Synthesis of metal-free, heavy-atom-free and long-lived room-temperature phosphorescent polymers by microwave irradiation
A technology of room temperature phosphorescence and microwave radiation, applied in chemical instruments and methods, luminescent materials, etc., can solve the problems of enhancement, toxicity, and increased material costs, and achieve strong phosphorescence emission, low price, and easy-to-obtain raw materials
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Embodiment 1
[0020] Dissolve 50 mg (0.26 mmol) of vinyl carbazole and 1.38 g (19.5 mmol) of acrylamide in 23 g of water in a round bottom flask, then add 0.014 g of ammonium persulfate, mix well and place in a WBFY201 microwave reactor ( 2450 ± 50 MHz microwave frequency) and connected to a straight condenser, reflux the copolymerization reaction at 520 W microwave output power for 4 min, after cooling to room temperature, drop the reaction solution into methanol to precipitate, filter, wash the filter with methanol The cake was dried three times in a vacuum oven at 70°C to obtain a metal-free, heavy-atom-free, long-lived phosphorescent polymer material at room temperature. The phosphorescent emission peaks are located at 414 nm, 440 nm and 462 nm. figure 1 As shown, the triplet lifetimes are 3.22 s, 3.24 s and 3.21 s, respectively.
[0021] The long-life room temperature phosphorescent polymer prepared in this example emits blue-violet light under the irradiation of a 365 nm ultraviolet l...
Embodiment 2
[0023] Dissolve 50 mg (0.26 mmol) of vinyl carbazole and 460 mg (6.48 mmol) of acrylamide in 8.5 g of water in a round bottom flask, then add 0.005 g of ammonium persulfate, mix well and place in a WBFY201 microwave reactor ( 2450 ± 50MHz microwave frequency) and connected to a straight condenser, reflux copolymerization reaction at 520W microwave output power for 3.5 minutes, after cooling to room temperature, drop the reaction liquid into methanol to precipitate, filter, and wash the filter cake with methanol 3 The second time, it was dried in a vacuum drying oven at 80°C to obtain a microwave-assisted synthesis of metal-free, heavy-atom-free, long-lived room temperature phosphorescent polymer. Its phosphorescent emission peaks are located at 414 nm, 440 nm and 462 nm, and the triplet lifetimes are 4.06 s, 3.89 s and 3.96 s, respectively. The lifetime decay diagram is shown in figure 2 .
[0024] The organic room-temperature phosphorescent material prepared in this example...
Embodiment 3
[0026] Dissolve 50 mg (0.26 mmol) of vinyl carbazole and 1.38 g (19.5 mmol) of acrylamide in 22 g of N,N-dimethylformamide in a round bottom flask, then add 0.018 g of ammonium persulfate, and mix well Placed in a WBFY201 microwave reactor (2450 ± 50 MHz microwave frequency) and connected to a straight condenser, reflux copolymerization reaction at 325 W microwave output power for 6 minutes, after cooling to room temperature, drop the reaction liquid into methanol to precipitate , filtered, washed the filter cake with methanol for 3 times, and dried in a vacuum oven at 80°C to obtain a metal-free, heavy-atom-free, long-life room-temperature phosphorescent polymer material, which emits blue-violet light under a 365 nm ultraviolet lamp. After the UV lamp was turned off, the afterglow time reached 2 s.
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