-linking agent provided by the invention has the positive effects of uniform product, no layering, convenient transportation and use, safety and reliability.

Description

technical field [0001] The invention belongs to the technical field of peroxide crosslinking agents, in particular to a pasty organic peroxide crosslinking agent and its compounding process. Background technique [0002] High-purity organic peroxides are extremely sensitive to heat, shock, impact and friction, and are easily decomposed, producing a large amount of methane, ethane, acetone, carbon dioxide and other gases. The pressure of destroying the package can easily lead to explosion and fire. In order to ensure the safety of organic peroxides in use and storage, auxiliary materials such as phlegmatizers and stabilizers are usually added to high-purity organic peroxides to form a mixture with stable properties and uniform texture. Water is the most common and cheap phlegmatizer, but after high-purity organic peroxides are dispersed in water, system instability such as settling and floating often occurs, resulting in poor product uniformity and affecting product use. At...

Claims

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Application Information

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IPC IPC(8): C08K5/14C08K3/26C08K3/36C08K3/34C08K5/11C08L23/20C08L23/16C08L83/04
CPCC08K5/14C08K3/26C08K3/36C08K3/346C08K5/11C08L23/22C08L23/16C08L83/04C08K2003/265
Inventor 王文博李庆朝杜孟成马德龙李剑波黄存影
Owner SHANDONG YANGGU HUATAI CHEM
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