Composition for fluororesin-containing coating, coating film, and substrate
A technology of fluorine-containing resin and composition, applied in coating, conductive paint, pigment slurry, etc., can solve the problems of insufficient workability, difficult lining welding operation, etc., and achieve excellent workability, sufficient conductivity, pollution, etc. less effect
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Embodiment 1
[0122] In order to make the concentration of CNT1 0.05% by mass, in addition, make the concentration of sodium carboxymethylcellulose ("MAC 500LC" manufactured by Nippon Paper Industries Co., Ltd.) 0.05% by mass, add CNT1 and carboxymethylcellulose To ion-exchange water: 10g. The obtained mixed liquid was irradiated with ultrasonic waves for 1 hour using an ultrasonic disperser to prepare a carbon nanotube dispersion liquid.
[0123] Next, 10 g of the carbon nanotube dispersion liquid and the fluororesin dispersion liquid were mixed so that the content of the carbon nanotubes became 0.01% by mass relative to 100% by mass of the total of the fluororesin and carbon nanotubes. The obtained mixed solution was stirred for 1 hour using a magnetic stirrer and a rotor to prepare a fluorine-containing resin coating composition.
[0124] The obtained composition for coating a fluorine-containing resin was placed on a stainless steel plate (a bat made by Stenlace), and dried at 80°C. N...
Embodiment 2~5、 comparative example 1、2
[0126] Except that the carbon nanotubes used as raw materials and the content of carbon nanotubes are changed as shown in Tables 1 and 2, others are the same as in Example 1, and the fluorine-containing resin coating compositions of each example are produced, and the fluorine-containing resin coating compositions of each example are produced. A coated film was used as a test film.
[0127] [Table 1]
[0128]
[0129] [Table 2]
[0130]
[0131] In Examples 1 to 5 in which the content of carbon nanotubes is within the range specified by the present invention, the surface resistivity of any coating film is less than 10 10 Ω / □, and the conductivity as a coating film is sufficient.
[0132] In Examples 4 and 5, the average fiber length of the carbon nanotubes was relatively long due to variations between batches. In Examples 4 and 5, even though the content of carbon nanotubes is relatively small, the surface resistivity is less than 10 4 Ω / □, the conductivity is more ex...
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