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Method for controlling ferrite content of nitrogen-controlled austenitic stainless steel forge piece

A technology of austenitic stainless steel and a control method, applied in the field of iron and steel metallurgy, can solve the problems of excessive ferrite content in materials, reducing ferrite content, affecting product use, etc., to achieve good product quality, reduce smelting costs, and yield. high effect

Pending Publication Date: 2021-04-16
ZHONGXING ENERGY EQUIP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Many components in the nuclear island equipment are made of austenitic stainless steel, such as reactor internals, some parts in the drive mechanism, the main pipeline of the primary circuit, and the casings of some pumps and valves. There are strict requirements (≤2%). If the chemical composition and processing technology cannot be reasonably controlled, the ferrite content of the material will exceed the standard and affect the use of the product. Therefore, what stable and effective process measures should be adopted to ensure the ferrite content of the product? It is very important to qualify
[0003] For controlling the ferrite content of austenitic stainless steel forgings, the traditional method is to control the content of each element in the chemical composition during smelting, and calculate the ferrite content to be ≤2%, but increasing the electrolytic nickel will increase the smelting cost. For this reason, the patent No. CN104250673A proposes a smelting process for reducing the ferrite content of nuclear-grade stainless steel castings, reducing the ferrite content with a small amount of nitrogen, and adding 0.01-0.015% of nitrogen can reduce the ferrite by 0.7-1% content

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] 1. Electric furnace smelting: melting raw and auxiliary materials to obtain molten steel;

[0028] 2. AOD refining: Refining the molten steel with an argon-oxygen furnace, controlling the melting chemical composition C: 0.025%, Si: 0.46%, Mn: 1.70%, Ni: 9.10%, Cr: 19.60%, N0.059%, and the balance is Fe and unavoidable impurity elements. The calculated ferrite content is 10.0%. After refining, the molten iron is cast into φ480 / φ490 electrode rods;

[0029] 3. ESR remelting: further refine the electrode rods of φ480 / φ490, and refine them into electroslag ingots of φ720 / φ730;

[0030] 4. Forging: Heat the φ720 / φ730 electroslag ingot at a heating rate of 90°C / h. After reaching 1170°C, keep it warm for 465 minutes. After the heat preservation is completed, it is out of the furnace for forging. Using hydraulic press or hammer forging, the final forging temperature is 820℃. After forging, it is quenched by flowing water to obtain φ230 forgings;

[0031] 5. Heat treatment:...

Embodiment 2

[0034] 1. Electric furnace smelting: melting raw and auxiliary materials to obtain molten steel;

[0035] 2. AOD refining: Refining the molten steel with an argon-oxygen furnace, controlling the melting chemical composition C: 0.025%, Si: 0.46%, Mn: 1.79%, Ni: 9.20%, Cr: 19.40%, N0.065%, and the balance is Fe and unavoidable impurity elements. The calculated ferrite content is 7.9%, and the molten iron is cast into a φ480 / φ490 electrode rod after refining;

[0036] 3. ESR remelting: further refine the electrode rods of φ480 / φ490, and refine them into electroslag ingots of φ720 / φ730;

[0037] 4. Forging: Heat the φ720 / φ730 electroslag ingot at a heating rate of 85°C / h. After reaching 1165°C, keep the heat for 460 minutes. After the heat preservation is completed, it is out of the furnace for forging. Using hydraulic press or hammer forging, the final forging temperature is 815℃. After forging, it is quenched by flowing water to obtain φ230 forgings;

[0038] 5. Heat treatme...

Embodiment 3

[0041] 1. Electric furnace smelting: melting raw and auxiliary materials to obtain molten steel;

[0042] 2. AOD refining: Refining the molten steel with an argon-oxygen furnace, controlling the smelting chemical composition C: 0.028%, Si: 0.42%, Mn: 1.74%, Ni: 9.30%, Cr: 19.31%, N0.063%, calculated ferrite The volume content is 6.8%. After refining, the molten iron is cast into a φ480 / φ490 electrode rod;

[0043] 3. ESR remelting: further refine the electrode rods of φ480 / φ490, and refine them into electroslag ingots of φ720 / φ730;

[0044] 4. Forging: Heat the φ720 / φ730 electroslag ingot at a heating rate of 90°C / h. After reaching 1180°C, keep it warm for 455 minutes. After the heat preservation is completed, it is out of the furnace for forging. Using hydraulic press or hammer forging, the final forging temperature is 812℃. After forging, it is quenched by flowing water to obtain φ230 forgings;

[0045] 5. Heat treatment: place the obtained forgings in a resistance furnac...

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Abstract

The invention discloses a method for controlling ferrite content of a nitrogen-controlled austenitic stainless steel forge piece. The method comprises the following steps of controlling the following components of, in percentage by weight, less than or equal to 0.030% and larger than or equal to 0.025% of C, less than or equal to 0.50% and larger than or equal to 0.40% of Si, less than or equal to 1.90% and larger than or equal to 1.70% of Mn, 9.00-10.00% of Ni, 18.50-20.00% of Cr, less than or equal to 0.080% and larger than or equal to 0.050% of N and the balance Fe and inevitable impurity elements, calculating the ferrite content to be 4% to 10%, and carrying out electric furnace smelting, AOD refining and ESR remelting to obtain the austenitic stainless steel electroslag ingot; then conducting heating at the temperature rising speed smaller than or equal to 100 DEG C / h, conducting heat preservation for not less than 0.6 min / mm when the temperature reaches 1160-1200 DEG C, and using flowing water for quenching after forging; and increasing the temperature to 1050-1070 DEG C for heat preservation for 1-1.2 min / mm, using flowing water for quenching, and obtaining the austenitic stainless steel forge piece with the ferrite content smaller than or equal to 2%. According to the method, the use requirements of key parts in nuclear power equipment are met.

Description

technical field [0001] The invention belongs to the technical field of iron and steel metallurgy, and in particular relates to a method for controlling the ferrite content of a nitrogen-controlled austenitic stainless steel forging. Background technique [0002] Many components in the nuclear island equipment are made of austenitic stainless steel, such as reactor internals, some parts in the drive mechanism, the main pipeline of the primary circuit, and the casings of some pumps and valves. There are strict requirements (≤2%). If the chemical composition and processing technology cannot be reasonably controlled, the ferrite content of the material will exceed the standard and affect the use of the product. Therefore, what stable and effective process measures should be adopted to ensure the ferrite content of the product? Qualification is even more critical. [0003] For controlling the ferrite content of austenitic stainless steel forgings, the traditional method is to co...

Claims

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Application Information

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IPC IPC(8): C22C33/04C22C38/00C22C38/02C22C38/58B21J5/00C21D6/00
Inventor 仇云龙朱卫飞孙振平姜志军柳子平崔斌
Owner ZHONGXING ENERGY EQUIP