Composite process antibacterial ceramic tile and preparation method thereof

A composite process and technology of ceramic tiles, applied in the field of new building ceramic materials, can solve the problems of weak bonding between the antibacterial layer and the glazed surface, affecting the surface decoration effect, poor antibacterial durability, etc., achieve excellent chemical resistance stability, and realize antifouling Good effect of performance and acid resistance

Active Publication Date: 2021-08-13
FOSHAN OCEANO CERAMICS +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them: the first kind of antibacterial ceramics, because the antibacterial material is directly added to the ceramic tile body or glaze and fired, and its antibacterial active ingredients are coated in the body or glaze, its antibacterial effect will be greatly reduced
The second antibacterial material is sprayed on the surface of ceramic tiles and then fired. After high-temperature heat treatment, the structure of the antibacterial material is destroyed, and the antibacterial effect is significantly reduced. A certain amount of antibacterial material is attached to the surface of ceramic tiles. During high-temperature heat treatment, it is easy to react with the glaze surface and affect the surface decoration. Effect
The third type adopts low-temperature heat treatment. The antibacterial layer has weak bonding force with the glaze surface. In practical application, the antibacterial layer is easy to fall off, and the antibacterial durability is poor.
However, the above-mentioned scheme mainly has the following problems. First, zinc oxide or silver oxide is used as the antibacterial material in the antibacterial and antifouling liquid adopted in the prior art. Or silver ion salt solution, in the process of washing, it is easy to wash off the antibacterial material, resulting in poor antibacterial persistence

Method used

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  • Composite process antibacterial ceramic tile and preparation method thereof

Examples

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Effect test

Embodiment 1

[0043] An antibacterial ceramic brick with composite technology, including a green body layer and an antibacterial glaze layer, wherein: the chemical composition of the raw material of the green body layer, by weight percentage, includes: SiO 2 66.76%, Al 2 o 3 24.87%, Fe 2 o 3 0.71%, TiO 2 0.15%, CaO1.15%, MgO0.32%, K 2 O 3.05%, Na 2 O 2.89%.

[0044] The glaze of the antibacterial glaze layer contains the first antibacterial agent and the basic glaze, the first antibacterial agent is zinc silicate, the addition of zinc silicate is 8 parts, the basic glaze is 92 parts, and the chemical composition of the basic glaze is by mass percentage Gauge includes SiO 2 56.07%, Al 2 o 3 19.77%, Fe 2 o 3 0.24%, TiO 2 0.25%, CaO 10.74%, MgO 4.41%, ZnO 5.13%, K 2 O 0.25%, Na 2 O3.14%.

[0045] The micropores on the surface of the antibacterial glaze layer are filled with an antibacterial and antifouling agent. The antibacterial and antifouling agent contains a second a...

Embodiment 2

[0052] An antibacterial ceramic brick with composite technology, including a green body layer and an antibacterial glaze layer, wherein: the chemical composition of the raw material of the green body layer, by weight percentage, includes: SiO 2 66.76%, Al 2 o 3 24.87%, Fe 2 o 3 0.71%, TiO 2 0.15%, CaO1.15%, MgO0.32%, K 2 O 3.05%, Na 2 O 2.89%.

[0053] The glaze of the antibacterial glaze layer contains the first antibacterial agent and the basic glaze, the first antibacterial agent is zinc aluminate, the addition of zinc aluminate is 5 parts, the basic glaze is 95 parts, and the chemical composition of the basic glaze is by mass percentage Gauge includes SiO 2 56.07%, Al 2 o 3 19.77%, Fe 2 o 3 0.24%, TiO 2 0.25%, CaO 10.74%, MgO 4.41%, ZnO 5.13%, K 2 O 0.25%, Na 2 O3.14%.

[0054] The micropores on the surface of the antibacterial glaze layer are filled with antibacterial and antifouling agents. The antibacterial and antifouling agents contain a second a...

Embodiment 3

[0061] An antibacterial ceramic brick with composite technology, including a green body layer and an antibacterial glaze layer, wherein: the chemical composition of the raw material of the green body layer, by weight percentage, includes: SiO 2 66.76%, Al 2 o 3 24.87%, Fe 2 o 3 0.71%, TiO 2 0.15%, CaO1.15%, MgO0.32%, K 2 O 3.05%, Na 2 O 2.89%.

[0062] The glaze of the antibacterial glaze layer contains the first antibacterial agent and the basic glaze, the first antibacterial agent is zinc silicate and zinc aluminate, the addition of zinc silicate and zinc aluminate is 7 parts, and the basic glaze is 93 parts, The basic polishing glaze chemical composition includes SiO in mass percentage 2 56.07%, Al 2 o 3 19.77%, Fe 2 o 3 0.24%, TiO 2 0.25%, CaO 10.74%, MgO 4.41%, ZnO 5.13%, K 2 O 0.25%, Na 2 O 3.14%.

[0063] The micropores on the surface of the antibacterial glaze layer are filled with antibacterial and antifouling agents, the antibacterial and antif...

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Abstract

The invention relates to the technical field of new building ceramic materials, and particularly discloses a composite process antibacterial ceramic tile and a preparation method thereof. The composite process antibacterial ceramic tile comprises a green body layer and an antibacterial glaze layer, glaze of the antibacterial glaze layer contains a first antibacterial agent, and surface micropores of the antibacterial glaze layer are filled with an antibacterial antifouling agent; and the first antibacterial agent comprises zinc silicate and / or zinc aluminate, the antibacterial antifouling agent contains a second antibacterial agent, and the second antibacterial agent comprises nano zinc phosphate and / or nano zinc zirconate. The preparation method comprises the following steps: preparing the green body layer, preparing the antibacterial glaze slip, spraying the antibacterial glaze slip on the surface of the green body layer, sintering to obtain a semi-finished product, polishing the semi-finished product, and polishing the surface of the semi-finished product by using an antibacterial antifouling agent to obtain the antibacterial ceramic tile. According to the antibacterial ceramic tile, a composite antibacterial technology combining in-glaze antibacterial and glaze layer surface micropore antibacterial is adopted, efficient and lasting antibacterial of a ceramic tile product is achieved, antibacterial components do not affect permeability of a glaze surface, and the antifouling performance of the glaze surface can be achieved.

Description

technical field [0001] The invention relates to the technical field of new building ceramic materials, in particular to a functional ceramic material, in particular to a compound process antibacterial ceramic brick and a preparation method thereof. Background technique [0002] At present, for non-polished ceramic tiles, there are mainly the following types of antibacterial ceramics: the first is to directly add antibacterial materials to ceramic tiles and mix and fire them. The antibacterial agent generally uses silver phosphate. The second is to spray antibacterial materials on the surface of ceramic tiles. During its preparation, an antibacterial mixed salt solution is sprayed on the surface of transparent glaze to form an antibacterial layer, which is fired at high temperature. The third is to spray antibacterial materials on the surface of finished bricks, and then undergo low-temperature heat treatment to achieve antibacterial effects. Among them: the first kind of an...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/04C03C8/14C03C8/18C04B35/14C04B35/622C04B41/86
CPCC03C8/04C03C8/14C03C8/18C04B35/14C04B35/622C04B41/86C04B41/5022C04B41/009C04B2235/3208C04B2235/3206C04B2235/3201C04B2235/3232C04B2235/3272C04B2235/3217C04B41/4543C04B41/0072
Inventor 柯善军田维蒙臻明马超
Owner FOSHAN OCEANO CERAMICS
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