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Preparation method of flexible stretchable miniature supercapacitor

A supercapacitor, miniature technology, used in the manufacture of hybrid/electric double layer capacitors, hybrid capacitor electrodes, hybrid capacitor current collectors, etc., to achieve high production accuracy, good tensile strain, and increased load.

Inactive Publication Date: 2021-10-22
WUHAN INSTITUTE OF TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the current manufacturing process of flexible electrode devices often involves complex processes such as laser etching, high-pressure pressing and masking.

Method used

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  • Preparation method of flexible stretchable miniature supercapacitor
  • Preparation method of flexible stretchable miniature supercapacitor
  • Preparation method of flexible stretchable miniature supercapacitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] A method for preparing a flexible and stretchable micro-supercapacitor is provided, comprising the following steps:

[0045] (1) Use 3D modeling software to construct a mold model and an interdigitated electrode pattern. The size of the bottom plate is 50mm long, 40mm wide, and 3mm high. The protrusion height of the electrode pattern on the bottom plate is 0.5mm. The thickness of the outer wall is 4mm, the height is 10mm, and the outer contour size is the same as that of the bottom plate.

[0046] (2) Using 3D printing technology, select commercialized polylactic acid wire with a diameter of 1.75mm, the printing layer height is 0.1mm, the printing accuracy is 0.1mm, the filling type is grid, the filling density is 100%, and the printing temperature is 150 ℃, print out the bottom plate part and the outer wall part of the mold.

[0047] (3) The outer wall of the mold is combined with the bottom plate, inject 6g of mixed Sylgard-184 silicone rubber and cross-linking agent...

Embodiment 2

[0058] A method for preparing a flexible and stretchable micro-supercapacitor is provided, comprising the following steps:

[0059] (1) Use 3D modeling software to construct the mold model and electrode pattern. The size of the bottom plate is 50 mm in length, 40 mm in width and 3 mm in height, and the protrusion height of the electrode pattern on the bottom plate is 0.5 mm. The thickness of the outer wall is 4mm, and the height is 10mm. The outer contour size is the same as that of the bottom plate.

[0060] (2) Using 3D printing technology, select commercialized polylactic acid wire with a diameter of 1.75mm, the printing layer height is 0.1mm, the printing accuracy is 0.1mm, the filling type is grid, the filling density is 100%, and the printing temperature is 150 ℃, print out the bottom plate part and the outer wall part of the mold.

[0061] (3) The outer wall of the mold is combined with the bottom plate, inject 6g of mixed Sylgard-184 silicone rubber and cross-linking ...

Embodiment 3

[0068] A method for preparing a flexible and stretchable micro-supercapacitor is provided, comprising the following steps:

[0069] (1) Use 3D modeling software to construct the mold model and electrode pattern. The size of the bottom plate is 50 mm in length, 40 mm in width and 3 mm in height, and the protrusion height of the electrode pattern on the bottom plate is 0.5 mm. The thickness of the outer wall is 4mm, and the height is 10mm. The outer contour size is the same as that of the bottom plate.

[0070] (2) Using 3D printing technology, select commercialized polylactic acid wire with a diameter of 1.75mm, the printing layer height is 0.1mm, the printing accuracy is 0.1mm, the filling type is grid, the filling density is 100%, and the printing temperature is 150 ℃, print out the bottom plate part and the outer wall part of the mold.

[0071] (3) The outer wall of the mold is combined with the bottom plate, inject 5g of mixed Sylgard-184 silicone rubber and crosslinking a...

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Abstract

The invention discloses a preparation method of a flexible stretchable miniature supercapacitor, which comprises the following steps of: (1) designing an interdigital electrode pattern by using modeling software; (2) by means of a 3D printer with polylactic acid wires serving as raw materials, printing an interdigital electrode mold,which is composed of a bottom plate and an outer wall, and interdigital electrode patterns formed by protrusions are arranged on the bottom plate; (3) uniformly mixing the silicone rubber and a cross-linking agent, and injecting the mixture into a mold to be cured and formed to form a silicone rubber-based interdigital electrode template, wherein the surface of the template is provided with an interdigital electrode pattern formed by grooves; (4) sequentially depositing a silver current collector, a Bi2O3 / CNT active material and a silver current collector in the groove through a dispensing process to obtain an interdigital electrode; and (5) coating electrolyte on the interdigital part, connecting copper sheets at the two ends of the electrode, and carrying out plastic packaging by using a PET film. The method is simple in process, and the obtained capacitor substrate is light in weight, good in bending performance, high in mechanical stability and suitable for large-scale production.

Description

technical field [0001] The invention belongs to the technical field of micro-supercapacitors, and in particular relates to a method for preparing a flexible and stretchable micro-supercapacitor. Background technique [0002] In recent years, with the rapid development of microelectronics technology, a series of new electronic products such as wearable, miniaturized, foldable, and highly integrated have begun to appear. Therefore, the energy storage and supply problems of these emerging electronic products have become an urgent problem to be solved. question. The new micro flexible supercapacitor has the advantages of integration, high power density, fast charge and discharge speed, reversible energy storage process, bendable, safe and environmentally friendly, and has become a research hotspot for emerging micro energy storage devices in recent years. Micro-supercapacitors are composed of current collectors, electrode materials, substrates, and electrolytes, and the key fac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/84H01G11/86H01G11/24H01G11/26H01G11/36H01G11/46H01G11/68
CPCH01G11/84H01G11/86H01G11/68H01G11/46H01G11/36H01G11/24H01G11/26Y02E60/13
Inventor 孙义民陈振宇周爱军
Owner WUHAN INSTITUTE OF TECHNOLOGY
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