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793results about How to "No heating required" patented technology

Normal-temperature synthesis method for polycarboxylic acid water-reducing agent

The invention discloses a normal-temperature synthesis method for a polycarboxylic acid water-reducing agent, and belongs to the field of cement concrete water-reducing agents. The water-reducing agent is prepared by the following steps of: copolymerizing polyoxyethylene ether monomer or polyoxyethylene ester monomer a containing unsaturated double bonds, unsaturated monocarboxylic acid and derivative monomer thereof b, unsaturated dicarboxylic acid c and unsaturated sulfonic acid or salt monomer thereof d in aqueous solution under the action of an oxidation reduction initiator, and finally neutralizing the solution by using alkali solution to obtain the water-reducing agent. The reaction can be performed at room temperature by adopting an oxidation reduction initiating system, and the appropriate reaction temperature is between 5 and 30 DEG C; and the synthesis process does not need heating, so energy is saved, and high-temperature side reaction is effectively controlled. The prepared polycarboxylic acid high-performance water-reducing agent has the characteristics of high water-reducing rate and good collapse protecting performance. The water-reducing agent has wide application range, and the method has low production process requirement and is suitable for industrialized large-scale production.
Owner:BEIJING UNIV OF TECH

Waterproof system for basement bottom board and wall surface and construction method thereof

The invention relates to a waterproof system for a basement bottom board and a wall surface and a construction method thereof. The construction method comprises the steps of: horizontally spreading and pasting a self-adhesive rubber bituminous waterproof sheet material on a concrete base layer, and building up a brick permanent protection wall outside a preset position of a basement wall surface, wherein the bottom of the brick permanent protection wall is vertically connected with the concrete base layer, the self-adhesive rubber bituminous waterproof sheet material spreads over corners of the basement wall surface and then is upward folded to be spread and pasted on the water attaining surface of the brick permanent protection wall, then the self-adhesive rubber bituminous waterproof sheet material is lapped with another self-adhesive rubber bituminous waterproof sheet material pasted above the brick permanent protection wall, a self-adhesive rubber bituminous waterproof sheet material is pasted on an outer vertical surface of the basement wall surface. The construction method has the advantages of strong construction continuity, fast speed, good construction environment, low cost and the like, eliminates the hidden danger of fire since the heating is avoided in the construction process, is safe and reliable, completely changes and improves the traditional waterproof construction environments and the waterproof construction technology. The waterproof system can be widely applied in basements, underground structures and roofs.
Owner:CHINA CONSTR SECOND ENG BUREAU LTD

Method for recycling palladium from silver electrolyte by using dimethylglyoxime

The invention discloses a method for recycling palladium from a silver electrolyte by using dimethylglyoxime. The method comprises the following steps: adding dimethylglyoxime into a palladium-containing electrolyte for precipitating palladium; performing solid-liquid separation, returning filtrate as an electrolyte, and eluting filter residue with nitric acid acidification water to obtain a dimethylglyoxime palladium crude product; dissolving the dimethylglyoxime palladium crude product with aqua regia, and then precipitating palladium with ammonium chloride; eluting an obtained ammonium chloropalladate precipitate with an ammonium chloride solution until filtrate is colorless; and adding water, heating, and dissolving; filtering, and cooling filtrate; adding ammonia water, complexing and dissolving; cooling, filtering, and eluting the filter residue with ammonia water; adding hydrochloric acid for acidifying filtrate; filtering to obtain a diammonium dichloropalladite precipitate; and reducing the precipitate by hydrazine hydrate to obtain palladium sponge with the grade of 99.99%. Heating and pH regulation are not required, and only quantitative precipitation of palladium is required; the selectivity is good; and the precipitated dimethylglyoxime palladium can achieve a very high purity after simple eluting, so that the palladium purifying process is greatly shortened and the palladium recycling rate is improved; the using amount of dimethylglyoxime is low; and except a small amount of ethanol, other ions are not brought, so that the reuse of the electrolyte is not affected.
Owner:SIHUI CITY HONGMING PRECIOUS METALS

Metallographic corrosion method for martensitic precipitation hardening stainless steel crystal boundary

The invention discloses a metallographic corrosion method for a martensitic precipitation hardening stainless steel crystal boundary, wherein the stainless steel is 05Cr17Ni4Cu4Nb martensitic precipitation hardening stainless steel. The method comprises the following steps: 1, coarsely grinding, finely grinding, polishing, cleaning and drying a metallographic sample to obtain a shine scratch-freepolished surface; and 2, picking up a corrosive agent, wiping the polished surface for 15-20s, flushing, and drying, wherein the corrosive agent is prepared by pouring 2-3ml of concentrated hydrochloric acid into 30ml of concentrated nitric acid, uniformly stirring and allowing the obtained solution to stand for above 5min. According to the invention, the 05Cr17Ni4Cu4Nb martensitic precipitation hardening stainless steel crystal boundary can be intelligibly and completely displayed, and the color and the morphology of the tissue have no influences on the observation of the contour of the crystal boundary. The method has the following advantages: the crystal boundary display effect is excellent; normal temperature corrosion and no need of heating are realized; and the corrosion time is short, and only 15-20 seconds are needed.
Owner:725TH RES INST OF CHINA SHIPBUILDING INDAL CORP

Clay-resisting slow-release slump-retaining type polycarboxylate superplasticizer and preparation method thereof

InactiveCN109626859AStrong adsorption capacity and dispersion performanceImprove dispersionCarboxylic esterDibasic acid
The invention relates to the technical field of concrete admixtures, in particular to a clay-resisting slow-release slump-retaining type polycarboxylate superplasticizer and a preparation method thereof. With polyether macromonomers, unsaturated carboxylic acid, unsaturated carboxylic ester, dibasic acid anhydride, a crosslinking agent, amide monomers, unsaturated phosphate ester, phosphate, an oxidizing agent , a reducing agent, a chain transfer agent, a neutralizing agent and water as raw materials, the clay-resisting slow-release slump-retaining type polycarboxylate superplasticizer is synthesized at normal temperature. Ester groups, amide groups and phosphate ester are introduced into the molecular structure of the polycarboxylate superplasticizer, and light crosslinking of the polycarboxylate superplasticizer is realized through the long-chain ester crosslinking agent, so that the superplasticizer has a good clay-resisting and slump-retaining effect and has the advantages of low mixing amount, high water reducing rate, high adaptability to clay-containing sand, good slump retaining performance and the like; besides, only normal-temperature polymerization is needed, the processis simple, the production cost is low, and the superplasticizer is suitable for industrial production.
Owner:山西黄河新型化工有限公司

Method for recycling base oil of waste liquid of oil-based drilling liquid

The invention relates to a method for recycling base oil of the waste liquid of an oil-based drilling liquid, and in particular belongs to a solid-liquid separation technique in the technical field of waste oil-based drilling liquid treatment. The method comprises the following steps of: (1) preparing a composite demulsifying agent, namely compounding AE, BP, AP and OP-10 or NP-10, wherein the mass ratio of the AE to the BP to the AP to the OP-10 or the NP-10 is 1 to 2 to 2 to 1, 2 to 1to 1 to 2, 1to 3to 3 to 2 or 2 to 3 to 2 to 1; (2) demulsifying and flocculating, namely under a stirring state, adding a polymeric flocculant, the composite demulsifying agent, an anionic surfactant and a cationic surfactant into the waste liquid of the oil-based drilling liquid; and (3) carrying out solid-liquid separation. The method provided by the invention is suitable for recycling and treatment of the base oil of the waste liquid of various oil-based drilling liquids, the technology is simple, no heating is needed, the investment is less, the cost is low, and the recycling rate of the oil is high; the recycled base oil is used for preparing the drilling liquid again, the performance of the drilling liquid is not changed, so that harmlessness and reclamation of the drilling liquid are realized, and energy is saved.
Owner:CHINA PETROLEUM & CHEM CORP +1

Method for displacement chemical silver plating on copper powder

The invention discloses a method for displacement chemical silver plating on copper powder. The method comprises the following steps of: cleaning and oil removal, water washing, acid etching, water washing, catalytic liquid treating, chemical silver plating and the like. In the method, a catalytic liquid capable of preplanting catalytic mass points is developed; the surface of the copper powder is preplanted with discretely distributed palladium mass points after the copper powder is treated by the catalytic liquid at a room temperature by controlling components, pH value and treatment time of the catalytic liquid; and the preplanted palladium mass points can catalyze and promote the silver ion reduction to improve precipitation speed and to retard copper-ammonia complex ions to be absorbed on the copper surface so as to obtain a sliver plating layer with good cladding performance in the chemical silver-plating process for the copper powder. Compared with the conventional method of displacement chemical silver plating, the method realizes surface activation of the copper powder by pretreating the catalytic liquid, a silver content of the silver plating copper powder is greatly improved, the problems of poor cladding performance of replacement type chemical silver plating and the like are solved, and the method is simple in process and convenient to operate and has good application prospect.
Owner:GUANGDONG UNIV OF TECH

Polyaluminium chloride e-poly-dimethyl-diallyl-ammonium chloride composite flocculent, preparation and use method thereof

The invention discloses a PAC-PDMDAAC compound coagulant, a corresponding preparation method and an application method. The PAC-PDMDAAC compound coagulant is prepared as the following steps: the PAC dry powder or solution is arranged in a mixing reactor, and water is added to obtain a PAC solution which is stirred under normal temperature and a PDMDAAC colloid is added into the solution; the mixed solution is stirred under normal temperature till the PDMDAAC colloid is completely dissolved to obtain a stable PAC-PDMDAAC. The application of the PAC-PDMDAAC compound coagulant is to adopt the PAC-PDMDAAC compound coagulant for the coagulation treatment to raw water and waste water and sewage and the dehydration treatment to sludge or silt directly or after dilution with water by any proportion. The component structure and content scope of the invention are distinct to guarantee the capability and stability of the obtained PAC-PDMDAAC compound coagulant, and the materials on industrial manufacturing are available. The various functions of the PAC-PDMDAAC compound coagulant can be adjusted during water treatment with high adaptability so as to reduce cost, reinforce coagulation effect and dramatically enhance the quality of obtained water.
Owner:NANJING UNIV OF SCI & TECH

Polymeric ferric sulfate-poly-dimethyl-diallyl-ammonium chloride composite flocculent, preparation and use method thereof

The invention discloses a PFS-PDMDAAC compound coagulant, a corresponding preparation method and an application method. The PFS-PDMDAAC compound coagulant is prepared as the following steps: the PFS dry powder or solution is arranged in a mixing reactor, and water is added to obtain a ferric-salt PFS solution which is stirred under normal temperature and a PDMDAAC colloid is added into the solution; the mixed solution is stirred under normal temperature till the PDMDAAC colloid is completely dissolved to obtain a stable PFS-PDMDAAC. The application of the PFS-PDMDAAC compound coagulant is to adopt the PFS-PDMDAAC compound coagulant for the coagulation treatment to raw water and waste water and sewage and the dehydration treatment to sludge or silt directly or after dilution with water by any proportion. The component structure and content scope of the invention are distinct to guarantee the capability and stability of the obtained PFS-PDMDAAC compound coagulant, and the materials on industrial manufacturing are available. The various functions of the PFS-PDMDAAC compound coagulant can be adjusted during water treatment with high adaptability so as to reduce cost, reinforce coagulation effect and dramatically enhance the quality of obtained water.
Owner:NANJING UNIV OF SCI & TECH

Low-temperature high-activity flue gas denitrification catalyst and preparation thereof

ActiveCN104941630ALow denitrification catalytic efficiencyHigh denitrification catalytic efficiency of flue gas at low temperature (90-120°C)Dispersed particle separationMetal/metal-oxides/metal-hydroxide catalystsRare-earth elementSinter Plant
The invention relates to a low-temperature high-activity flue gas denitrification catalyst and preparation thereof. According to the catalyst, a carbon-base material serves as a carrier and carries one or more metal active components of active Al2O3, Mn, Cu and Fe and one or two of rare earth active components of Ce and La. The content of the carbon-base carrier ranges from 35% to 65%, the carrying content of the Al2O3 ranges from 2% to 5% by the content of the aluminum element, the content of the metal active components ranges from 13% to 26% by the content of the metal elements, and the carrying content of the rare earth active components ranges from 20% to 39% by the content of the rare earth elements. According to the catalyst, the carbon-base material is activated through dilute nitric acid and then is coated with aluminum oxide sol, the metal active components and the rare earth active components are carried, then drying and sintering are carried out in the inert atmosphere, and the catalyst is obtained. The catalyst high in flue gas denitrification catalytic efficiently at the low temperature (90-120 DEG C) and not likely to cause poisoning and failures is obtained. The catalyst is low in production cost, simple in production technology and especially suitable for thermal power plants, steel plants, sintering plants and other enterprises with heavy fuel gas emission.
Owner:北京大学包头创新研究院

Closed-type constant-temperature multi-layer water circulation turtle cultivation system

The invention discloses a closed-type constant-temperature multi-layer water circulation turtle cultivation system which comprises a multilayer turtle cultivation pool devices, a cultivation water environment adjusting device, an indoor air environment adjusting device and a cultivation system operation control device, wherein the multilayer turtle cultivation pool device comprises a plurality of turtle cultivation pools, circulating water return pipes, circulating water outlet branch pipes and main circulating water outlet pipes, primary solid liquid precipitation devices, blow-down valves and pollution discharge blow-down pipes; the cultivation water environment adjusting device comprises a solid-liquid separator, a blow-down valve, a sterilizer, a protein separator, a biological filtering device or tank, a circulating pump and a water heating device; and the indoor air environment adjusting device comprises an air heating device, an air oxygenating device and an insulation building. According to the closed type constant-temperature multi-layer water circulation turtle cultivation system, turtle cultivation environments can be comprehensively controlled, the land, the water and the energy are saved, an optimal ecological environment suitable for turtles to rapidly grow is established, turtle cultivation is free of drugs, and healthy and safe food sanitation requirements are met.
Owner:ZHEJIANG UNIV

Heat source-free short-time preparation method of controlled-release type polycarboxylic acid high-performance slump retaining agent

The invention relates to a polycarboxylate superplasticizer, and particularly relates to a heat source-free short-time preparation method of a controlled-release type polycarboxylic acid high-performance slump retaining agent. The heat source-free short-time preparation method comprises the following steps: adding methyl allyl polyethenoxy ether and water in a container, after stirring for 0.5 hour at normal temperature, adding an initiator and an initiation additive, stirring for 2min at normal temperature; titrating a mixed water solution of acrylic acid, hydroxyethyl acrylate and 2-acrylamide-2-methylacrylsulfonate, and a chain transfer agent water solution simultaneously within 1 hour, then insulating heat for 0.5 hour, regulating a pH value to 6-7 by adopting an alkaline liquor, and finally diluting by adding water until the solid content is 40 percent. The heat source-free short-time preparation method is simple in preparation process, simple in equipment, and free from heating in the whole reaction process so that energy resources are saved; the production period is only 2 hours, and thus the production efficiency is greatly increased, and the application range is wide; and the synthesized controlled-release type polycarboxylic acid high-performance slump retaining agent has the characteristics of less doping amount, good slump retaining property, environment friendliness and the like.
Owner:山东卓星化工有限公司

Method for preparing high-purity bulleyaconitine A

The invention discloses a method for preparing high-purity bulleyaconitine A. The method comprises the following steps of: soaking a fresh radix aconiti agrestis root in acid aqueous solution, performing homogenate extraction and cavitation mixing solid-liquid extraction, collecting and concentrating the filtrate, and respectively performing gradient elution to obtain a crude bulleyaconitine A product through ion exchange resin column chromatography and macroporous adsorption resin column chromatography; and uniformly mixing crude bulleyaconitine A product and ethanol aqueous solution, dissolving in a water bath, cooling the filtrate to room temperature, standing and crystallizing at the temperature of 4 DEG C, repeatedly washing the crystal by using the ethanol aqueous solution, and obtaining a final product. According to the method, crushing and extracting are finished in one step through a homogenization method, and the method has the advantages of zero dust and simple flow. By adoption of a negative-pressure cavitation extraction technology, the mass transfer rate is improved, heating is not required, and the production period is shortened; and moreover, the reagents used in the whole process are ethanol and water, the organic solvent amount is greatly reduced, the production cost can be reduced, the environmental pollution is reduced, and the method has good application prospect.
Owner:INST OF MEDICINAL PLANTS YUNNAN ACAD OF AGRI SCI

Cleaning agent for stainless steel seamless stay tubes and preparation method for cleaning agent

The invention relates to the technical field of chemical cleaning, in particular to a cleaning agent for stainless steel seamless stay tubes and a preparation method for the cleaning agent. The cleaning agent for the stainless steel seamless stay tubes is prepared by mixing the following raw materials in percentage by weight at normal temperature: 45.5 to 72.75 percent of water, 1 to 2 percent of alkylphenol polyoxyethylene, 2.5 to 5 percent of citric acid, 5 to 10 percent of oxalic acid, 2.5 to 5 percent of sodium molybdate, 5 to 10 percent of triethanolamine, 7.5 to 15 percent of fatty alcohol-polyoxyethylene ether, 3 to 6 percent of tartaric acid, 0.25 to 0.5 percent of nitric acid, 0.25 to 0.5 percent of hydrofluoric acid and the balance of hexamethylenetetramine. The cleaning agent for the stainless steel seamless stay tubes has novel process, is easy to operate and strong in cleaning force, does not need to be heated, can be reused, can be used for cleaning the stainless steel seamless stay tubes without corroding the surface of stainless steel, and keeps the glossiness of the stainless steel; and the cleaning agent for the stainless steel seamless stay tubes has no injury to the skin, is low-carbon and environment-friendly, has high cost performance, and saves the cost.
Owner:云霄县食品快检中心
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