Aluminate-based low-dielectric microwave dielectric ceramic and preparation method thereof

A technology of microwave dielectric ceramics and aluminate, applied in the field of microwave dielectric ceramics, can solve problems such as high energy loss, high signal delay, high system heating, etc., achieve high quality factor, alleviate signal delay, and increase transmission rate Effect

Active Publication Date: 2021-10-08
WENZHOU ADVANCED MFG TECH INST OF HUAZHONG UNIV OF SCI & TECH
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  • Abstract
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Problems solved by technology

[0003] Aiming at the deficiencies in the prior art, the present invention provides an aluminate-based low dielectric microwave dielectric ceramic and its ...

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  • Aluminate-based low-dielectric microwave dielectric ceramic and preparation method thereof
  • Aluminate-based low-dielectric microwave dielectric ceramic and preparation method thereof
  • Aluminate-based low-dielectric microwave dielectric ceramic and preparation method thereof

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Embodiment Construction

[0021] In order to make the object, technical solution and advantages of the present invention clearer, the present invention will be further described in detail below in conjunction with the accompanying drawings and embodiments. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention. In addition, the technical features involved in the various embodiments of the present invention described below can be combined with each other as long as they do not constitute a conflict with each other.

[0022] Such as figure 1 As shown, a preparation method of aluminate-based low dielectric microwave dielectric ceramics, comprising:

[0023] (1) CaCO with a purity of more than 99.5% 3 , Ln 2 o 3 , ZrO 2 , MO 2 , and Al 2 o 3 According to the chemical formula (2+x)CaO-0.5Ln 2 o 3 -(2-y)ZrO 2 -(x+y)MO 2 -1.5Al 2 o 3 Perform batching to obtain mixed raw materials, wherein, Ln is Y, L...

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Abstract

The invention discloses an aluminate-based low-dielectric microwave dielectric ceramic and a preparation method thereof. The main crystal phase of the microwave dielectric ceramic has a garnet type crystal structure, the specific chemical composition is (2+x)CaO-0.5Ln2O3-(2-y)ZrO2-(x+y)MO2-1.5Al2O3, Ln is Y, La, Lu, Gd or other lanthanide elements, M is Hf, Sn or Ti, x is more than or equal to 0 and less than or equal to 0.5, and y is more than or equal to 0 and less than or equal to 2.0. The dielectric constant of the microwave dielectric ceramic ranges from 10.81 to 13.52, the quality factor ranges from 72441 GHz to 121930 GHz, and the temperature coefficient of resonance frequency ranges from +0.50 ppm/DEG C to -35.48 ppm/DEG C. In the preparation process, the pre-sintering condition of the ceramic material is that the temperature is kept at 1300 DEG C for 5 hours, and the sintering condition is that the temperature is kept at 1500-1600 DEG C for 10 hours. The microwave dielectric ceramic prepared in the invention has the characteristics of low dielectric constant, high quality factor and adjustable resonant frequency temperature coefficient to near zero, and is suitable for preparing microwave communication devices such as dielectric substrates, dielectric resonators, dielectric antennas and the like.

Description

technical field [0001] The invention belongs to the technical field of microwave dielectric ceramics, and more specifically relates to an aluminate-based low dielectric microwave dielectric ceramic and a preparation method thereof. Background technique [0002] Microwave dielectric ceramics are the basic materials for preparing passive devices such as high-frequency capacitors, dielectric substrates, dielectric waveguide filters, and dielectric antennas, and are therefore widely used in various wireless communication systems. As 5G communication gradually enters the commercial stage, the integration level and operating frequency of communication equipment continue to increase, and problems such as signal delay, signal crosstalk, and system heating become increasingly prominent. Microwave dielectric ceramics with low dielectric constant and low dielectric loss can effectively increase the transmission rate of microwave signals and reduce signal energy loss, which meets the ne...

Claims

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Application Information

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IPC IPC(8): C04B35/44C04B35/622C04B35/626C04B35/64
CPCC04B35/44C04B35/622C04B35/62605C04B35/64C04B2235/3208C04B2235/3244C04B2235/3232C04B2235/3227C04B2235/3225C04B2235/3224C04B2235/656C04B2235/6567C04B2235/96
Inventor 宋小强雷文吕文中付明王晓川梁飞汪小红范桂芬
Owner WENZHOU ADVANCED MFG TECH INST OF HUAZHONG UNIV OF SCI & TECH
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