A kind of azo printing and dyeing wastewater treatment process
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A technology for treating process, printing and dyeing wastewater, applied in textile industry wastewater treatment, water/sewage treatment, water treatment parameter control, etc. Effect
Active Publication Date: 2021-11-16
江苏通海染整有限公司
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As a strong oxidant, persulfate is added to the printing and dyeing wastewater, because it has no specific oxidation characteristics, and the organic matter in the wastewater will react with it. The treatment cost is high and the efficiency is low, so it is difficult to be used in printing and dyeing wastewater on a large scale. ;
[0004] CN101624250B discloses a sewage treatment method of anaerobic zero-valent iron, which releases Fe in the anaerobic reactor through internal electrolysis, neutralization of organic acids, etc. 2+ , because zero-valent iron contains carbon and other inert materials, it is the cathode during the reaction process, and iron is the anode, forming an electrode reaction. However, in the process of treating printing and dyeing wastewater in this process, due to the poisonous effect of azo fuels, it will greatly reduce the reaction. Efficiency, even difficult to degrade degradable substances in printing and dyeing wastewater
[0005] There is a major problem in the above processes of printing and dyeing wastewater using zero-valent iron as a reducing agent, that is, in the actual wastewater treatment process, it is difficult to directly treat refractory organic matter with oxidants or microorganisms, and the toxic substances in printing and dyeing wastewater will reduce microbial activity and thus As a result, the biochemical method is difficult to continue to operate, and in the oxidation process, due to the variety of organic substances in the printing and dyeing wastewater, it is difficult to treat toxic substances
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Embodiment 1
[0034] Take a certain printing and dyeing wastewater, pH9.3, chroma 970, CODcr1400mg / L, methyl orange 9.16×10 -5 mol / L;
[0037] The sludge discharged from the biological adsorption tank is transported to the wall-breaking treatment process, and the sludge is subjected to wall-breaking treatment. 2 10 minutes under the acoustic energy density;
[0038] (3) Anaerobic acidification
[0039] The sludge treated by wall breaking is transported to the anaerobic acidification process for acidification treatment, and after controlling its pH to be maintained between 4.5-5, the reaction conditions are maintained for 1 hour;
[0040] (4) Reduction treatment
[0041] The supernatant of the anaerobic acidification process and the effluent of the biosorption treatment process are transported to the r...
Embodiment 2
[0046] On the basis of Example 1, the effluent from the biosorption treatment was sent to the micro-electrolysis process, and the effluent from the micro-electrolysis process was sent to the dehydration process for dehydration treatment.
[0047] Effluent water quality: pH7.1, chroma 29, CODcr53 mg / L, methyl orange was not detected.
Embodiment 3
[0049] On the basis of Example 2, the concentrated solution of the ultrafiltration process is subjected to oxidation treatment before entering the biochemical process, and the oxidation treatment is a Fenton oxidation process.
[0050] Effluent water quality: pH 7.1, chroma 18, CODcr 35 mg / L, methyl orange was not detected.
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Abstract
This case involves a process for the treatment of azo printing and dyeing wastewater, which undergoes biosorption treatment, wall breaking treatment, anaerobic acidification, reduction treatment, and membrane filtration in sequence. The printing and dyeing wastewater containing azo dyes is subjected to biosorption treatment. With a huge specific surface area, more than 70% of the azo dyes are adsorbed on the surface of the bacterial micelles, and the sludge adsorbed with dye pollutants is subjected to ultrasonic wall breaking treatment, so that the toxic and harmful dyes are fully mixed with the crushed slurry of microorganisms. Transport it to the anaerobic acidification process for treatment. When the pH drops to 4.5‑6.3, the supernatant of the anaerobic acidification tank is transported to the reduction treatment process for reduction treatment. Zero-valent iron can treat azo dyes under acidic anaerobic conditions. Reduction, the azo bond is broken, and the chromaticity is reduced.
Description
technical field [0001] The invention belongs to the field of printing and dyeing wastewater treatment, and in particular relates to an azo printing and dyeing wastewater treatment process. Background technique [0002] With the rapid development of the textile industry, the discharge of printing and dyeing wastewater is huge. The printing and dyeing wastewater has the characteristics of high concentration of organic matter, high chroma, high content of inorganic salts, complex components, and poor biodegradability. Due to the low treatment rate, the discharge of printing and dyeing wastewater to the water environment cause serious pollution. Dyes have a complex structure, and many of them are variants. They come from a wide range of sources. Most of the dyes are made from carcinogens. If they are discharged into water bodies without treatment, studies have shown that some dyes will continue to pass through the food chain. accumulation. Although its concentration may be low...
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