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Red mud-based material for roadbed water-stable layer and preparation method of red mud-based material

A technology for water stabilization layer and base material, applied in the field of building materials, can solve the problems of poor coagulation, heavy metal dissolution with large performance fluctuation of roadbed materials, etc., to achieve the effect of improving strength, enhancing mechanical properties, and meeting performance requirements

Active Publication Date: 2021-07-20
SHANDONG HI SPEED GRP CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In order to solve the existing problems of roadbed materials such as large fluctuations in performance, heavy metal dissolution, and high alkalinity in the prior art, the present invention proposes a red mud-based material for roadbed water stability layer and its preparation method. It contains a large amount of calcium-silicon-aluminum salts and alkaline stimulating substances, which can be carbonized to reduce the alkalinity of the red mud itself and improve the activity. In addition, the red mud has a certain gelling property, but its coagulation property is poor, which is different from solidification. The waste gypsum is synergistically activated by heat, adding slag to improve the gelling activity of the red mud itself. At the same time, during the hydration reaction, the three complement each other to form a new gel. The material structure becomes denser with the hydration time, thereby improving Red mud based material strength

Method used

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  • Red mud-based material for roadbed water-stable layer and preparation method of red mud-based material
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preparation example Construction

[0045] In a second aspect, the present invention provides a method for preparing a red mud-based material for a roadbed water stabilization layer, comprising:

[0046] Step 1: Pretreatment of red mud, that is, carbonation;

[0047] Step 2: Synergistically thermally activate the pretreated red mud and solid waste gypsum, and then add slag;

[0048] Step 3: Add activator, heavy metal curing agent and water retaining agent;

[0049] Step 4: Stir various raw materials in proportion to make a slurry, and then cure and solidify.

[0050] The specific conditions of the carbonation are: the humidity is 20%-80%, the temperature is 50-100°C, CO 2 The pressure intensity is 1-2.5MPa, and the time is 120-180min, preferably 180min. The purpose of carbonation is to reduce the alkalinity of the red mud itself and improve the activity.

[0051] The synergistic thermal activation temperature of red mud and solid waste gypsum is 400-900°C and the time is 60-90min. Under this condition, the s...

Embodiment 1

[0065] 1) Take 80 parts of Bayer red mud, pretreat and carry out carbonation treatment, the humidity is 40%, the temperature is 100°C, CO 2 The pressure intensity is 1MPa, and the time is 180min;

[0066] 2) Take 10 parts of slag and 20 parts of desulfurized gypsum;

[0067] 3) Synergistically thermally activate the pretreated red mud and desulfurized gypsum at a temperature of 600°C for 60 minutes, and add slag;

[0068] 4) Take 3 parts of phosphate, 6 parts of water glass 1.8M, and 8 parts of polyacrylamide, in parts by mass;

[0069] 5) Mix and stir various raw materials, and stir for 10 minutes.

[0070] Table 1. Performance characterization of the red mud-based material of the roadbed water stabilization layer in Example 1

[0071]

[0072]

[0073] The experimental data show that with the extension of time, the pH value of the red mud-based material used for the roadbed water stabilization layer has risen to a certain extent, but it is significantly lower than t...

Embodiment 2

[0075] 1) Take 85 parts of Bayer red mud, pretreat and carry out carbonation treatment, the humidity is 50%, the temperature is 80°C, CO 2 The pressure intensity is 1.5MPa, and the time is 180min;

[0076] 2) Take 15 parts of slag and 20 parts of desulfurized gypsum;

[0077] 3) Synergistically thermally activate the pretreated red mud and desulfurized gypsum at a temperature of 700°C for 60 minutes, and add slag;

[0078] 4) Take 4 parts of limestone, 8 parts of water glass 2.0M, 6 parts of starch grafted acrylate, in parts by mass;

[0079] 5) Mix and stir various raw materials, and stir for 10 minutes.

[0080] Table 2. Performance characterization of the red mud-based material of the roadbed water stabilization layer in Example 2

[0081] 3d 7d 28d PH value 9.10 9.34 10.02 Compressive strength / MPa 5.01 9.67 38.9 Deflection value / 0.01mm 21.5 22.3 23.4

[0082] The experimental data shows that, compared with Example 1, the initial ...

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Abstract

The invention relates to the field of building materials, in particular to a red mud-based material for a roadbed water stable layer and a preparation method of the red mud-based material. The red mud-based material for the roadbed water-stable layer comprises 80-95 parts of red mud, 10-20 parts of furnace slag, 20-30 parts of solid waste gypsum, 1-5 parts by mass of a heavy metal curing agent, 4-8 parts by mass of an exciting agent and 6-10 parts by mass of a water-retaining agent. The red mud and the solid waste gypsum are synergistically thermally activated, the slag is added, the gelling activity of the red mud is improved, meanwhile, in the hydration reaction process, the red mud, the slag and the red mud are synergistically complemented to generate new gel, and the material structure is more and more compact along with hydration time, so that the strength of the red mud-based material is improved. On the other hand, the specific heavy metal curing agent, exciting agent and water-retaining agent are selected, so that the alkalinity of the red mud-based material is further reduced, and the red mud-based material has relatively low heavy metal dissolution rate.

Description

technical field [0001] The invention relates to the field of building materials, in particular to a red mud-based material used for roadbed water stabilization layers and a preparation method thereof. Background technique [0002] The information disclosed in this background section is only intended to increase the understanding of the general background of the present invention, and is not necessarily taken as an acknowledgment or any form of suggestion that the information constitutes the prior art already known to those skilled in the art. [0003] Red mud is a red solid powdery waste discharged from the aluminum industry when it extracts alumina. Every time 1 ton of alumina is produced, 1 to 2 tons of red mud will be produced. All are stored in the open air, and most of the dam body of the storage yard is constructed with red mud. The stacking of red mud not only wastes land resources, but due to its highly alkaline nature, the chemical components of red mud will also ...

Claims

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Application Information

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IPC IPC(8): C04B28/14C04B18/10C04B18/04
CPCC04B28/143C04B28/144C04B28/142C04B18/0409C04B18/10C04B2111/0075C04B2201/50C04B22/16C04B12/04C04B24/2652C04B14/28C04B24/38C04B14/04C04B24/2641Y02W30/91
Inventor 左志武李召峰王凯周志浩张宁
Owner SHANDONG HI SPEED GRP CO LTD