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Dispersion method of nano magnesium oxide, nano magnesium oxide expanding agent and application of nano magnesium oxide expanding agent in preparation of expanding cement base material

A technology of nano-magnesium oxide and expansive cement, which is applied in the dispersion of nano-magnesium oxide, the application in the preparation of expansive cement base material, and the field of nano-magnesium oxide expansion agent, which can solve the problem that the expansion performance of magnesia cannot be effectively exerted, and the expansion of cement-based materials Slow development, reduced mechanical properties and other problems, to achieve the effect of improving shrinkage cracking, uniform and stable dispersion, and compensating shrinkage deformation

Active Publication Date: 2021-04-30
南通鸿钜材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The nano-magnesia expansion agent prepared by this method has not been dispersed, which will easily cause particle agglomeration, and the expansion performance of magnesium oxide cannot be effectively exerted, which will easily lead to the slow expansion of cement-based materials in the early stage and the reduction of mechanical properties in the later stage.

Method used

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  • Dispersion method of nano magnesium oxide, nano magnesium oxide expanding agent and application of nano magnesium oxide expanding agent in preparation of expanding cement base material
  • Dispersion method of nano magnesium oxide, nano magnesium oxide expanding agent and application of nano magnesium oxide expanding agent in preparation of expanding cement base material
  • Dispersion method of nano magnesium oxide, nano magnesium oxide expanding agent and application of nano magnesium oxide expanding agent in preparation of expanding cement base material

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] (1) Dispersion of nano-magnesia: take 3.2g dispersant polycarboxylate superplasticizer (purchased from Jilong Chemical Building Materials Co., Ltd.) in a beaker, add 400g distilled water in the beaker, then get 16.0g nano-magnesia and add it to the beaker; After stirring with a glass rod, the mixed solution was dispersed with a heat-collecting magnetic stirrer (the magnetic stirrer was purchased from Hunan Frontier Technology Co., Ltd., the model is photosynthetic DF-101S), the rotating speed was 600 rpm, the power was 40W, and the stirring time was 5min; Immediately after stirring and dispersing, carry out ultrasonic ice-bath dispersion (ultrasonic disperser is purchased from Hunan Frontier Technology Co., Ltd., FS-750T type), dispersing power is 50W, dispersing time is 5min, and the limit temperature is 35°C. The SEM image of nano-magnesium oxide expansion agent is prepared. Such as figure 1 As shown, the size of nano magnesium oxide is 50nm, and no aggregation occurs...

Embodiment 2

[0056] (1) Dispersion of nano-magnesia: get 4.0g dispersant polycarboxylate superplasticizer (purchased from Jilong Chemical Building Materials Co., Ltd.) in a beaker, add 600g distilled water in the beaker, then get 40g nano-magnesia and add in the beaker; After the glass rod was stirred, the mixed solution was dispersed by a heat-collecting magnetic stirrer (the magnetic stirrer was purchased from Hunan Frontier Technology Co., Ltd., the model is photosynthetic DF-101S), the rotating speed was 800 rpm, the power was 40W, and the stirring time was 10 min; Immediately after dispersion, ultrasonic ice bath dispersion was carried out (ultrasonic disperser was purchased from Hunan Frontier Technology Co., Ltd., FS-750T type), the dispersion power was 50W, the dispersion time was 10min, and the limit temperature was 40°C to prepare the nano-magnesia expansion agent;

[0057] (2) Preparation of expansive concrete: According to JGJ55-2011 "Ordinary Concrete Mixing Design Regulations"...

Embodiment 3

[0062] (1) Dispersion of nano-magnesia: take 2.0g dispersant polycarboxylate superplasticizer (purchased from Jilong Chemical Building Materials Co., Ltd.) in a beaker, add 350g distilled water in the beaker, then take 8.8g nano-magnesia and add it to the beaker; After stirring with a glass rod, the mixed solution was dispersed by a heat-collecting magnetic stirrer (the magnetic stirrer was purchased from Hunan Frontier Technology Co., Ltd., the model is photosynthetic DF-101S), the rotating speed was 900 rpm, the power was 40W, and the stirring time was 5min; Immediately after stirring and dispersing, carry out ultrasonic ice-bath dispersion (ultrasonic disperser is purchased from Hunan Frontier Technology Co., Ltd., FS-750T type), dispersing power is 60W, dispersing time is 8min, and the limit temperature is 40°C to prepare nano-magnesium oxide expansion agent;

[0063] (2) Preparation of expansive cement mortar: According to GB / T17671-1999 "Cement Mortar Strength Test Method...

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Abstract

The invention discloses a dispersion method of nano magnesium oxide, which comprises the following steps of uniformly mixing nano magnesium oxide, a polycarboxylate superplasticizer and water to obtain a mixed solution, dispersing the nano magnesium oxide in the mixed solution by magnetic stirring, and dispersing by ultrasonic wave to obtain the nano magnesium oxide expanding agent. The invention also provides a nano magnesium oxide expanding agent prepared by the dispersion method of nano magnesium oxide and application of the expanding agent in preparation of expanding cement. The application comprises the following steps of adding the nano magnesium oxide expanding agent into a cement base material, and stirring and mixing to obtain the expanding cement base material. The prepared nano magnesium oxide expanding agent can effectively improve the expanding effect of cement, improve the dry shrinkage cracking phenomenon of the cement, and improve the crack resistance and mechanical properties of the cement.

Description

technical field [0001] The invention relates to the application of nano-magnesia, in particular to a dispersion method of nano-magnesia, a nano-magnesia expansion agent and its application in preparing expansive cement substrates. Background technique [0002] Traditional cement has the disadvantages of high heat of hydration, large dry shrinkage, and poor crack resistance. Therefore, traditional cement-based materials often have problems of easy fracture and micro-crack spalling, resulting in poor durability, safety and functionality of concrete structures, and a short life cycle. In order to improve the drying shrinkage and cracking of concrete structures, adding expansion agent is an effective way to improve the crack resistance of cement-based materials, but it is easy to cause the deterioration of the mechanical properties of cement-based materials. [0003] Magnesium oxide in cement clinker has low activity due to high calcination temperature, and the external additio...

Claims

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Application Information

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IPC IPC(8): C04B22/06C04B28/04
CPCC04B40/0046C04B28/04C04B22/066C04B2103/302C04B18/08C04B18/141C04B14/06C04B14/02C04B18/146
Inventor 施韬顾元刘艳明
Owner 南通鸿钜材料科技有限公司
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