Lithium ion battery and electronic device

A lithium-ion battery and electrolyte technology, which is applied to battery electrodes, secondary batteries, circuits, etc., can solve the problems of lithium-ion battery cycle performance and high-temperature performance degradation, low mass density, and increase the specific surface area of ​​the positive electrode surface, etc., to achieve Effects of excellent cycle performance and high-temperature storage performance

Active Publication Date: 2021-09-21
ZHUHAI COSMX BATTERY CO LTD
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Problems solved by technology

Carbon nanotubes are very suitable for use as a conductive agent due to their high conductivity, unique one-dimensional tubular structure and low mass density. They can be used as a conductive agent by adding a small amount of single-walled carbon nanotubes to the positive active layer to replace traditional conductive agents. In this way, the main content of the positive electrode active material in the positive electrode sheet is increased, and the energy density of the battery is improved. However, the specific surface area of ​​the positive electrode surface will be increased after adding single-walled carbon nanotubes, which will cause side reactions to occur easily on the positive electrode surface. And it is easy to blow out during high temperature storage, which will lead to poor cycle performance and high temperature performance of lithium-ion batteries

Method used

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  • Lithium ion battery and electronic device
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  • Lithium ion battery and electronic device

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preparation example Construction

[0049] 1) Preparation of positive electrode sheet

[0050] Mix positive electrode active material lithium cobalt oxide (LCO), binder polyvinylidene fluoride (PVDF), conductive agent acetylene black, and carbon nanotubes, add N-methylpyrrolidone (NMP), and stir under the action of a vacuum mixer until Mix the system into a positive electrode active slurry with uniform fluidity; apply the positive electrode slurry evenly on the upper and lower functional surfaces of the aluminum foil with a thickness of 12 μm; bake the above-mentioned coated aluminum foil in an oven with 5 different temperature gradients , and then dried in an oven at 120° C. for 8 hours, so that the positive electrode active slurry formed a positive electrode active layer on the aluminum foil, and then rolled and cut to obtain positive electrode sheets.

[0051] Wherein, the charging upper limit voltage of the positive electrode active material lithium cobalt oxide is 4.48V.

[0052] 2) Preparation of negative...

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Abstract

The invention provides a lithium ion battery and an electronic device. The lithium ion battery comprises a positive plate and an electrolyte; a positive active layer of the positive plate comprises a single-walled carbon nanotube; the electrolyte comprises fluoroethylene carbonate and ethylene carbonate, and the mass percentage content of the fluoroethylene carbonate in the electrolyte is 10-25%; and the mass percentage content of the ethylene carbonate in the electrolyte is less than 9%. The lithium ion battery can effectively solve the problems of 45 DEG C interval cycle later-stage air blowing and high-temperature storage air blowing caused by the single-walled carbon nanotube contained in the positive electrode so that the lithium ion battery has excellent cycle performance and high-temperature performance.

Description

technical field [0001] The invention belongs to the technical field of lithium ion batteries, and relates to a lithium ion battery and an electronic device. Background technique [0002] Since its commercialization, lithium-ion batteries have been widely used in the fields of digital, energy storage, power, military aerospace and communication equipment because of their advantages such as light weight, high specific energy, no memory effect, and good cycle performance. [0003] With the widespread application of lithium-ion batteries, consumers have put forward higher requirements for the energy density, cycle life, high-temperature performance, and safety performance of lithium-ion batteries. At present, there are many ways to increase the energy density of the battery, such as increasing the charging voltage of the positive electrode, using a silicon negative electrode with a higher capacity, increasing the compaction density of the positive and negative electrodes, and re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M10/0525H01M10/0566H01M10/0568H01M10/0569H01M4/583H01M4/62
CPCH01M10/0525H01M10/0566H01M10/0568H01M10/0569H01M4/583H01M4/625Y02E60/10
Inventor 曾长安李素丽李俊义
Owner ZHUHAI COSMX BATTERY CO LTD
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