Quick-bonding UV/moisture dual-curing adhesive and preparation method thereof
A dual-curing, adhesive technology, used in adhesives, adhesive types, adhesive additives, etc., can solve the problem that two-component structural adhesives and PUR hot-melt adhesives cannot achieve instant bonding and positioning, double-sided adhesive Insufficient relay, etc.
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Embodiment 1
[0024] Example 1: Synthesis of UV / Moisture Dual Curing Urethane Acrylic Resin
[0025] 50.0 parts of PPG-2000 (polyether diol, Dow, USA) were dehydrated under vacuum at 110°C for 2 hours, and the temperature was lowered to 70°C. Added 30 parts of polymeric MDI (8319, Yantai Wanhua), 0.01 parts of Butyl tin, reacted for 2 hours. Add 2.0 parts of hydroxyethylacrylamide and continue the reaction for 2 hours. After vacuum defoaming for 0.5 hour, a UV / moisture dual-curing polyurethane acrylic resin (named as resin 1) was obtained.
Embodiment 2
[0026] Example 2: Synthesis of UV / Moisture Dual Curing Urethane Acrylic Resin
[0027] 56.0 parts of PCL220 (polycaprolactone diol, Daicel Corporation, Japan) were vacuum dehydrated at 110°C for 2 hours, the temperature was lowered to 70°C, 40 parts of polymeric MDI (8319, Yantai Wanhua), 0.01 parts of dilauric acid di Butyl tin, reacted for 2 hours. 4.0 parts of hydroxyethylacrylamide was added, and the reaction was continued for 2 hours. After vacuum defoaming for 0.5 hour, a UV / moisture dual-curing polyurethane acrylic resin (named as resin 2) was obtained.
Embodiment 3
[0031] Mix the following compounds uniformly under vacuum conditions: 30.0 g of monofunctional urethane acrylic resin (GENOMER*4188, RAHN company), 15.0 g of UV / moisture dual curing urethane acrylic resin (self-made resin 1), 4.5 g of isooctyl acrylate , fumed silica (TS720, Cabot Corporation) 1.0 g, photoinitiator (ethyl 2,4,6-trimethylbenzoylphenylphosphonate) 1.5 g, dibutyltin dilaurate 0.01 g. Apply the mixed raw materials on the glass sample strip, use LED lamp (365nm, curing energy is 2000mJ / cm 2 ) after irradiation, attach the glass sample strips to test the initial adhesive force and the adhesive force after moisture curing.
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