The present invention discloses a curtain wall for door and an air conditioning device, the curtain wall comprises at least two inner and outer sunlight transparent panel parallel to each other, a peripheral frame or sealing member which with the boards define a heat collection chamber, and a heat absorbing body arranged in the chamber. The invention also provided an air conditioning apparatus, wherein, the chamber communicates with an air duct positioned below a ceiling or a prearranged inside ceiling through air vents on the upper of the chamber, so as to open into an interior room. The invention combines building structure member and the air conditioning device together, which adequately uses building space, and furthest uses lighting area of the building, and adjustment of air temperature and humidity, sterilization, cleanse, fresh air supply, non-noise and harmful gas discharge can be operated depending on solar energy.