Multi-layer polymer dispersed liquid crystal film prepared by adopting prism method and preparation method of multilayer polymer dispersed liquid crystal film
A technology for dispersing liquid crystals and polymers, which is applied in optics, instruments, nonlinear optics, etc. It can solve the problems of high driving voltage, slow response time, low contrast, etc., and achieve good absorption, fast response speed, and improved service life.
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[0035] This embodiment provides a multi-layered polymer-dispersed liquid crystal film prepared by a prism method and a preparation method thereof. The film includes a colorless polyimide that contains nano-copper wires on one side and a composite nano-silver wire on the lower side from top to bottom. A transparent film, a liquid crystal layer containing an ultraviolet absorber and a polymer network, and a colorless polyimide transparent film containing nano-copper wire composite nano-silver wires on one side on the upper side, the preparation method thereof specifically includes the following steps:
[0036] First, preparation of colorless polyimide transparent film
[0037] Mix 20-40g of biphenyltetracarboxylic dianhydride and 2-16g of p-phenylenediamine, then add 300-600mL of dry p-chlorophenol solvent, stir at a speed of 300-1200r / min for 20-60min, and then heat up To 150-300 ℃, reflux reaction for 3-5 hours to obtain a polyimide solution; perform salivation film formation ...
Embodiment 1
[0052] This embodiment provides a multi-layered polymer-dispersed liquid crystal film prepared by a prism method and a preparation method thereof. The film includes a colorless polyimide transparent film containing nano-copper wires composite nano-silver wires on the lower side, A liquid crystal layer containing an ultraviolet absorber and a polymer network and a colorless polyimide transparent film containing nano-copper wire composite nano-silver wires on the upper side, the preparation method specifically includes the following steps:
[0053] First, preparation of colorless polyimide transparent film
[0054] Mix 20g of biphenyltetracarboxylic dianhydride and 2g of p-phenylenediamine, then add 300mL of dry p-chlorophenol solvent, stir at a speed of 300r / min for 20min, then raise the temperature to 150°C, and reflux for 3h to obtain polyamide Imine solution; perform salivation film formation on the substrate, the process controls the volatilization temperature at 10°C, remo...
Embodiment 2
[0069] This embodiment provides a multi-layered polymer-dispersed liquid crystal film prepared by a prism method and a preparation method thereof. The film includes a colorless polyimide transparent film containing nano-copper wires composite nano-silver wires on the lower side, A liquid crystal layer containing an ultraviolet absorber and a polymer network, and a colorless polyimide transparent film containing a nano-copper wire composite nano-silver wire on the upper side, the preparation method specifically includes the following steps:
[0070] First, preparation of colorless polyimide transparent film
[0071] Mix 25g of biphenyltetracarboxylic dianhydride and 4g of p-phenylenediamine, then add 350mL of dry p-chlorophenol solvent, stir at a speed of 500r / min for 30min, then raise the temperature to 180°C, and reflux for 4h to obtain polyamide Imine solution; perform salivation film formation on the substrate, the process controls the volatilization temperature at 20°C, re...
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Abstract
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